• Title/Summary/Keyword: P-T path

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Kinetics and Mechanism of Pyridinolysis of Aryl Dithiocyclopentanecarboxylates in Acetonitrile

  • Oh, Hyuck-Keun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.8
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    • pp.2357-2360
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    • 2010
  • Kinetic studies on the pyridinolysis of aryl dithiocyclopentanecarboxyaltes 2 were carried out at $60.0^{\circ}C$ in acetonitrile. In the aminolysis of 2, the $\beta_X$ values were 0.5 - 0.8 with anilines, and there was no breakpoint. However, in the pyridinolysis of 2, biphasic Bronsted plots were obtained, with a change in slope from a large value ($\beta_X{\cong}0.7$) to a small value ($\beta_X{\cong}0.4$) at $pK_{a}^0$ = 5.2. This was attributed to a change in the rate-limiting step from breakdown to the formation of a zwitterionic tetrahedral intermediate, $T^{\pm}$, in the reaction path, with an increase in the basicity of the pyridine nucleophile. An obvious change in the cross-interaction constant ${\rho}_{XZ}$ from a large positive ($\rho_{XZ}$ = +1.02) value to a small negative value (${\rho}_{XZ}$ = -0.17) supports the proposed mechanistic change.

Precise Measurement of the change n the optical length of a fiber Fabry-Perot interferometer. (광섬유 Fabry-Perot 간섭계를 이용한 위상 변화량의 정밀 측정)

  • 김영준
    • Proceedings of the Optical Society of Korea Conference
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    • 1989.02a
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    • pp.113-118
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    • 1989
  • By using the single mode optical fiber, we fabricated Fiber-optic Fabry-Perot interferometer (FFPI). The change over a wide range in the optical path length of a FFPI is observed. The temporal movement of the interference fringes by external condition to P.Z. T) is converted to circular motion on an oscilloscope display and then recorded with a micro-computer. The two output voltages of the D/A converters are applied to X and Y terminals of oscilloscope to display circular motion on oscilloscope. Thus the direction of phase shift can be determined with observing the direction of circular motion. The variation of the optical length can be measured by calculating the angle of spot of circle with an accuracy of λ/90 wave length due to variation of temperature in this system 2.7x10-4$^{\circ}C$.

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Solving the Team Orienteering Problem with Particle Swarm Optimization

  • Ai, The Jin;Pribadi, Jeffry Setyawan;Ariyono, Vincensius
    • Industrial Engineering and Management Systems
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    • v.12 no.3
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    • pp.198-206
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    • 2013
  • The team orienteering problem (TOP) or the multiple tour maximum collection problem can be considered as a generic model that can be applied to a number of challenging applications in logistics, tourism, and other fields. This problem is generally defined as the problem of determining P paths, in which the traveling time of each path is limited by $T_{max}$ that maximizes the total collected score. In the TOP, a set of N vertices i is given, each with a score $S_i$. The starting point (vertex 1) and the end point (vertex N) of all paths are fixed. The time $t_{ij}$ needed to travel from vertex i to j is known for all vertices. Some exact and heuristics approaches had been proposed in the past for solving the TOP. This paper proposes a new solution methodology for solving the TOP using the particle swarm optimization, especially by proposing a solution representation and its decoding method. The performance of the proposed algorithm is then evaluated using several benchmark datasets for the TOP. The computational results show that the proposed algorithm using specific settings is capable of finding good solution for the corresponding TOP instance.

Metamorphism of gneiss complex in the Paju-Gimpo area, northwestern Gyeonggi massif, Korea (경기육괴 북서부의 파주-김포지역에 분포하는 편마암복합체의 변성작용)

