• Title/Summary/Keyword: PAN (polyacrylonitrile)

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Enhanced Fiber Structure of Carbonized Cellulose by Purification (정제 과정에 의한 탄화 셀룰로오스 섬유 구조의 증가)

  • Kim, Bong Gyun;Sohng, Jae Kyung;Liou, KwnagKyoung;Lee, Hei Chan
    • Applied Chemistry for Engineering
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    • v.16 no.2
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    • pp.257-261
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    • 2005
  • The microbial cellulose is in a form of three dimensional net structures that consists of 20~50 nm fibrils. It possesses high crystallinity and orientation. It is difficult to synthesize large amount of fibrous carbon nanomaterials by the carbonization process using raw materials such as polyacrylonitrile (PAN), regenerated cellulose (Rayon) and pitch. However, it seems possible thru the application of microbial cellulose as raw material. The application of such cellulose can be further extended to the synthesis of highly oriented graphite fiber. Out of three different cellulose-producing strains, G. xylinus ATCC11142 was chosen as it has the highest productivity (0.066 g dried cellulose/15 mL medium). Tar is often produced during the carbonization of cellulose that limits the formation fibrous structure of the carbonized sample. In order to solve such a problem, pre-studied purification methods of carbon nanotube such as liquid phase oxidation, gas phase oxidation and filtration associated with ultrasonication were applied at the carbonized cellulose. In that case. only by filtration associated with ultrasonication, improved the formation of fiber structure of the carbonized cellulose.