• 제목/요약/키워드: PAHs (polycyclic aromatic hydrocarbons)

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국외논문정보 - 직업적인 PAHs 노출과 폐암 위험 : 유럽의 multicenter 연구를중심으로 (Occupational exposure to polycyclic aromatic hydrocarbons and lung cancer risk : a multicenter study in Europe)

  • Olsson, Ann C.; Fevotte, Joelle;Fletcher, Tony;Cassidy, Adrian;Mannetje, Andrea't;Zaridze, David;Szeszenia-Dabrowska, Neonila;Rudnai, Peter;Lissowska, Jolanta;Fabianova, Eleonora;Mates, Dana;Bencko, Vladimir;Foretova, Lenka;Janout, Vladimir;Brennan, Paul;Boffetta, Paolo
    • 월간산업보건
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    • 통권265호
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    • pp.44-51
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    • 2010
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국내 도로 노면 퇴적입자 내 PAHs의 인체 위해성 평가 (Human Health Risk Assessment of Polycyclic Aromatic Hydrocarbons (PAHs) from Road Dust Sediments in Korea)

  • 이가인;김홍경;지승민;장용철
    • 환경영향평가
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    • 제29권4호
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    • pp.286-297
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    • 2020
  • 본 연구에서는 국내 4개 도시(6개 지점)로부터 도로 노면 퇴적입자 내 PAHs의 농도 및 분포특성을 비교, 분석하고 오염 수준에 대한 초과 발암 위해도를 산정하여 인체 위해성 평가를 수행하였다. 지역별 오염농도를 바탕으로 흡입, 섭취, 피부 노출에 대한 노출경로를 설정하여 결정론적 위해성평가를 수행한 결과, 울산 지역의 경우 위해도 발암 기준 1×10-6을 상회하는 결과가 나타났다. 또한 발암위해도가 있다고 판단되는 해당 지역에 대한 확률론적 위해성평가 결과, 확률적 평균값이 단일값을 활용한 결정론적 위해도 산정에서 도출되었던 발암위해도와 중앙값에 근접한 수준을 나타내었다. 민감도 분석 결과, 노출시간에 따른 기여도가 가장 크게 나타났다. 향후 기준치를 초과하는 발암 위해도를 나타내는 지역에 대한 위해도 관리는 물론 상세한 모니터링을 통한 추가 위해성 평가가 이루어져야 할 것으로 판단되며, 지역적 특성을 반영한 노출계수의 산정을 통해 인체 위해도 평가 결과 신뢰도를 높여야 할 것으로 사료된다.

서울지역 대기 중 다환방향족탄화수소의 발생원별 기여도 평가 (Contributive Estimation of Polycyclic Aromatic Hydrocarbons by Emission Source in Seoul Area)

  • 박찬구;윤중섭;어수미;신정식;김민영;손종열;모세영
    • 한국대기환경학회지
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    • 제22권3호
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    • pp.287-295
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    • 2006
  • PAHs (Polycyclic Aromatic Hydrocarbons), one of the carcinogenic materials in environment, were investigated in this study. The standardized analysis conditions were tested, and then various factors which affect to the ambient PAHs concentration in Seoul were estimated. Moreover, the emissions of PAHs from major stationary sources were investigated to determine the quantitative relationships between ambient PAHs concentrations and emission sources. From the factor analysis, three factors relevant to the ambient PAHs in Seoul were found. Factor 1 was related to the concentrations of chrysene, pyrene, indeno (1, 2, 3-cd)pyrene, benzo[b]fluoranthene, benzo[k]fluoranthene, and benzo prerylene which were mainly emitted from gasoline and diesel fueled cars. Factor 2 showed higher loadings in phenanthrene and anthracene which were due to LNG and BC oil combustion in industry and home. And factor 3 included dibenz(a, h)anthracene and acenaphthene which were emitted from open burning and municipal solid waste incineration. Conclusively, all of three factors were consisted in 82% of total variance. The contribution of mobile sources in ambient air in Seoul was estimated at 64%, that of industrial and home sources at 17%, and that of open burning and municipal incineration at 1%.

Diurnal Variation, Vertical Distribution and Source Apportionment of Carcinogenic Polycyclic Aromatic Hydrocarbons (PAHs) in Chiang-Mai, Thailand

