• Steel and Composite Structures
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• v.18 no.5
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• pp.1215-1237
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• 2015

The majority of connections in moment resisting frames are considered as being fully-rigid. Consequently, the real behavior of the connection, which has some level of flexibility, is ignored. This may result in inaccurate predictions of structural response. This study investigates the influence of flexibility of the extended end-plate connections in the steel moment frames. This is done at two levels. First, the actual micro-behavior of extended end-plate moment connections is explored with respect to joint flexibility. Then, the macro-behavior of frames with end-plate moment connections is investigated using modal, nonlinear static pushover and incremental dynamic analyses. In all models, the P-Delta effects along with material and geometrical nonlinearities were included in the analyses. Results revealed considerable differences between the behavior of the structural frame with connections modeled as fully-rigid versus those when flexibility was incorporated, specifically difference occurred in the natural periods, strength, and maximum inter-story drift angle.

• Structural Engineering and Mechanics
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• v.73 no.1
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• pp.17-25
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• 2020

A finite element (FE) model for analyzing slender reinforced high-strength concrete (HSC) columns under biaxial eccentric loading is formulated in terms of the Euler-Bernoulli theory. The cross section of columns is divided into discrete concrete and reinforcing steel fibers so as to account for varied material properties over the section. The interaction between axial and bending fields is introduced in the FE formulation so as to take the large-displacement or P-delta effects into consideration. The proposed model aims to be simple, user-friendly, and capable of simulating the full-range inelastic behavior of reinforced HSC slender columns. The nonlinear model is calibrated against the experimental data for slender column specimens available in the technical literature. By using the proposed model, a numerical study is carried out on pin-ended slender HSC square columns under axial compression and biaxial bending, with investigation variables including the load eccentricity and eccentricity angle. The calibrated model is expected to provide a valuable tool for more efficiently designing HSC columns.

• Food Engineering Progress
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• v.15 no.2
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• pp.169-174
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• 2011

This study was performed to analyze the effects of ultra fine pulverization (UFP) on the physicochemical properties of sweet potato starch (SPS). The average diameter and specific surface area of the SPS was decreased from 22.94 to 10.25 $\mu$m and from 0.879 to 1.909 $m^2$ /g throughout UFP, respectively, and the damaged starch content was increased from 13.7 to 99.2%. The pulverized sweet potato starch (PSPS) had higher swelling power, solubility, and transmittance values than the SPS. X-ray diffractograms revealed that the SPS had a C-type pattern, which disappeared in PSPS. The rapid visco analysis (RVA) characteristics, peak viscosity, break down, and set back of SPS ceased to exist in PSPS. According to differential scanning calorimetry (DSC) curves, the peak temperature ($T_p$) and gelatinization enthalpy ($\Delta$E) of SPS were $71.95^{\circ}C$ and 10.40 J/g, respectively, while these remained undetected in PSPS. The enzymatic digestibilities of SPS and PSPS were 61.7 and 84.7%, respectively.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.32 no.3
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• pp.229-233
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• 2019

Pure $BiFeO_3$ (BFO) and (Eu, V) co-doped $Bi_{0.9}Eu_{0.1}Fe_{0.975}V_{0.025}O_{3+{\delta}}$ (BEFVO) thin films were deposited on $Pt(111)/Ti/SiO_2/Si(100)$ substrates by chemical solution deposition. The effects of co-doping were observed by X-ray diffraction, Raman spectroscopy, and scanning electron microscopy (SEM). The electrical properties of the BEFVO thin film were improved as compared to those of the pure BFO thin film. The remnant polarization ($2P_r$) of the BEFVO thin film was approximately $26{\mu}C/cm^2$ at a maximum electric field of 1,190 kV/cm with a frequency of 1 kHz. The leakage current density of the co-doped BEFVO thin film ($4.81{\times}10^{-5}A/cm^2$ at 100 kV/cm) was two orders of magnitude lower than of that of the pure BFO thin film.

• Steel and Composite Structures
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• v.29 no.5
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• pp.623-633
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• 2018

A robust element is essential for successful design of steel frames with Direct analysis (DA) method. To this end, an innovative and efficient curved-quartic-function (CQF) beam-column element using the fourth-order polynomial shape function with end-springs in series is proposed for practical applications of DA. The member initial imperfection is explicitly integrated into the element formulation, and, therefore, the P-${\delta}$ effect can be directly captured in the analysis. The series of zero-length springs are placed at the element ends to model the effects of semi-rigid joints and material yielding. One-element-per-member model is adopted for design bringing considerable savings in computer expense. The incremental secant stiffness method allowing for large deflections is used to describe the kinematic motion. Finally, several problems are studied in this paper for examining and validating the accuracy of the present formulations. The proposed element is believed to make DA simpler to use than existing elements, which is essential for its successful and widespread adoption by engineers.

• Structural Engineering and Mechanics
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• v.83 no.6
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• pp.811-824
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• 2022

Despite its disadvantages, soft story can reduce the damage to the upper floors by concentrating drift in that specific story provided that large drifts are avoided. Gapped-Inclined Brace (GIB) with reduced P-delta effects and the control of soft story stiffness makes it possible to take advantage of the soft story in buildings and increase their capacity for energy dissipation. OpenSees software is used in this study to validate and modify the GIB model's shortcomings. Also, the analysis method for this element is changed for design. The modified element is evaluated in 3D analysis. Finally, to retrofit an existing building, this element is used. Based on the Iranian seismic code, a six-story reinforced concrete building is modelled and studied with 3D analysis. In this building, the construction shortcomings and elimination of infills on the ground floor cause the formation of a soft story. Results of nonlinear static analysis, nonlinear dynamic, and incremental dynamic analysis using both components of seismic acceleration applied to the structure at different angles and the fragility curves indicate the improvement of the retrofitted structure's performance using the modified element to reach the required performance level following the retrofit code.

