• 제목/요약/키워드: PC spectroscopy

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Differentiation between Normal and White Striped Turkey Breasts by Visible/Near Infrared Spectroscopy and Multivariate Data Analysis

  • Zaid, Amal;Abu-Khalaf, Nawaf;Mudalal, Samer;Petracci, Massimiliano
    • 한국축산식품학회지
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    • 제40권1호
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    • pp.96-105
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    • 2020
  • The appearance of white striations over breast meat is an emerging and growing problem. The main purpose of this study was to employ the reflectance of visible-near infrared (VIS/NIR) spectroscopy to differentiate between normal and white striped turkey breasts. Accordingly, 34 turkey breast fillets were selected representing a different level of white striping (WS) defects (normal, moderate and severe). The findings of VIS/NIR were analyzed by principal component (PC1) analysis (PCA). It was found that the first PC1 for VIS, NIR and VIS/NIR region explained 98%, 97%, and 96% of the total variation, respectively. PCA showed high performance to differentiate normal meat from abnormal meat (moderate and severe WS). In conclusion, the results of this research showed that VIS/NIR spectroscopy was satisfactory to differentiate normal from severe WS turkey fillets by using several quality traits.

Study on the eletronic absorption and surface morphology of phthalocyanine double layer thin films

  • 허일수;류일환;홍다정;임상규
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.337-337
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    • 2011
  • The elecronic absorption and surface morphology evolution of two types of molecular double layer thin films, copper phthalocyanine(CuPc) layer deposited on top of chloro[subphtalocyaninato]boron(III) (SubPc) layer, denoted as SubPc/CuPc, and vice versa, at various thicknesses were invertigated using ultraviolet(UV)-visible spectroscopy and atomic force microscopy (AFM). Both types of double layer structures showed similar broadened absorption patterns in UV-visible region which were well consistent with fitted spectra by a simple linear combination of single layer absorption spectra of two materials. In contrast, the surface morphology of double layer structures was dependent on the order of deposition. For CuPc/SubPc structures, the surface morphology was characterized by elongated grains, characteristic of SubPc thin films, indicating the morphological influence of underlying CuPc layer on subsequent SubPc layer was not large. For SubPc/CuPc structures, however, the underlying SubPc layer acted as a morphological template for the subsequently deposited CuPc layer. It was also observed that the grain size of CuPc layer varied by the thickness of underlying SubPc layer.

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Study on Electronic Absorption and Surface Morphology of Double Layer Thin Films of Phthalocyanines

  • Park, Gyoo-Soon;Heo, Il-Su;Ryu, Il-Hwan;Yim, Sang-Gyu
    • Bulletin of the Korean Chemical Society
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    • 제32권3호
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    • pp.943-946
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    • 2011
  • The electronic absorption and surface morphology evolution of two types of molecular double layer thin films, copper phthalocyanine (CuPc) layer deposited on chloro[subphthalocyaninato]boron(III) (SubPc) layer, denoted as SubPc/CuPc, and vice versa, with various thicknesses were investigated using ultraviolet (UV)-visible spectroscopy and atomic force microscopy (AFM). Both types of double layer structures showed similar broadened absorption patterns in the UV-visible region that were consistent with the fitted spectra following simple linear combination of the single layer absorption spectra of the two materials. In contrast, the surface morphology of double layer structures was dependent on the order of deposition. For the CuPc/SubPc structures, surface morphology was characterized by elongated grains, which are characteristic of SubPc thin films, indicating that the morphological influence of the underlying CuPc layer on the subsequent SubPc layer was not large. For the SubPc/CuPc structures, however, the underlying SubPc layer acted as a morphological template for the subsequently deposited CuPc layer. It was also observed that the grain size of the CuPc layer varied according to the thickness of the underlying SubPc layer.

Improving Impact Resistance of Polymer Concrete Using CNTs

  • Daghash, Sherif M.;Soliman, Eslam M.;Kandil, Usama F.;Taha, Mahmoud M. Reda
    • International Journal of Concrete Structures and Materials
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    • 제10권4호
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    • pp.539-553
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    • 2016
  • Polymer concrete (PC) has been favoured over Portland cement concrete when low permeability, high adhesion, and/or high durability against aggressive environments are required. In this research, a new class of PC incorporating Multi-Walled Carbon Nanotubes (MWCNTs) is introduced. Four PC mixes with different MWCNTs contents were examined. MWCNTs were carefully dispersed in epoxy resin and then mixed with the hardener and aggregate to produce PC. The impact strength of the new PC was investigated by performing low-velocity impact tests. Other mechanical properties of the new PC including compressive, flexural, and shear strengths were also characterized. Moreover, microstructural characterization using scanning electron microscope and Fourier transform infrared spectroscopy of PC incorporating MWCNTs was performed. Impact test results showed that energy absorption of PC with 1.0 wt% MWCNTs by weight of epoxy resin was significantly improved by 36 % compared with conventional PC. Microstructural analysis demonstrated evidence that MWCNTs significantly altered the chemical structure of epoxy matrix. The changes in the microstructure lead to improvements in the impact resistance of PC, which would benefit the design of various PC structural elements.

파장 변조 기법을 이용한 연소배기 가스의 계측 (Measurement of Exhaust Gas Concentration using Wavelength Modulation Spectroscopy)

  • 김동혁;김세원;신명철;김용모
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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    • pp.97-103
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    • 2006
  • This work forcus on the development of gas sensor that measure the concentrations of exhaust gas using diode laser. Each diode laser for exhaust gas measurement is set to work at near-IR using both DA and WMS methods. Also use of fiber-coupled optical elements makes such a sensor rugged and easy to align. On-line data acquisition and processing can be performed with a PC running LabVIEW software, and absorption signals are measured simultaneously by multiplexing method. Finally, It were experimentally compared WMS (Wavelength Modulation Spectroscopy) with DA (Direct Absorption) for the accuracy.