  • Pongpiachan, Siwatt
    • Asian Pacific Journal of Cancer Prevention
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    • 제14권3호
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    • pp.1851-1863
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    • 2013
  • Diurnal variation of particulate polycyclic aromatic hydrocarbons (PAHs) was investigated by collecting PM10 at three different sampling altitudes using high buildings in the city center of Chiang-Mai, Thailand, during the relatively cold period in late February 2008. At site-1 (12 m above ground level), B[a]P concentrations ranged from 30.3-1,673 pg $m^{-3}$ with an average of $506{\pm}477\;pg\;m^{-3}$ contributing on average, $8.09{\pm}8.69%$ to ${\Sigma}PAHs$. Ind and B[b]F concentrations varied from 54.6 to 4,579 pg $m^{-3}$ and from 80.7 to 2,292 pg $m^{-3}$ with the highest average of $1,187{\pm}1,058\;pg\;m^{-3}$ and $963{\pm}656\;pg\;m^{-3}$, contributing on average, $19.0{\pm}19.3%$ and $15.4{\pm}12.0%$ to ${\Sigma}PAHs$, respectively. Morning maxima were predominantly detected in all observatory sites, which can be described by typical diurnal variations of traffic flow in Chiang-Mai City, showing a morning peak between 6 AM. and 9 AM. Despite the fact that most monitoring sites might be subjected to specific-site impacts, it could be seen that PAH profiles in Site-1 and Site-2 were astonishingly homogeneous. The lack of differences suggests that the source signatures of several PAHs become less distinct possibly due to the impacts of traffic and cooking emissions from ground level.

Estimation of polycyclic aromatic hydrocarbons emission from sewage sludge of sewerage treatment plants in Korea

  • Kim, Dong-Hwan;Hwang, Jong-Seob;Lee, Min-Hee;Ok, Gon
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2003년도 International Symposium on Clean Environment
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    • pp.85-88
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    • 2003
  • Polycyclic aromatic hydrocarbons (PARs) are an important group of organic contaminants present in sewage sludge, due to their persistence, toxic, bioaccumulative and long range transfer. These characters make themselves as Persistent Organic Pollutants(POPs) in Long Range Transboundary Air Pollutions convention(LRT AP) of Europe. A method of the gas chromatographic-mass spectrometric (GC-MS) determination of PARs present in sewage sludge was developed and applied to analyzed samples from five sewerage treatment plants (SWTPs), having different treatment types. PARs were extracted from freeze-dried samples by toluene 16 hours in a soxhlet extraction system. The sludge extracts were cleaned-up by an activated silica gel column chromatography. The sum of the 16 US Environmental Protection Agency PARs sewage sludge samples varied from 2.44 to 4.82 ${\mu}g$/g. Concentration of emission carcinogen PARs(PARcarc), such as Benzo(a)anthracene, Benzo(b)fluoranthene, Benzo(k)fluoranthene, Benzo(a)pyrene, Dibenzo(a, h)anthracene and Indeno(1, 2, 3-cd)pyrene ranged from 0.62 to 1.03 ${\mu}g$/g. The total amount of PAHs emission from sewage sludge in Korea was calculated as a top-down approach. PARs and $\sum$PAHcarc from sewage treatment plants had several pathway each by-products. In the ocean dumping, PAHs and $\sum$PAHcarc emissions were 1155.95 kg/year and 5040.32 kg/year. In recycle, PAHs and $\sum$PAHcarc emissions were 98.36 kg/year and 428.87 kg/year. In the landfill, PAHs and $\sum$PAHcarc emissions were 190.40 kg/year and 830.21 kg/year. In the incineration, PAHs and $\sum$PAHcarc emission were 33.10 kg/year and 830.21 kg/year. (In case of incineration, the whole provisions of PARs and $\sum$PAHcarc contained to flowed in sludge was supposed to be exhausted to environment through exhaust after incineration.)

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Hebei Spirit호 유류유출 사고 이후 태안 양식어장에서 잔존유류의 농도 변화 (Variation in the Residual Oils in the Culture Grounds on the Taean Coast, Korea after the Hebei Spirit Oil Spill)

  • 김형철;이완석;황운기;최용석
    • 한국수산과학회지
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    • 제43권6호
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    • pp.705-714
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    • 2010
  • The residual oil concentrations in seawater and sediments were investigated along the Taean coast of Korea, following the Hebei Spirit oil spill, which occurred on 7 December 2007. The oil concentration in seawater ranged from 0.059 to $0.866\;{\mu}g/L$ for the tidal flat culture grounds and from 0.016 to $0.943\;{\mu}g/L$ in the fish cage areas in 2008. These were dominated by the seawater temperature relationship. Polycyclic aromatic hydrocarbons (PAHs) in sediments were also analyzed and the concentrations ranged from 3.4 to 509.7 ng/g dry weight. The average PAH level was higher in seawater from the Sinduri area than the Padori area, while the average PAH level in sediments was higher in Padori. The diagnostic ratio of PAHs was investigated to determine the origins of the PAHs. The PAHs in the Seongam area, which was not affected by the oil spill, are of pyrolytic origin, while the PAHs in Padori and Sinduri were of petrogenic origin. The residual oils in the areas affected by the oil spill tended to decrease over time, except in summer. The oils in pore water remained 6- to 16-fold higher, as compared to the seawater overlying the tidal flat, implying that residual oils will continue to influence the affected region for the foreseeable future.