• Title/Summary/Keyword: P91

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mPW1PW91 Calculated Structures and IR Spectra of Thiacalix[4]biscrown-5 Complexed with Alkali Metal Ions

  • Choe, Jong-In
    • Bulletin of the Korean Chemical Society
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    • v.32 no.5
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    • pp.1685-1691
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    • 2011
  • The molecular structures of thiacalix[4]biscrown-5 (1) and p-tert-butylthiacalix[4]biscrown-5 (2) and their alkali-metal-ion complexes were optimized using the DFT BLYP/6-31G(d) and mPW1PW91/6-31G(d,p) (hybrid HF-DF) calculations. The total electronic energies, the normal vibrational modes, and the Gibbs free energies of the mono- and di-topic complexes of each host with the sodium and potassium ions were analyzed. The $K^+$-complexes exhibited relatively stronger binding efficiencies than $Na^+$-complexes for both the monoand di-topic complexes of 1 and 2 comparing the efficiencies of the sodium and potassium complexes with an anisole and phenol. The mPW1PW91/6-31G(d,p) calculated distances between the oxygen atoms and the alkali metal ions were reported in the alkali-metal-ion complexes ($1{\cdot}Na^+$, $1{\cdot}2Na^+$, $1{\cdot}K^+$, $1{\cdot}2K^+$, $2{\cdot}Na^+$, $2{\cdot}Na^+$, $2{\cdot}K^+$, $2{\cdot}2K^+$). The BLYP/6-31G(d) calculated IR spectra of the host 1 and its mono-topic alkali-metal-ion complexes are compared.

인공 산성 빗물로 인한 잎으로부터의 양이온 이론

  • 류태선;김준호
    • The Korean Journal of Ecology
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    • v.16 no.4
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    • pp.409-416
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    • 1993
  • After spraying simulated sulphuric acid rain (SSAR) to the leaves of Glycine max, Quercus aliena var. pellucida and Pinus rigida, the leachates were consecutively collected and quantitatively determined for the concentration of K and Ca. The amount of the leached ion decreased with subsequent acid treatment for all plants. But as the pH of SSAR decreased, the amount of the leached ion increased. The cumulative quantities of K leached from each species were 1.04 to 1.46 times higher at pH 4.0, 1.09 to 1.58 times higher at pH 3.5 and 1.24 to 2.03 times higher at pH 3.0 compared with pH 5. 6 treatments. The cumulative quantities of Ca leached from each species were 1.23 to 1.47 times higher at pH 4.0, 1.50 to 1.92 times higher at pH 3.5, and 2.45 to 3.30 times higher at pH 3.0 compared with pH 5.6 treatments. The Ca /K ratio in 1000 ml leachate was 1.10 to 2.91 for Q. aliena var. pellucida and 1.68 to 2.98 for P. rigida, but 0.66 to 0.91 for G, max. The Ca /K ratio in 1000 rnl leachate increased for all three species, as the pH of SSAR decreased. Foliage analysis after acid rain treatment showed leaching effect at pH 3.0.

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Fabrication and Characterization of CNFs/Magnesium Composites Prepared by Liquid Pressing Process (액상가압공정을 이용한 CNF/Mg 복합재료의 제조 및 특성평가)

  • Kim, Hee-Bong;Lee, Sang-Bok;Yi, Jin-Woo;Lee, Sang-Kwan;Kim, Yang-Do
    • Composites Research
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    • v.25 no.4
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    • pp.93-97
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    • 2012
  • Carbon nano fibers (CNFs) reinforced magnesium alloy (AZ91) matrix composites have been fabricated by liquid pressing process. In order to improve the dispersibility of CNFs and the wettability with magnesium alloy melt, CNFs were mixed with submicron sized SiC particles ($SiC_p$). Also, the mixture of CNFs and $SiC_p$ were coated with Ni by electroless plating. In liquid pressing process, AZ91 melts have been pressed hydrostatically and infiltrated into three reinforcement preforms of only CNFs, the mixture of CNFs and $SiC_p$ (CNF+$SiC_p$), and Ni coated CNFs and $SiC_p$ ((CNF+$SiC_p$)/Ni). Some CNFs agglomerates were observed in only CNFs reinforced composite. In cases of the composites reinforce with CNF+$SiC_p$ and (CNF+$SiC_p$)/Ni, CNFs were dispersed homogeneously in the matrix, which resulted in the improvement of mechanical properties. The compressive strengths of CNF+$SiC_p$ and (CNF+$SiC_p$)/Ni reinforced composites were 38% and 28% higher than that of only CNFs composite.

