• Title/Summary/Keyword: PC/A

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Extensional and Complex Viscosities of Linear and Branched Polycarbonate Blends

  • Park, Jung-Hoon;Hyun, Jae-Chun;Kim, Woo-Nyon;Kim, Sung-Ryong;Ryu, Seung-Chan
    • Macromolecular Research
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    • v.10 no.3
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    • pp.135-139
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    • 2002
  • Blends of the linear bisphenol-A polycarbonate (L-PC) and randomly branched bisphenol-A polycarbonate (Br-PC), prepared by co-rotating twin screw extrusion, were investigated using differential scanning calorimetry (DSC), sag resistance time tester, extensional rheometry, and advanced rheometric expansion system (ARES). From the DSC results, the glass transition temperature (T$_{g}$) of the L-PC/Br-PC blend was increased with the increase of Br-PC in the blend, and the blend showed a single T$_{g}$, which suggests a miscible blend. The sag resistance time of the L-PC/Br-PC blend was increased with the increase of Br-PC in the blends. From the results of rheological measurements of the L-PC/Br-PC blends, the extensional viscosity and the complex viscosity of the blends were found to increase with the increase of Br-PC in the blends. The increase of extensional viscosity and complex viscosity was related with the increase of sag resistance time with the Br-PC in the L-PC/Br-PC blends.nds.

Characteristics of Metal-Phthalocyanine for Catalytic Combustion of Methanol (메탄올의 촉매연소에 대한 금속-프탈로시아닌의 특성)

  • Seo, Seong-Gyu;Yoon, Hyung-Sun;Lee, Sun-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.10
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    • pp.1809-1816
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    • 2000
  • The catalytic combustion of methanol as a model volatile organic compound(VOC) was been investigated over metal-phthalocyanine(PC) in a fixed bed flow reactor system. The catalytic activity of Co-PC pretreated with air and methanol mixture at $450^{\circ}C$ and 60 cc/min for 1 hr was very excellent. The order of catalytic activity on methanol combustion was summarized as follows: metal free-PC < Zn-PC < Fe-PC < Cu($\alpha$)-PC < Co-PC. By TG/DTA analysis, the tendency of thermal decomposition was increased as follows: metal free-PC < Zn-PC < Cu($\alpha$)-PC < Co-PC < Fe-PC. Under this pretreatment condition, the basic structures of Co-PC, Cu($\alpha$)-PC and Fe-PC were destroyed, and the new metal oxide such as $Co_3O_4$ from Co-PC was confirmed by EA and XRD analysis. But Zn-PC and metal free-PC were retained its basic structure under this pretreatment condition. On the combustion of methanol over Co-PC, HCHO and $HCOOCH_3$ were observed as an intermediate products in the high concentration of reactant or the short contact time(W/F).

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Growth regulation and Nitrogen Uptake Inhibition of Zoysia matrella Applying Prohexadione Calcium (Prohexadione-calcium 처리에 따른 금잔디의 생육 조절 및 질소 흡수 억제)

  • Kim, Woo-Sung;Kim, Young-Sun;Lim, Chi-Hwan
    • Korean Journal of Environmental Agriculture
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    • v.40 no.4
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    • pp.359-365
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    • 2021
  • BACKGROUND: Prohexadione-calcium (PC) is a plant growth regulator of cyclohexanedione family acting on inhibiting gibberellin biosynthesis and has been used to regulate shoot elongation of turfgrass in the golf course during the summer season. This study was conducted to investigate the effects of PC on the inhibition of shoot elongation, growth, and nitrogen uptake in Zoysia matrella. METHODS AND RESULTS: Treatments were as follows; non-treatment, control (TE 0.01 a.i. g/m2/100 mL), 0.0025PC (PC 0.0025 a.i. g/m2/100 mL), 0.005PC (PC 0.005 a.i. g/m2/100 mL), 0.01PC (PC 0.01 a.i. g/m2/100 mL) and 0.02PC (PC 0.02 a.i. g/m2/100 mL). Visual quality and chlorophyll content were not significantly different. As compared to non-treatment, shoot length and clipping yield in 0.005PC, 0.01PC and 0.02PC treatments were decreased by 29-36% and 65-82%, respectively, and those of 0.0025PC were not significantly different. N uptake of Z. matrella after applying PC was decreased by 28.9-77.8% than that of non-treatment. Inhibition effects of PC treatment in Z. matrella were not significantly different from those of control. CONCLUSION(S): These results indicated that the application of prohexadione calcium inhibited shoot elongation, clipping yield and N uptake amount in Z. matrella, and trinexapac-ethyl could be replaced with prohexadione-calcium in turfgrass management.

