• 한국염색가공학회지
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• 제21권5호
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• pp.27-34
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• 2009

PET fabric was dyed in black shade with disperse dyes of three primary color. The effect of combination ratio of dye concentration and energy type of disperse dye on dyeing and color property of black dyed PET fabric was investigated. Dyeing compatibility of disperse dyes of three primary color on PET was evaluated by comparison of dyeing rates of them. From the results, color property was dependent upon the combination ratio of dye concentration. In order to obtain low lightness ($L^*$) and black color, blue dye should be added enough. S-type disperse dye and $130^{\circ}C$ dyeing was suitable rather than SE-type dyes or $120^{\circ}C$ dyeing. Disperse dyes of three primary color used showed good dyeing compatibility at high dye concentration. Washfastness was fair to moderate and lightfastness was moderate.

• 한국염색가공학회지
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• 제13권4호
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• pp.249-255
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• 2001

To interpret the dyeing behavior of PTT fiber with C. I. Disperse Violet 1, the thermodynamic Parameters of dyeing, such as standard affinity, heat of dyeing(enthalpy change), entropy change, diffusion coefficient, and activation energy of diffusion, were obtained from isotherms and dyeing rates at various temperatures and compared with those of PET fiber. The heat of dyeing(enthalpy change) and the entropy change of PTT fiber showed smaller negative values than those of PET fiber. This means that the dye molecules in the PTT fiber are combined more loosely than in the PET fiber and that is due to the flexibility of polymer chains of PTT fiber. The diffusion coefficients of C. I. Disperse Violet 1 into the PTT fiber were larger than those for PET fiber, and the activation energy of diffusion on PTT fiber was smaller than that on PET fiber.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2008년도 제39차 학술발표회
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• pp.13-14
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• 2008

In black dyeing of PET fabric, high concentrations of disperse dyes of three primary color are generally used, which leads low exhaustion level of dye and discharge of a large amount of unfixed dye into dyehouse effluent. In this study, the effect of combination ratio of dye concentration, liquor ratio, and dyeing pH on dyeing and color property of black dyed PET fabric was investigated.

• Fibers and Polymers
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• 제7권2호
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• pp.174-179
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• 2006

Dyeing and color fastness properties of a reactive disperse dye containing an acetoxyethylsulphone group on PET, Nylon, silk and N/P fabrics were examined. The reactive disperse dye exhibited almost the same dyeing properties on PET fabric as a conventional disperse dye except the level of dye uptake. The most appropriate pH and dyeing temperature for the dyeing of Nylon fabric were 7 and $100^{\circ}C$ respectively. The build-up on Nylon fabric was good and various color fastnesses were good to excellent due to the formation of the covalent bond. Application of the reactive disperse dye on silk fabric at pH 9 and $80^{\circ}C$ yielded optimum color strength. The rate of dyeing on Nylon fabric was faster than that on PET fabric when both fabrics were dyed simultaneously in a dye bath, accordingly color strength of the dyed Nylon was higher. The reactive disperse dye can be applied for one-step and one-bath dyeing of N/P mixture fabric with good color fastness.

• 한국염색가공학회지
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• 제20권2호
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• pp.66-74
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• 2008

Effect of disperse dyeing on flame retardant finishing of PET fabrics via UV curing using three UV curable phosphorous-containing methacrylates and ammonium polyphosphate(APP) was investigated. The dye fixation and flame retardancy of PET fabrics did not change significantly with excellent durability to five laundering cycles irrespective of the dyeing and finishing sequence. However, the flame retardancy of Pekoflam-treated fabrics was lower than that of the UV treated and decreased substantially when heat treatment was carried out before the dyeing. The dyeability of the flame-retardant PET fabrics was not affected in the case of UV curing of the methacrylates alone. However, UV finishing after the dyeing caused significant decrease in K/S and ${\Delta}E$ due to changed refraction and inherent color of surface coating of the UV curable monomers and APP. Whereas the heat treatment with Pekoflam decreased both color fastness to laundering and sublimation, surprisingly the UV finish of PET fabrics before and after the dyeing increased the color fastness probably resulting from the presence of photopolymerized surface layer on the fabrics.