• Bulletin of the Korean Chemical Society
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• v.32 no.1
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• pp.263-272
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• 2011

Highly luminescent and monodisperse InP quantum dots (QDs) were prepared by a non-organometallic approach in a non-coordinating solvent. Fatty acids with well-defined chain lengths as the ligand, a non coordinating solvent, and a thorough degassing process are all important factors for the formation of high quality InP QDs. By varying the molar concentration of indium to ligand, QDs of different size were prepared and their absorption and emission behaviors studied. By spin-coating a colloidal solution of InP QD onto a silicon wafer, InP QD thin films were obtained. The thickness of the thin films cured at 60 and $200^{\circ}C$ were nearly identical (approximately 860 nm), whereas at $300^{\circ}C$, the thickness of the thin film was found to be 760 nm. Different contrast regions (A, B, C) were observed in the TEM images, which were found to be unreacted precursors, InP QDs, and indium-rich phases, respectively, through EDX analysis. The optical properties of the thin films were measured at three different curing temperatures (60, 200, $300^{\circ}C$), which showed a blue shift with an increase in temperature. It was proposed that this blue shift may be due to a decrease in the core diameter of the InP QD by oxidation, as confirmed by the XPS studies. Oxidation also passivates the QD surface by reducing the amount of P dangling bonds, thereby increasing luminescence intensity. The dielectric properties of the thin films were also investigated by capacitance-voltage (C-V) measurements in a metal-insulator-semiconductor (MIS) device. At 60 and $300^{\circ}C$, negative flat band shifts (${\Delta}V_{fb}$) were observed, which were explained by the presence of P dangling bonds on the InP QD surface. At $300^{\circ}C$, clockwise hysteresis was observed due to trapping and detrapping of positive charges on the thin film, which was explained by proposing the existence of deep energy levels due to the indium-rich phases.

• Journal of Biomedical Engineering Research
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• v.19 no.1
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• pp.81-90
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• 1998

Electromagnetic waves may induce various effects on nervous tissues either by thermal or non-thermal mechanisms. This paper intoduces a method to evalute the non-thermal effect to central nervous system by measuring the EEGs of the rabbits treated by nimodipine before exposed to weak microwave field. 20 rabbits were divided into 2 groups and their EEGs were measured after their head section were exposed to 2,450 MHz microwave with the power density of 10 dBm and 20 dBm respectively for 10 minutes and compared with those of the 3rd group of 10 rabbits which were not exposed. The 4th group of 10 rabbits were intravenously given with nimodipine before exposed to 20 dBm field to determine whether this drug would reverse the EEGs changes induced by weak microwave irradiation. As field poser exceeded 20 dBm although no significant physiological changes were observed, total induced EEGs power was remarkably decreased suggesting the presence of CNS activation. Using Fourier analysis on the EEGs signal it was found that remarkable decrease in delta band and increase in the alpha and beta bands in a significant manner(P<0.05) compared to control group. The changes were, however, not reversed by nimodipine-treatment. The effects may be pure thermal in nature because no significant change has been observed in nimodipine treated rabbits.

• Journal of the Korean Chemical Society
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• v.23 no.4
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• pp.243-247
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• 1979

Kinetics of the reaction of phenethyltosylate with substituted pyridines at 50, 60 and 70$^{\circ}C$ in acetonitrile were investigated by an electric conductivity method. The effects of substituents on the reaction of phenethyltosylate with pyridines were discussed. The rates of reaction were increased with electron donating power of substituents of pyridines. The isokinetic relationship was shown $E_{\alpha}$ and ${\Delta}S^{\neq}$, it's temperature was 240$^{\circ}$K. Bronsted plots were excellent linear except for 4-amino pyridine given by the following equation, logk=O. 22pKa-3.71 (r=O. 986). According to a plot of log k against Hammett substituent constants, the Iinearity was good except for bamino pyridine too, log k= -1.330${\sigma}$+0.08 (r= -0.987). In both cases, deviation of 4-amino pyridine from linearity was considered to solvent effect, resonance effect and ${\sigma}$ value itself. From all the above results, this reaction was found typical $S_N2$ reaction which the rates of reaction was determined by C…N bond formation at transition state.

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.414-422
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• 2008

Adsorption experiments for $H_2$, $CH_4$, CO, $CO_2$ on activated carbon and zeolite 5A were performed by static volumetric method. A 4-bed pressure swing adsorption (PSA) process was to study separation of hydrogen from multi-component mixture gases ($H_2$ 72.2%, $CH_4$ 4.06%, CO 2.03%, $CO_2$ 21.6%). Dual-site langmuir (DSL) isotherm showed good or fair agreement with the experimental results. The optimum height of activated carbon layer was 55 cm with breakthrough results on the packing ratio of activated carbon to zeolite 5A. In PSA process, the effects of the process parameters such as total cycle time ($T_c$), ${\Delta}P$ at the provide purge step and adsorption pressure on the PSA performance were studied experimentally and theoretically.