• 제목/요약/키워드: PC/A

검색결과 9,444건 처리시간 0.047초

Extensional and Complex Viscosities of Linear and Branched Polycarbonate Blends

  • Park, Jung-Hoon;Hyun, Jae-Chun;Kim, Woo-Nyon;Kim, Sung-Ryong;Ryu, Seung-Chan
    • Macromolecular Research
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    • 제10권3호
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    • pp.135-139
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    • 2002
  • Blends of the linear bisphenol-A polycarbonate (L-PC) and randomly branched bisphenol-A polycarbonate (Br-PC), prepared by co-rotating twin screw extrusion, were investigated using differential scanning calorimetry (DSC), sag resistance time tester, extensional rheometry, and advanced rheometric expansion system (ARES). From the DSC results, the glass transition temperature (T$_{g}$) of the L-PC/Br-PC blend was increased with the increase of Br-PC in the blend, and the blend showed a single T$_{g}$, which suggests a miscible blend. The sag resistance time of the L-PC/Br-PC blend was increased with the increase of Br-PC in the blends. From the results of rheological measurements of the L-PC/Br-PC blends, the extensional viscosity and the complex viscosity of the blends were found to increase with the increase of Br-PC in the blends. The increase of extensional viscosity and complex viscosity was related with the increase of sag resistance time with the Br-PC in the L-PC/Br-PC blends.nds.

메탄올의 촉매연소에 대한 금속-프탈로시아닌의 특성 (Characteristics of Metal-Phthalocyanine for Catalytic Combustion of Methanol)

  • 서성규;윤형선;이선원
    • 대한환경공학회지
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    • 제22권10호
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    • pp.1809-1816
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    • 2000
  • 본 연구는 상압유통식 반응장치를 이용하여 석유화학공단에서 주로 발생되는 휘발성 유기화합물(volatile organic compound: VOC) 인 methanol의 연소에 대한 다양한 금속-프탈로시아닌의 촉매활성에 관하여 연구하였다. Co-PC의 촉매활성은 air+methanol의 혼합물을 이용하여 전처리한 경우가 air만으로 전처리한 경우보다 더 높았으며, 금속-PC의 촉매활성은 metal free-PC < Zn-PC < Fe-PC < Cu($\alpha$)-PC < Co-PC의 순서 였다. TG/DTA 분석 결과, 금속-PC 의 열분해 용이 성은 metal free-PC < Zn-PC < Cu($\alpha$)-PC < Co-PC < Fe-PC의 순서로 나타었으며, 금속과 프탈로시아닌의 결합특성에 따른 차이로 판단된다. XRD 및 EA 분석결과, 전처리한 후의 Zn-PCS와 metal free-PC는 원래의 결정구조가 거의 유지되었지만, Co-PC, Cu($\alpha$)PC 및 Fe-PC는 원래의 결정구조가 파괴되는 것으로 나타났다. 전처리한 후의 Co-PC는 금속산화물인 $Co_3O_4$의 형태로 존재하였으며, Co-PC의 촉매활성이 가장 우수하였다. Co-PC 상에서 methanol의 촉매연소는 반응물의 농도가 높거나 접촉시간(W/F)이 짧을 경우, 중간생성물로서 HCHO 및 $HCOOCH_3$가 관찰되었다.

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Prohexadione-calcium 처리에 따른 금잔디의 생육 조절 및 질소 흡수 억제 (Growth regulation and Nitrogen Uptake Inhibition of Zoysia matrella Applying Prohexadione Calcium)