• 한국염색가공학회지
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• 제31권3호
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• pp.147-154
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• 2019

In this study, poly(ethylene terephthalate)(PET) fibres dyed with Disperse Red 167 using supercritical $CO_2$ technology. The purpose of this study was to investigate relationship between PET fibers and supercritical $CO_2$ during dyeing. The effects of temperature, pressure, dyeing time and mass ratio between the dye and PET in the dyeing chamber were considered. Thermal and mechanical properties of the fibers were investigated. Tensile strength of dyed PET fibers decreased at higher temperature and pressure conditions. DSC and DMA results indicated that the Tg and Tm values decreased significantly when compared to the pure PET fibers. However, uniformly dyed PET fibers were typically observed.

• 한국염색가공학회지
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• 제20권2호
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• pp.38-46
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• 2008

PET fabrics were cationized via photografting under continuous UV irradiation with a cationic monomer. The grafted PET was dyed with three acid dyes. Effect of dye concentration, dyeing time, temperature and pH on acidic dyeing of the cationized PET fabrics was assessed to find optimal dyeing condition. The cationized fabrics was successfully dyed at $75^{\circ}C$ under pH 5.5. However the dyeing sites of the grafted fabrics were nearly occupied above 5%owf dye concentration and the rapid exhaustion of the anionic dyes was observed. The dyeability of the cationized PET fabrics was increased proportionally with increasing percent grafting because of the introduction of ionic attraction between quaternary ammonium groups and acid dyes. Lower dyeability both at alkaline and pH 3 condition attributed to negative zeta potentials of the grafted fabrics and the reduced charge of the acid dyes respectively.

• 한국염색가공학회지
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• 제21권2호
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• pp.40-47
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• 2009

Dimethylaminopropyl methacryamide was photografted onto PET fabrics by continuous UV irradiation under ambient conditions. Several factors affecting the photografting were studied including irradiation energy, monomer and photoinitiator concentrations. ATR and ESCA analysis showed the successful grafting of the monomer onto the PET surface. The grafted PET fabrics showed higher zeta potentials below pH 7 compared with the ungrafted PET. The dyeability of the grafted PET fabrics to two $\alpha$-bromoacrylamide reactive dyes was investigated under various dyeing conditions including dye concentration, pH, dyeing temperature and time. The grafting imparted the reactive dyeability to PET fabrics, which was proportional to the grafted monomer content. The reactive dyeing behavior of the grafted PET fabrics was similar to that of conventional wool fabrics.

• 한국염색가공학회지
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• 제5권4호
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• pp.67-78
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• 1993

In one bath dyeing system of silk/PET fiber blend fabric with acid/disperse dyes, adsorption behavior of disperse dyes and acid dyes on silk and PET fabrics were examined. In the dyeing of PET with C.I.Disperse Red 19(Red 19) and C.I.Disperse Red 60(Red 60) at 10$0^{\circ}C$(carrier dyeing) and 13$0^{\circ}C$, dye uptake with Red 60 was higher than that with Red 19. When the silk/PET dyed with Red 19 and Red 60 at 10$0^{\circ}C$(carrier dyeing) and 13$0^{\circ}C$, dye uptake on PET was influenced by affinity of the dye to the silk fabric dyed together. When the silk/PET dyed with Blue 80/Red 19 and Blue 80/Red 60 at 10$0^{\circ}C$(carrier dyeing) and 13$0^{\circ}C$ for 60 minutes, color of PET dyed with Red 19 and Red 60 was little influenced by Blue 80 but silk dyed with Blue 80 was influenced. Interrelation of K/S value and Munsell value was scarcely any but showed the change tendency of K/S value.

• 한국염색가공학회지
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• 제18권1호
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• pp.1-9
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• 2006

Treatment of PET fabrics with alkali, chitosan and Al-mordanting has been carried out and the role of the chitosan coating in the dyeing process was clarified. The pre-treatment was effectively evaluated differences in dyeing behavior between its treated and untreated PET fabrics using wood of Caesalpinia sappan. The pre-treated on PET fabrics has been examined by SEM and evidence for the presence of chitosan sought using a air permeability test. Similar colour fastness by computer color matching(CCM) obtained on both untreated and pre-treated PET fabrics. The pre-treated PET was found to be of a deeper hue to that of its dyed untreated PET and, despite of its better colour depth, the wash fastness of the pre-treated dyeing was comparable to that of its dyed untreated PR. The application of chitosan or mordanting reveled that pre-treatment imparted to the PET additional functional groups that were available for coordination with the Brazilin.