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Synchrotron radiation photoelectron spectroscopy study of oxygen doping effect by oxygen plasma treatment to inverted top emitting organic light emitting diodes

  • Hong, Ki-Hyon;Kim, Ki-Soo;Kim, Sung-Jun;Choi, Ho-Won;Tak, Yoon-Heung;Lee, Jong-Lam
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.118-120
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    • 2009
  • We reported that the evidence of oxygen doping to copper-phthalocyanine (CuPc) by $O_2$-plasma treatment to Au electrode of inverted top emitting organic light emitting diodes (ITOLEDs). The operation voltage of OLEDs at 150 mA/$cm^2$ decreased from 16.1 to 10.3 V as oxygen atoms indiffued to CuPc layer using $O_2$-plasma. Synchrotron radiation photoelectron spectroscopy results showed that a new bond of Cu-O appeared and the energy difference between the highest occupied molecular orbital and $E_F$ is lowered by 0.20 eV after plasma treatment. Thus the hole injection barrier was lowered, reducing the turn-on voltage and increasing the quantum efficiency of OLEDs.

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Binding energy study from Photocurrent signal in $CdGa_2Se4$ layers

  • Lee, Sang-Youl;Hong, Kwang-Joon
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.47-47
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    • 2009
  • The photoconductive $CdGa_2Se4$ layer has been investigated using photocurrent (PC) spectroscopy as a function of temperature. Three peaks corresponding to the band-to-band transitions were observed in the PC spectra for all temperature ranges. Also, contrary to our expectation, the PC intensities decreased with decreasing temperatures. From the relation of log $J_{ph}$ vs 1/T, where $J_{ph}$ is the PC density, two dominant levels by the exponential variation of the PC with varying temperature were observed, one at high temperatures and the other at low temperatures.

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Tunneling Spectra in Organic Cu-Pc/$Bi_2Sr_2CaCu_2O_{8+\delta}$ Tunnel Junctions

  • Kim, Sunmi;E, Jungyoon;Lee, Kiejin;Ishbas, Takayuki;Lee, Yang-San
    • Progress in Superconductivity
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    • 제3권1호
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    • pp.41-44
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    • 2001
  • We report the current transport properties of a normal metal/organic conductor/ superconductor tunnel junction as a novel high- $T_{c}$ superconducting three terminal device. The organic copper (II) phthalocyanine (Cu-Pc) layer was used far a polaronic quasiparticle (QP) injector. The injection of polaronic QP from the Cu-Pc interlayer into a superconductor $Bi_2$$Sr_2$$CaCu_2$ $O_{8+}$ $\delta$/(BSCCO) thin film generated a substantially larger nonequilibrium effect as compared to the normal QP injection current. The tunneling spectroscopy of an Au/cu-PC/BSCCO junction exhibited a zero bias conductance peak which may be due to Andreev reflection at a Cu-Pc/d-wave superconductor junction.n..

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Synthesis and Characterization of KTiNbO5 Nano-particles by Novel Polymerizable Complex Method

  • Wang, Ning-Ning;Lan, Yun-Xiang;He, Jie;Dong, Rui;Hu, Jin-Song
    • Bulletin of the Korean Chemical Society
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    • 제34권9호
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    • pp.2737-2740
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    • 2013
  • The layered $KTiNbO_5$ was successfully synthesized with titanium(IV) isopropoxide and niobium oxalate by a novel polymerized complex (PC) method. The morphology and structure of the as-prepared sample was characterized by means of High-Resolution Transmission Electron Microscope, powder X-ray diffraction, and Laser Raman Spectroscopy. The spectral response characteristic was recorded by using UV-vis Diffuse Reflectance Spectroscopy. Results show that $KTiNbO_5$ as-prepared by PC method presents an uniform morphology of nano-particles, the mean particle sizes is ca. 28 nm corresponding to the (002), and the crystal structure can be well indexed to the orthorhombic phase. The sample as-prepared by PC method has higher band gap energy than that of the sample prepared by a solid-state reaction method due to the quantum size effect.

THE COMBINATION OF CHEMOMETRICS AND 2D NIR CORRELATION SPECTROSCOPY IN THE ANALYSIS OF DENATURATION PROCESS

  • Czarnik-Matusewicz, Boguslawa;Murayama, Koichi;Wu, Yuqing;Ozaki, Yukihiro
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1286-1286
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    • 2001
  • Despite extensive theoretical and experimental studies the structure of the protein-solvent interface is subject of many controversy. Understanding the processes that occur in aqueous solution requires understanding of the solvent influence on the structure of protein. The aim of this study is to investigate the applicability of NIR methods in the study of hydration phenomena in protein solutions. Temperature-induced changes in NIR spectra of -lactoglobulin (BLG) in aqueous solutions have been investigated by means of two-dimensional correlation spectroscopy (2DCOS) and principal component analysis (PCA). With the temperature increase the balance of forces between the BLG's interaction with itself and the BLGs interaction with its environment is disrupted leading to BLG unfolding. Significant differences of 2D signals and distinct discrepancies of loading on PC1 and PC2 were observed as a result of temperature increase. In the native folded conformation of BLC, most of the nonpolar amino acids are hidden in the centre of the structure, out of contact with water molecules, while charged groups are outside, in the contact with water. The polar groups promote low density Ih-type structure in the water outside this first hydration shell. When BLG unfolds it assumes a more extended configuration on which the previously buried nonpolar groups are exposed to water and promote the higher density II-type structure outside its first shell. Detailed assignments of bands attributed to the bulk water, different states of the hydrated water and the changed conformation of BLG are proposed.

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