• Journal of Korean Society of Environmental Engineers
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• v.30 no.8
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• pp.775-780
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• 2008

Sludge conditioning is widely used to improve aggregation and dewaterability of waste sludge in sludge treatment processes. The study aims to examine quantitative correlations between coagulant dosage and sludge cake dewaterability using three kinds of coagulants, such as an aluminum sulfate, a ferric chloride, and a poly aluminum chloride(PAC). When an aluminum sulfate, a ferric chloride, and a PAC were injected with 0.79$\sim$1.19 mmol/g, 0.61$\sim$1.25 mmol/g TSS, and 0.21$\sim$0.39 mmol/g TSS, respectively, specific resistances to filtration of the sludge were decreased at 95.0% or more. This study shows that the correlation between coagulant dosage per g sludge(D) and normalized specific resistance to filtration(R) could be expressed by the exponential functions.

• Journal of the Korean Society for Environmental Technology
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• v.19 no.6
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• pp.563-569
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• 2018

The efficiency of wastewater treatment using microalgae was investigated in this study, focusing on nutrients and flocculation. In the experiments for reducing nutrients by incubation of microalgae, the total phosphorus and total nitrogen were removed over 92 % and 99 %, respectively. The higher flocculation rates as the average values 94% of Poly Aluminum Chloride(PAC) and 92 % of $FeCl_3$ were presented for the flocculation experiments under the conditions of Auto-flocculation and various additives. Also, the optimal(minimal) concentrations for over 90 % of flocculation were 30 mg/L and 40 mg/L for PAC and $FeCl_3$, respectively.

• Journal of Environmental Science International
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• v.22 no.10
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• pp.1353-1361
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• 2013

The objectives of this paper are the characterization of the pretreatment of wastewater by microfiltration (MF) membranes for river maintenance and water recycling. This is done by investigation of the proper coagulation conditions, such as the types and doses of coagulants, mixing conditions (velocity gradients and mixing periods), pH, etc., using jar tests. The effluent water from a pore control fiber (PCF) filter located after the secondary clarifier at Kang-byeon Sewage Treatment Plant (K-STP) was used in these experiments. Two established coagulants, aluminum sulfate (Alum) and poly aluminum chloride (PAC), which are commonly used in sewage treatment plants to treat drinking water, were used in this research. The results indicate that the optimal coagulation velocity gradients (G) and agitation period (T) for both Alum and PAC were 200-250 $s^{-1}$ and 5 min respectively, but the coagulation efficiencies for both Alum and PAC were lower at low values of G and T. For a 60 min filtration period on the MF, the flux efficiencies ($J/J_0$ (%)) at the K-STP effluent that were coagulated by PAC and Alum were 92.9 % and 79.9 %, respectively, under the same coagulation conditions. It is concluded that an enhanced membrane process is possible by effective filtration of effluent at the K-STP using the coagulation-membrane separation process.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.7
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• pp.385-390
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• 2017

This study investigated removal characteristic of soluble Cs in water by RPT (Radioactivity pollutant treatment) with coagulation and sedimentation. The RPT conducted with various chemical and natural coagulants to remove the soluble Cs which consisted pre-adsorption, Sedimentation and post-adsorption. Natural absorbent included Illite and zeolite. Especially, Illite divided LPI (Large Particle Illite) and SPI (Small Particle Illite) by grain size. Also, Chemical coagulants included high basicity PAC (poly aluminum chloride). The adsorbent had a plate structure mainly composed of quartz, albite and muscovite. The surface area were $4.201m^2/g$ and $4.227m^2/g$ and the particle sizes were $197.4-840.9{\mu}m$ and $3.28-53.57{\mu}m$, respectively. The adsorption efficiency of the natural Illite was 82.8% for LPI and 85.6% for SPI. The removal efficiency of turbidity, which was an indirect indicator of adsorbent recovery, was 96.4% and 98.3%, respectively.

• Journal of Korean Society of Water and Wastewater
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• v.29 no.2
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• pp.193-202
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• 2015