  • Ahn, Kun-Sang;Park, Young-Seog;Kim, Cheong-Bin;Chen, Jiangfeng
    • The Journal of the Petrological Society of Korea
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    • v.7 no.3
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    • pp.177-189
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    • 1998
  • Proterozoic gneisss complex of the Paju-Gimpo area, Northwestern Gyeonggi Massif, consists of mainly gneiss and schist with locally intercalated quartzite and metamorphic calcareous rocks. Mineral assemblages of the gneiss and schist are classified into two type: sillimanite free (garnet zone) and sillimanite bearing (sillimanite zone) assemblages. In the Goyang area, Kyanite occurs as metastable relict grain in two gneiss samples, in which sillimanite, garnet, biotite, K-feldspar and plagioclase occur. Cordierite bearing mineral assemblages of gneiss are biotite+garnet+sillimanite+cordierite+plagioclase+quartz ($\pm$K-feldspar, muscovite), and represent the upper amphibolite or granulite facies metamorphism. The metamorphic complex has experienced two different regional metamorphism. The prograde metamorphism is a medium-pressure type characteries by kyanite. The peak metamorphic P-T condition of the prograde metamorphism calculated from the kyanite bearing rock is 7.0~9.4 kb and $718~778^{\circ}C$. The retrograde metamorphism, after the prograde metamorphism, is the low-pressure type characteries by occurrence of cordierite. The peak metamorphic P-T condition of later calculated from the cordierite bearing rock is 3.6~5.5 kb and $750~889^{\circ}C$. Together with the occurrence of relict kyanite, garnet+biotite+plagioclase assemblage as relict in the cordierite, and the result of estimated P-T metamorphic conditions indicate a clockwise P-T path.

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A Study on the Image of Dental Hygiene and the Career Consideration of Some Local High School Students (일부지역 고등학생들의 치과위생사에 대한 이미지와 진로 고려의사에 관한 연구)

  • Lee, Sunmi;Mun, Wonsuk
    • Journal of The Korean Society of Integrative Medicine
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    • v.8 no.2
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    • pp.149-157
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    • 2020
  • Purpose : The purpose of this study was that For high school students in Busan, in order to provide basic data in selecting dental hygienists by establishing the correct perception and image of dental hygienists by identifying the image of dentists and career doctors who will choose dental hygienists. Methods : The comparison of group differences with dental hygienists' images was analyzed with independent sample t-test and one-way ANOVA. Correlation between image factors of dental hygienists was analyzed using Pearson's correction coefficient. Results : The image for dental hygienists averaged 3.87 points overall, while the average for each area of the image was 4.09 points for professional images, 4.07 points for business images, 4.08 points for personal images and 3.28 points for social images. When choosing a career path, 18.8 percent said they would not consider dental hygiene, and if they said they would consider dental hygiene, both work, professional, personal and social images were significantly high (p<.05). Professional and professional images (r=.975, p<.05) in the correlation between factors of dental hygienist images, personal and professional images (r=.942, p<.05), social and professional images (r=.865, p<.05), business and personal images (r=.924, p<.05), business image and social image (r=.858, p<.05), personal and social images (r=.882, p<.05) expressed a statistically significant amount of correlation. Conclusion : The study found that high school students' image of dental hygienists was rather positive, but their social image was rather low, and most students did not consider dental hygiene. Therefore, specific measures will be needed to build a desirable image for dental hygienists and positively recognize dental hygienists with active promotion and career experience for dental hygienists in the future.

Effects of Job Characteristics, Organizational Culture on Job Satisfaction and Turnover Intention in Public Institution Nurses (공공기관 간호사의 직무특성, 조직문화가 직무만족과 이직의도에 미치는 영향)

  • Lee, Young Joo;Kim, So Hee;Lee, Taewha
    • Journal of Korean Academy of Nursing Administration
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    • v.21 no.4
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    • pp.354-365
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    • 2015
  • Purpose: The aim of this study was to examine the relationship between job characteristics, organizational culture, job satisfaction and turnover intention, including the direct and indirect effects of the variables on turnover intention. Methods: A questionnaire was completed by a convenience sample of 144 nurses working for two public institutions. Data were analyzed using independent t-test, One-way ANOVA, Pearson correlation, Hierarchical multiple regression and Path analysis with SPSS/WIN 21.0 and AMOS 21.0 programs. Results: The mean score for job satisfaction and turnover intention was similar to that of other hospital nurses. The factors affecting job satisfaction were: position, number of job changes, relationship-oriented culture, and hierarchical-oriented culture(Adj. $R^2=.48$, F=14.43, p<.001). The factors affecting turnover intention were: age, position, overtime, and job satisfaction(Adj. $R^2=.61$, F=19.48, p<.001). Job autonomy and relationship-oriented culture had a significant indirect effect on turnover intention. Conclusion: In developing intervention strategies to improve job satisfaction and reduce turnover intention there is a need to consider both the job characteristics and organizational culture of nurses in public institutions.