Study on the eletronic absorption and surface morphology of phthalocyanine double layer thin films

  • Heo, Il-Su;Ryu, Il-Hwan;Hong, Da-Jeong;Im, Sang-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.337-337
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    • 2011
  • The elecronic absorption and surface morphology evolution of two types of molecular double layer thin films, copper phthalocyanine(CuPc) layer deposited on top of chloro[subphtalocyaninato]boron(III) (SubPc) layer, denoted as SubPc/CuPc, and vice versa, at various thicknesses were invertigated using ultraviolet(UV)-visible spectroscopy and atomic force microscopy (AFM). Both types of double layer structures showed similar broadened absorption patterns in UV-visible region which were well consistent with fitted spectra by a simple linear combination of single layer absorption spectra of two materials. In contrast, the surface morphology of double layer structures was dependent on the order of deposition. For CuPc/SubPc structures, the surface morphology was characterized by elongated grains, characteristic of SubPc thin films, indicating the morphological influence of underlying CuPc layer on subsequent SubPc layer was not large. For SubPc/CuPc structures, however, the underlying SubPc layer acted as a morphological template for the subsequently deposited CuPc layer. It was also observed that the grain size of CuPc layer varied by the thickness of underlying SubPc layer.

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A Basic Study of Crane Trajectory Distance Calculation for Sustainable PC Members Erection of Large Logistic Building (대형물류센터 PC부재 양중을 위한 크레인 궤적거리 산정 기초 연구)

  • Lim, Jeeyoung;Oh, Jinhyuk;Kim, Sunkuk
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.77-78
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    • 2023
  • As large logistics buildings have high floor heights and long spans, these buildings are designed as PC structures, and large cranes are used to lift PC members. PC erection planning can generally cause errors depending on the field engineer's experience. To solve this problem, a basic analysis method is needed to establish a systematic PC member erection plan. Crane work can be minimized if the trajectory is easily and quickly calculated according to the location of the crane and applied to the site. Therefore, the objective of this study is a basic study of crane trajectory distance calculation for sustainable PC members erection of large logistic building. In this study, a crawler crane commonly used for lifting PC members is limited. The trajectory distance for the PC erection plan was automatically calculated using the algorithm.

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A Study on the Relationship between PC Use and Playfulness (PC 이용과 놀이성(playfulness)의 관계에 대한 연구)

  • Baek, Sang-Yong
    • Asia pacific journal of information systems
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    • v.10 no.4
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    • pp.101-113
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    • 2000
  • This study deals with the concept of Microcomputer Playfulness(MCP), Even though MCP was introduced recently in the MIS research, the concept is expected and empirically supported to be significant in explaining information technology adoption and usage. Based on the Technology Acceptance Model(TAM), this study presented a revised model to explain individual PC use and explored the role of MCP in PC use. The results showed that MCP has a direct influence on PC use rather than a mediator between Self-efficacy and PC use, and that MCP is a better predictor of PC use than Computer Anxiety.