The determining the appropriate dosage of coagulant is very important, because dosage of coagulant in the coagulation process for wastewater affects removing the amount of pollutants, cost, and producing sludge amount. Accordingly, in this study, in order to determine the optimal PAC dosage in the coagulation process, CCD (Central composite design) was used to proceed experimental design, and the quadratic regression models were constructed between independent variables (pH, influent turbidity, PAC dosage) and each response variable (Total coliform, E.coli, PSD (Particle size distribution) (< $10{\mu}m$), TP, $PO_4$-P, and $COD_{cr}$) by the RSM (Response surface methodology). Also, Considering the various response variables, the optimum PAC dosage and range were derived. As a result, in order to maximize the removal rate of total coliform and E.coli, the values of independent variables are the pH 6-7, the influent turbidity 100-200 NTU, and the PAC dosage 0.07-0.09 ml/L. For maximizing the removal rate of TP, $PO_4$-P, $COD_{cr}$, and PSD(< $10{\mu}m$), it is required for the pH 9, the influent turbidity 200-250 NTU, and the PAC dosage 0.05-0.065 ml/L. In the case of multiple independent variables, when the desirable removal rate for total coliform, E.coli, TP, and $PO_4$-P is 90-100 % and that for $COD_{cr}$ and PSD(< $10{\mu}m$) is 50-100 %, the required PAC dosage is 0.05-0.07 ml/L in the pH 9 and influent turbidity 200-250 NTU. Thus, if the influent turbidity is high, adjusting pH is more effective way in terms of cost since a small amount of PAC dosage is required.

• Journal of Environmental Health Sciences
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• v.38 no.2
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• pp.128-135
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• 2012

Objectives: This study was aimed at determining the optimum coagulation dosage in a high turbid kaolin water sample using streaming current detection (SCD) as an alternative to the jar test. Methods: SCD is able to optimize coagulant dosing by titration of negatively charged particles. Kaolin particles were used to mimic highly turbid water ranging from 50 to 600 NTU, and polyaluminum chloride (PAC, 17%) was applied as a titrant and coagulant. The coagulation consisted of rapid stirring (5 min at 140 rpm), reduced stirring (20 min at 70 rpm), and settling (60 min). To confirm the coagulation effect, a jar test was also compared with the SCD titration results. Results: SCD titration of kaolin water samples showed that the dose of PAC increased as the pH rose. However, supernatant turbidity less than 1 NTU after coagulation was not achieved for high turbid water by SCD titration. Instead, a conversion factor was used to calculate the optimum PAC dosage for high turbid water by correlating a jar test result with that from an SCD titration. Using this approach, we were able to successfully achieve less than 1 NTU in treated water. Conclusions: For high turbid water influent in a water treatment plant, particularly during summer, the application of SCD control by applying a conversion factor can be more useful than a jar test due to the rapid calculation of coagulation dosage. Also, the interpolation of converted PAC dose could successfully achieve turbidity in the treated water of less than 1 NTU. This result indicates that an SCD system can be effectively used in a water treatment plant even for high turbid water during the rainy season.

• Journal of Environmental Health Sciences
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• v.23 no.3
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• pp.109-120
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• 1997

The purpose of this study is to evaluate the effectiveness of wastewater treatment containing surfactant. For that, comparative analysis of effectiveness of Featon Oxidation, Aluminum Sulfate, PAC (Poly Aluminum Chloride) on the treatment of the synthetic wastewater containing LAS (Linear Alkyl Sulfate), a main component of the commercial detergent was carried. Then, the optimum pH, the dosage of reagents, and the concentration of the LAS in each treatment were determined. The results of the study were summarized as following. 1. In Fenton Oxidation, optimal pH was 3 and 97.92% removal of LAS was achieved. However, the increase of the pH reduced the efficiency of LAS removal. The proper chemical dosages of FeSO$_4$ and $H_2O_2$ were 300 mg/l and the increase of dosages didn't affected the removal efficiency. Therefore, it was concluded that the economic chemical dosage was 300 mg/l of FeSO$_4$ and $H_2O_2$. 2. In case of Alum treatment, optimal pH was 11 with 61.13% removal efficiency. At other pH range, the removal efficiency was very low indicating that removal efficiency is greatly influenced by pH. The proper chemical dosage was 200 mg/l with the removal efficiency of 77.65%. The increase of chemical dosage, however, reduced the removal efficiency. 3. In case of using PAC, optimal pH was 6 with 97.99% removal efficiency. The result showed that wastewaters containing surfactant were almost completely removed at pH 6 by PAC. Removal efficiency was decreased by increasing PAC dosage higher than 400 mg/l and dosage over 700 mg/l of PAC abolished the treatment. 4. The comparative analysis of three methods revealed that the effective pH ranges were at pH 2-5 with Fenton oxidation, at pH 6-11 with PAC, and pH 11 with Alum. The removal efficiencies at these pH were 83.95-97.92%, 75.98-97.99% and 61.13%, respectively. 5. Increase in LAS concentration reduced the removal efficiencies of all three methods. In the case of PAC or Alum treatment, treatment abolished at LAS concentration higher than 700 mg/l.