  • 김우성;김영선;임치환
    • 한국환경농학회지
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    • 제40권4호
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    • pp.359-365
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    • 2021
  • BACKGROUND: Prohexadione-calcium (PC) is a plant growth regulator of cyclohexanedione family acting on inhibiting gibberellin biosynthesis and has been used to regulate shoot elongation of turfgrass in the golf course during the summer season. This study was conducted to investigate the effects of PC on the inhibition of shoot elongation, growth, and nitrogen uptake in Zoysia matrella. METHODS AND RESULTS: Treatments were as follows; non-treatment, control (TE 0.01 a.i. g/m2/100 mL), 0.0025PC (PC 0.0025 a.i. g/m2/100 mL), 0.005PC (PC 0.005 a.i. g/m2/100 mL), 0.01PC (PC 0.01 a.i. g/m2/100 mL) and 0.02PC (PC 0.02 a.i. g/m2/100 mL). Visual quality and chlorophyll content were not significantly different. As compared to non-treatment, shoot length and clipping yield in 0.005PC, 0.01PC and 0.02PC treatments were decreased by 29-36% and 65-82%, respectively, and those of 0.0025PC were not significantly different. N uptake of Z. matrella after applying PC was decreased by 28.9-77.8% than that of non-treatment. Inhibition effects of PC treatment in Z. matrella were not significantly different from those of control. CONCLUSION(S): These results indicated that the application of prohexadione calcium inhibited shoot elongation, clipping yield and N uptake amount in Z. matrella, and trinexapac-ethyl could be replaced with prohexadione-calcium in turfgrass management.

Study on the eletronic absorption and surface morphology of phthalocyanine double layer thin films

  • 허일수;류일환;홍다정;임상규
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.337-337
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    • 2011
  • The elecronic absorption and surface morphology evolution of two types of molecular double layer thin films, copper phthalocyanine(CuPc) layer deposited on top of chloro[subphtalocyaninato]boron(III) (SubPc) layer, denoted as SubPc/CuPc, and vice versa, at various thicknesses were invertigated using ultraviolet(UV)-visible spectroscopy and atomic force microscopy (AFM). Both types of double layer structures showed similar broadened absorption patterns in UV-visible region which were well consistent with fitted spectra by a simple linear combination of single layer absorption spectra of two materials. In contrast, the surface morphology of double layer structures was dependent on the order of deposition. For CuPc/SubPc structures, the surface morphology was characterized by elongated grains, characteristic of SubPc thin films, indicating the morphological influence of underlying CuPc layer on subsequent SubPc layer was not large. For SubPc/CuPc structures, however, the underlying SubPc layer acted as a morphological template for the subsequently deposited CuPc layer. It was also observed that the grain size of CuPc layer varied by the thickness of underlying SubPc layer.

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대형물류센터 PC부재 양중을 위한 크레인 궤적거리 산정 기초 연구 (A Basic Study of Crane Trajectory Distance Calculation for Sustainable PC Members Erection of Large Logistic Building)

  • 임지영;오진혁;김선국
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 봄 학술논문 발표대회
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    • pp.77-78
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    • 2023
  • As large logistics buildings have high floor heights and long spans, these buildings are designed as PC structures, and large cranes are used to lift PC members. PC erection planning can generally cause errors depending on the field engineer's experience. To solve this problem, a basic analysis method is needed to establish a systematic PC member erection plan. Crane work can be minimized if the trajectory is easily and quickly calculated according to the location of the crane and applied to the site. Therefore, the objective of this study is a basic study of crane trajectory distance calculation for sustainable PC members erection of large logistic building. In this study, a crawler crane commonly used for lifting PC members is limited. The trajectory distance for the PC erection plan was automatically calculated using the algorithm.

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PC 이용과 놀이성(playfulness)의 관계에 대한 연구 (A Study on the Relationship between PC Use and Playfulness)

  • 백상용
    • Asia pacific journal of information systems
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    • 제10권4호
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    • pp.101-113
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    • 2000
  • This study deals with the concept of Microcomputer Playfulness(MCP), Even though MCP was introduced recently in the MIS research, the concept is expected and empirically supported to be significant in explaining information technology adoption and usage. Based on the Technology Acceptance Model(TAM), this study presented a revised model to explain individual PC use and explored the role of MCP in PC use. The results showed that MCP has a direct influence on PC use rather than a mediator between Self-efficacy and PC use, and that MCP is a better predictor of PC use than Computer Anxiety.