An Estimated Value and Change in TDF Binding Major Minerals of Soybean Sprouts Depending on Cultivation Days and Parts (콩나물의 재배기간과 부위별 TDF에 결합된 주요 무기질의 변화와 추정 이용율)

  • Eun, Jeong-Hwa;Eum, Ji-Hye;Kim, Dae-Jin
    • Journal of Life Science
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    • v.19 no.8
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    • pp.1088-1092
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    • 2009
  • This study was conducted to determine an estimated value and change in TDF (total dietary fiber) binding major minerals (Ca, P, K Mg) of soybean sprouts depending on cultivation periods of 1, 3 or 5 days, and parts of cotyledon and hypocotyl. The compositions of TDF binding major minerals in soybean sprouts were evaluated by the enzymatic-gravimetric method developed by Prosky and adopted by AOAC. The content of TDF binding P ranged between 915.28 mg and 1037.82 mg per 100 g cotyledon. Average contents of Ca, K, and Mg in cotyledon ranged between 541.67 mg and 634.34 mg, 180.91 mg and 253.98 mg, 231.90 mg and 301.01 mg, respectively, on dry matter basis. The average contents of TDF binding Ca in hypocotyl per 100 g were between 454.36 mg and 540.33 mg, and other major minerals contents were between 149.24 mg and 186.21 mg for P, 164.17 mg and 182.78 mg for K, and 152.53 mg and 161.22 mg for Mg, respectively. The proportional changes of Ca, an estimated value in cotyledon, ranged between 5.58% and 30.98%, 47.18% and 59.10% for P, 95.24% and 95.50% for K, and 58.45% and 68.64% for Mg, respectively, based on dry matter. An estimated value of Ca, P, K, and Mg in hypocotyl ranged between 6.71% and 13.52%, 91.03% and 91.76%, 96.91% and 98.92%, and 61.03% and 66.37%, respectively, on dry matter basis.

A Study of ADL Performance on Elderly Total Knee Replacement Patients (슬관절전치환술 환자의 일상생활동작 수행력에 관한 연구)

  • Park Chang-gon;Park Rae-joon
    • The Journal of Korean Physical Therapy
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    • v.15 no.4
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    • pp.151-179
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    • 2003
  • The purpose of this study was to examine the influence of total knee replacement to arthritis patients in pain intensity and functional impairment. For this study, over 50-year-old 30 patients who had osteoarthritis and 69 patients who got total knee replacement at the one of the departments of orthopedics in Daegu were interviewed from June, 2002 to March, 2003. The results of this study were as follows : First, pain intensity was decreased to experimental group after operation than control group(P<.01) And the presence of crepitation was also decreased to them(P<.05). On the other hand there's no significant difference was noted in the presence of stiffness, degree of flexion contracture and extension contracture between two groups. Second, over 91 days group after operation and visitor's group of physiotherapy unit were better than others in Level of knee function(P<.01). Third, over 91 days group after operation and visitor's group of physiotherapy unit were higher than others in Barthel Index of knee function(P<.01). Forth, over 91 days group after operation and visitor's group of physiotherapy unit were higher than others in Level of IADL(P<.05). Fifth, over 91 days group after operation and visitor‘s group of physiotherapy unit were higher than others in Katz Index of knee function(P<.01). Sixth, although Old Ages' Activity Index seemed to get better as time goes by, there's no statistical difference. Seventh, over 91 days group after operation and visitor's group of physiotherapy unit were higher than admission group and under 30 days group after operation in Social Activity Index(P<.05). Eighth, the function of the knee was connected with the abilities in the activity of the old and the social skill. The Barthel index was connected with the function of the knee joint and the activities of the old and Katz index. IADL function was connected with the activities of the old and the social activity. The Katz index was connected with the Barthel index. The activity of the old was connected with the Barthel index, the functional score of the knee joint andthe IADL score. The ability of social skill was connected with the activity of the old, IADL score and the function of the knee.

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Artificial Oxidation of Cysteine Residues in Peroxiredoxin 6 Detected by Twodimensional Gel Electrophoresis and Capillary Liquid Chromatography-Electrospray Mass Spectrometry