• Journal of the Korean Wood Science and Technology
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• v.48 no.3
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• pp.271-282
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• 2020

Sewage treatment plants are social infrastructure of cities. The sewage distribution rate in Korea is reaching 94% based on the sewage statistics based in the year of 2017. In Korean sewage treatment plants, use of PAC (Poly Aluminum Chloride) accounts for 58%. It contains a large amount of impurities (heavy metal) according to the quality standards, however, there have been insufficient efforts to reinforce the standards or technically improve the quality, which resulted in secondary pollution problems from injecting excessive coagulant. Also, the increase in the use of chemicals is leading to the increases in the annual amount of sewage sludge generated in 2017 and the need to reuse sludge. As such, this study aims to verify the possibility of reusing sludge by evaluating the stability of heavy metals based on the injection of coagulant mixture during water treatment which uses the torrefield wood powder and natural materials, and evaluating the sedimentation and heating value of sewage sludge. As a result of analyzing heavy metals (Cr, Fe, Zn, Cu, Cd, As, Pb, and Ni) from the coagulant mixture and PAC (10%), Cr, Cd, Pb, Ni, and Hg were not detected. As for Zn, while its concentration notified in the quality standards for drinking water is 3 mg/L, only a small amount of 0.007 mg/L was detected in the coagulant mixture. Maximum amounts of over double amounts of Fe, Cu, and As were found with PAC (10%) compared to the coagulant mixture. Also, an analysis of sludge sedimentation found that the coagulant mixture showed a better performance of up to double the speed of the conventional coagulant, PAC (10%). The dry-basis lower heating value of sewage sludge produced by injecting the coagulant mixture was 3,378 kcal/kg, while that of sewage sludge generated due to PAC (10%) was 3,171 kcal/kg; although both coagulants met the requirements to be used as auxiliary fuel at thermal power plants, the coagulant mixture developed in this study could secure heating values 200 kal/kg higher than the counterpart. Therefore, utilization of the coagulant mixture for water treatment rather than PAC (10%) is expected to be more environmentally stable and effective, as it helps generating sludge with better stability against heavy metals, having a faster sludge sedimentation, and higher heating value.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.12
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• pp.689-697
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• 2017

As a fundamental study to apply the new flocculation method using ballast in water treatment process, the optimal conditions for general and ballast coagulant dosage, and pH, which are known to have a significant influence, were derived by response surface methodology. Poly aluminum chloride (PAC) and magnetite ballast were used as a general coagulant and ballast, respectively. Coagulation experiments were performed by jar-tester using the kaolin based synthetic water. The effects of three independent variables (pH, PAC, and ballast) on response variables (turbidity removal rate and average settling velocity of flocs) and the optimum condition of independent variables to induce the optimum flocculation were obtained by 17 experimental conditions designed by Box-Behnken procedure. After performing experiments, the quadratic regression model was derived for each of response variables, and the response surface analysis was conducted to explore the correlation between independent variables and response variables. The $R^2$ values for the turbidity removal rate and the average settling velocity were 0.9909 and 0.8295, respectively. The optimal conditions of independent variables were 7.4 of pH, 38 mg/L of PAC and 1,000 mg/L of ballast. Under these conditions, the turbidity removal rate was more than 97% and the average settling velocity exceeded 35 m/h.

• Journal of environmental and Sanitary engineering
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• v.20 no.3 s.57
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• pp.36-43
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• 2005

Prior to the study of the sewage treatment methods, water quality for Gwangju sewage of fluent was investigated from January to December, 2004 for sewage water reuse. Monthly mean values of BOD, SS, turbidity, total phosphorus and color were 4.1 mg/L, 2.9 mg/L, 0.8 NTU, 1.3 mg/L, and 27 unit, respectively. Jar-test was performed to investigate the removal efficiency of pollutants under the coagulation conditions of fast mixing for 5 min, slow mixing for 15 min and precipitation for 1hr. Here, alum and polyaluminium chloride (PAC) were used as coagulants to reduce color, turbidity, total phosphorus (TP) and total organic carbon (TOC) in sewage effluents. The results showed that PAC gave better efficiency in removing turbidity and dissolved phosphorus than alum. It was also found from the relative molecular weight (RMW) distribution analysis that organic matter over 1,000 Dalton (Da) was easily removed by coagulation and subsequently MF treatment, while it was not effective for less than 500 Da. Based on tis result, Natural organic matter (NOM) with lower molecular weight (< 500 Da) may cause harmful disinfectant by-product (DBP) after chlorine treatment. Thus, activated carbon adsorption seems to be required for the complete removal of DBP in the hybrid system.