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염산용액(鹽酸溶液)에서 PC88A와 비누화 PC88A에 의한 Gd와 Nd의 분리추출(分離抽出) (Solvent Extraction for the Separation of Gd and Nd from Chloride Solution with PC88A and Saponified PC88A)

  • 이만승;이진영;김준수
    • 자원리싸이클링
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    • 제17권1호
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    • pp.12-19
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    • 2008
  • Gd와 Nd이 혼합된 염산용액에서 PC88A와 비누화 PC88A에 의한 용매추출실험을 하였다. 본 연구에서 수행한 실험조건에서 H88A에 의해 Gd이 Nd보다 추출이 잘 되었으며, 40% 비누화된 H88A를 사용하여 Gd와 Nd의 분배계수가 증가하였다. PC88A와 비누화 PC88A에 의한 추출시 초기추출조건으로부터 Gd와 Nd의 분배계수를 예측할 수 있는 모델을 개발하였다. 본 연구에서 개발된 모델을 초기추출조건에 적용하여 예측한 Gd와 Nd의 분배계수는 실험으로 측정한 값과 서로 잘 일치하였다

CuPc/$C_{60}$ 이중층을 이용한 유기 광기전 소자의 전기적 특성 (Electrical Properties of Organic Photovoltaic Cell using CuPc/$C_{60}$ double layer)

  • 이호식;박용필
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2008년도 춘계종합학술대회 A
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    • pp.744-746
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    • 2008
  • Organic photovoltaic effects were studied in a device structure of ITO/CuPc/Al and ITO/CuPc/$C_{60}$/BCP/Al. A thickness of CuPc layer was varied from 10 nm to 50 nm, we have obtained that the optimum CuPc layer thickness is around 40 nm from the analysis of the current density-voltage characteristics in CuPc single layer photovoltaic cell. From the thickness-dependent photovoltaic effects in CuPc/$Cu_{60}$ heterojunction devices, higher power conversion efficiency was obtained in ITO/20nm CuPc/40nm $C_{60}$/Al, which has a thickness ratio (CuPc:$C_{60}$) of 1:2 rather than 1:1 or 1:3. Light intensity on the device was measured by calibrated Si-photodiode and radiometer/photometer of International Light Inc(IL14004).

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CuPc를 이용한 유기 광기전 소자의 전기적 특성 (Electrical Properties of Organic Photovoltaic Cell using CuPc)

  • 이호식;박용필
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2008년도 추계종합학술대회 B
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    • pp.612-614
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    • 2008
  • Organic photovoltaic effects were studied in a device structure of ITO/CuPc/Al and ITO/CuPc/$C_{60}$/BCP/Al. A thickness of CuPc layer was varied from 10nm to 50nm, we have obtained that the optimum CuPc layer thickness is around 40nm from the analysis of the current density-voltage characteristics in CuPc single layer photovoltaic cell. From the thickness-dependent photovoltaic effects in CuPc/$C_{60}$ heterojunction devices, higher power conversion efficiency was obtained in ITO/20nm CuPc/40nm $C_{60}$/Al, which has a thickness ratio (CuPc:$C_{60}$) of 1:2 rather than 1:1 or 1:3. Light intensity on the device was measured by calibrated Si-photodiode and radiometer/photometer of International Light Inc(IL14004).

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하프PC 슬래브에 발생한 균열이 합성 슬래브의 휨 내력에 미치는 영향에 관한 실험적 연구 (Influence of Cracks in Precast Concrete Deck on the Flexural Strength of Composite Half PC Slab)

  • 서태석;이문성;최창식
    • 한국구조물진단유지관리공학회 논문집
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    • 제13권2호통권54호
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    • pp.199-205
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    • 2009
  • 하프PC 슬래브는 시공중에 슬래브 판에 균열이 발생하기 쉽고 이러한 균열들을 보수보강 하지 않은 상태에서 덧침콘크리트를 타설할 경우 합성슬래브의 내력에 영향을 미칠 것으로 사료된다. 하지만 하프PC 슬래브에 발생한 균열이 합성슬래브의 구조성능에 미치는 영향에 관한 연구는 아직까지 없는 실정이다. 따라서 본 연구에서는 하프PC 슬래브에 발생한 균열이 합성 슬래브의 내력에 미치는 영향을 조사하기 위하여 덧침 콘크리트를 타설하기 전에 하프PC 슬래브에 균열을 발생시킨 시험체와 균열이 없는 합성슬래브 시험체를 제작하여 슬래브의 휨 성능을 검토하였다.