  • Kimata, Junko;Shigeri, Yasushi;Yoshida, Yasukazu;Niki, Etsuo;Kinumi, Tomoya
    • Mass Spectrometry Letters
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    • v.3 no.1
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    • pp.10-14
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    • 2012
  • Artificially oxidized cysteine residues in peroxiredoxin 6 (Prx6) were detected by electrospray interface capillary liquid chromatography-linear ion trap mass spectrometry after the preparation of two-dimensional gel electrophoresis (2D-GE). We used Prx6 as a model protein because it possesses only two cysteine residues at the 47th and 91st positions. The spot of Prx6 on 2D-GE undergoes a basic (isoelectric point, pI 6.6) to acidic (pI 6.2) shift by exposure to peroxide due to selective overoxidation of the active-site cysteine Cys-47 but not of Cys-91. However, we detected a tryptic peptide containing cysteine sulfonic acid at the 47th position from the basic spot and a peptide containing both oxidized Cys-47 and oxidized Cys-91 from the acidic spot of Prx6 after the separation by 2D-GE. We prepared two types of oxidized Prx6s: carrying oxidized Cys-47 (single oxidized Prx6), and other carrying both oxidized Cys-47 and Cys-91 (double oxidized Prx6). Using these oxidized Prx6s, the single oxidized Prx6 and double oxidized Prx6 migrated to pIs at 6.2 and 5.9, respectively. These results suggest that oxidized Cys-47 from the basic spot and oxidized Cys-91 from the acidic spot are generated by artificial oxidation during sample handling processes after isoelectric focusing of 2D-GE. Therefore, it is important to make sure of the origin of cysteine oxidation, if it is physiological or artificial, when an oxidized cysteine residue(s) is identified.

Relationship between Job Characteristic and Quality of Life among some Elderly (노인의 직업특성과 삶의 질과의 관련성)

  • Park, Bu-Yeon;Ko, Dae-Sik;Park, Hyung-Su
    • The Journal of the Korea institute of electronic communication sciences
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    • v.8 no.6
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    • pp.941-947
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    • 2013
  • This study is to provide basic data on the jobs program to identify the relevance of the professional activities and quality of life of the elderly and the elderly, were performed using the National Health and Nutrition Examination Survey.. Survey population of 1,472 patients were 65 years of age or older. The survey method, t-test, ANOVA and multilevel regression analysis was used. This study result of quality of life of elderly people with a job, unemployed elderly people appeared to be higher than the quality of life(${\beta}=0.041$, p=0.000). In work mode regular workers was an average of 0.93 points((p=0.005), in working hour full-time average 0.91 points(p=0.079), in job classification professional average 0.91 points(p=0.044) the higher the quality of life. Elderly business jobs, there is a need to improve the quality of life of the elderly to consider the results of this study work business.

A Structural Model for Chemotherapy Related Cognitive Impairment and Quality of Life in Breast Cancer Patients (유방암 환자의 항암화학요법 관련 인지기능 변화와 삶의 질의 구조모형)

  • Lee, Jung Ran;Oh, Pok Ja
    • Journal of Korean Academy of Nursing
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    • v.49 no.4
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    • pp.375-385
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    • 2019
  • Purpose: This study aimed to develop and test a structural model for chemotherapy-related cognitive impairment of breast cancer patients based on a literature review and Hess and Insel's chemotherapy-related cognitive change model. Methods: The Participants consisted of 250 patients who were ${\geq}19$ years of age. The assessment tools included the Menopause Rating Scale, Symptom Experience Scale, Hospital Anxiety and Depression Scale, Everyday Cognition, and Functional Assessment of Cancer Therapy-Breast Cancer. Data were analyzed using the SPSS 21.0 and AMOS 21.0 programs. Results: The modified model was a good fit for the data. The model fit indices were ${\chi}^2=423.18$ (p<.001), ${\chi}^2/df=3.38$, CFI=.91, NFI=.91, TLI=.89, SRMR=.05, RMSEA=.09, and AIC=515.18. Chemotherapy-related cognitive impairment was directly influenced by menopausal symptoms (${\beta}=.38$, p=.002), depression and anxiety (${\beta}=.25$, p=.002), and symptom experiences (${\beta}=.19$, p=.012). These predictors explained 47.7% of the variance in chemotherapy-related cognitive impairment. Depression and anxiety mediated the relations among menopausal symptoms, symptom experiences, and with chemotherapy related cognitive impairment. Depression and anxiety (${\beta}=-.51$, p=.001), symptom experiences (${\beta}=-.27$, p=.001), menopausal symptoms (${\beta}=-.22$, p=.008), and chemotherapy-related cognitive impairment (${\beta}=-.15$, p=.024) had direct effects on the quality of life and these variables explained 91.3%. Conclusion: These results suggest that chemotherapy-related toxicity is highly associated with cognitive decline and quality of life in women with breast cancer. Depression and anxiety increased vulnerability to cognitive impairment after chemotherapy. Nursing intervention is needed to relieve chemotherapy-related toxicity and psychological factor as well as cognitive decline for quality of life in patients undergoing chemotherapy.