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Solvent Extraction for the Separation of Gd and Nd from Chloride Solution with PC88A and Saponified PC88A (염산용액(鹽酸溶液)에서 PC88A와 비누화 PC88A에 의한 Gd와 Nd의 분리추출(分離抽出))

  • Lee, Man-Seung;Lee, Jin-Young;Kim, Joon-Soo
    • Resources Recycling
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    • v.17 no.1
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    • pp.12-19
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    • 2008
  • Solvent extraction experiments have been performed to separate Gd and Nd from chloride solution with PC88A and saponified PC88A. In the experimental ranges conducted in this study, the extraction percentage of Gd was higher than that of Nd. Use of 40% saponified PC88A increased the distribution coefficients of Gd and Nd. A chemical model was developed to predict the distribution coefficients of the two metals from the initial extraction conditions. The measured distribution coefficients of Gd and Nd with PC88A and saponified PC88A agreed well with those calculated in this study.

Electrical Properties of Organic Photovoltaic Cell using CuPc/$C_{60}$ double layer (CuPc/$C_{60}$ 이중층을 이용한 유기 광기전 소자의 전기적 특성)

  • Lee, Dong-Shin;Park, Yong-Pil
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2008.05a
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    • pp.744-746
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    • 2008
  • Organic photovoltaic effects were studied in a device structure of ITO/CuPc/Al and ITO/CuPc/$C_{60}$/BCP/Al. A thickness of CuPc layer was varied from 10 nm to 50 nm, we have obtained that the optimum CuPc layer thickness is around 40 nm from the analysis of the current density-voltage characteristics in CuPc single layer photovoltaic cell. From the thickness-dependent photovoltaic effects in CuPc/$Cu_{60}$ heterojunction devices, higher power conversion efficiency was obtained in ITO/20nm CuPc/40nm $C_{60}$/Al, which has a thickness ratio (CuPc:$C_{60}$) of 1:2 rather than 1:1 or 1:3. Light intensity on the device was measured by calibrated Si-photodiode and radiometer/photometer of International Light Inc(IL14004).

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Electrical Properties of Organic Photovoltaic Cell using CuPc (CuPc를 이용한 유기 광기전 소자의 전기적 특성)

  • Lee, Ho-Shik;Park, Yong-Pil
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2008.10a
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    • pp.612-614
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    • 2008
  • Organic photovoltaic effects were studied in a device structure of ITO/CuPc/Al and ITO/CuPc/$C_{60}$/BCP/Al. A thickness of CuPc layer was varied from 10nm to 50nm, we have obtained that the optimum CuPc layer thickness is around 40nm from the analysis of the current density-voltage characteristics in CuPc single layer photovoltaic cell. From the thickness-dependent photovoltaic effects in CuPc/$C_{60}$ heterojunction devices, higher power conversion efficiency was obtained in ITO/20nm CuPc/40nm $C_{60}$/Al, which has a thickness ratio (CuPc:$C_{60}$) of 1:2 rather than 1:1 or 1:3. Light intensity on the device was measured by calibrated Si-photodiode and radiometer/photometer of International Light Inc(IL14004).

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Influence of Cracks in Precast Concrete Deck on the Flexural Strength of Composite Half PC Slab (하프PC 슬래브에 발생한 균열이 합성 슬래브의 휨 내력에 미치는 영향에 관한 실험적 연구)

  • Seo, Tae-Seok;Lee, Moon-Sung;Choi, Chang-Sik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.2 s.54
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    • pp.199-205
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    • 2009
  • Recently, as the concern for the development of a construction method for an environmental protection and for tall building is increasing, the use of the half precast concrete(PC) slab that has the solution of environmental problems and the advantage such as reduction of construction period is being demanded. However, there is shortcoming that the crack can occur easily while constructing, and these cracks can have a bad influence upon the structural performance of PC composite slab. However, there is little studies on the influence of these cracks on the structural performance of composite PC slab. In this study, the specimen caused the crack before pouring topping concrete in the half PC slab and the PC composite slab without the cracks were produced to investigate the structural performance of PC composite slab with crack.