The effect of parental neglect, abuse on middle school children's life satisfaction - Focused on the mediating effects of ego-resilience (부모에게 받은 방임과 학대가 중학생의 삶의 만족도에 미치는 영향 -자아탄력성의 매개효과를 중심으로)

  • Woo, Jea-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.10
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    • pp.569-579
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    • 2017
  • The purpose of this study was to test the mediation effects of adolescents' ego-resilience on the relation between neglect, abuse and life satisfaction. The 6-year longitudinal data from the Korean Children & Youth Panel Survey (KCYPS) were collected from 1st grade middle school students. The data were analyzed by structural equation modeling and Sobel testing.The results of this study were as follows. First, the results revealed that the path from neglect and abuse to life satisfaction was partially mediated by family relations. The relations between trauma(neglect) and ego-resilience are negative(${\beta}=-.258$, p<.001). The relations between ego-resilience and life satisfaction are positive(${\beta}=.843$, p<.001). Second, the verification of the mediation effect of ego-resilience showed that ego-resilience was a full mediator between trauma(neglect) and life satisfaction for 1st grade middle school students(Z=-.169, t(CR)=-.012 (p<.05). Based on these results, the practical implications were discussed.

A study on effect in hemiplegic patients in the Hinged Plastic Ankle Foot Orthoses and Solid Plastic Ankle Foot Orthosis (관절형 및 고정형 플라스틱 단하지 보조기가 편마비환자의 정적${\cdot}$동적 균형에 미치는 효과)

  • Lim Ho-Yong;Ahn Yeon-Jun;Kim Yeong-Rok;Park Seung-Kyu
    • The Journal of Korean Physical Therapy
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    • v.16 no.3
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    • pp.161-175
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    • 2004
  • The purpose of this study was to determine the effect of HPAFO(Hinged Plastic Ankle Foot orthosis) and SPAFO(Solid Plastic Ankle Foot Orthosis) on standing balance and step moving in hemiplegia patients. Twenty hemiplegic patients were either inpatient or outpatient at the Rehabilitation medicine, MokPo J General Hospital and JeonJu J Medical Center from July 15, 2002 to September 15, 2002. Patients were able to ambulate independently for at least 10 meters and to stand independently for at least 10 minutes with balance measurement tool. The static balance and dynamic activity measurement was determined by SAKAI active balancer(Japan) with wearing HPAFO and wearing SPAFO. The static balance and dynamic activity analysis was analyzed by independent t-test. The results were as follows: 1. There were no significant difference in body weight bearing percent between wearing HPAFO and wearing SPAFO(p>0.05). 2. There were significant difference in whole path length between wearing HPAFO and wearing SPAFO(p<0.05). 3. There were significant difference in Effective Value Area between wearing HPAFO and wearing SPAFO(p>0.001). 4. There were significant difference in repeated functional time between wearing HPAFO and wearing SPAFO(p>0.001). 5. There were significant difference in cadence between wearing HPAFO and wearing SPAFO(p>0.001). The result of this study showed that wearing HPAFO and wearing SPAFO gave fair amount of improvement to static standing balance and dynamic movement ability of hemiplegic patients. The comparison result showed significant differences in between HPAFO and SPAHFO. The result of this study had a general limitation due to the restricted number of cases. The future study needs more detailed research and comparison with various variance between these two orthoses.

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Petrogenesis and Metamorphism of Charnockite of Eastern Jirisan Area (지리산 동부 지역에 분포하는 차노카이트의 변성작용과 성인에 관한 연구)

  • 김동연;송용선;박계헌
    • The Journal of the Petrological Society of Korea
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    • v.11 no.3_4
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    • pp.138-156
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    • 2002
  • Precambrian metamorphic rocks of southwest Sobaeksan massif consist of mainly granitic gneiss, porphyroblastic gneiss and quartzofeldspathic gneiss. The orthopyroxene-bearing rocks(charnockites) are found in the west of Hadong-Sancheong anorthosite complex. The charnockites are 3km wide, 12km long and divided into massive and foliated types based on their texture. The compositions of charnockites are comparable to granodiorite to adamellite and subalkaline. Variations in major and trace elemental abundances show typical magmatic differentiation trends. The geochemical data plotted on tectonic discrimination diagrams reveal that these charnockites were formed in the active tectonic environment. The massive and folidated charnockites are mainly composed of plagioclase, orthopyroxene, microcline, quartz and disseminated garnet. Camels generally show characteristic zonal textures with decreasing $X_{alm}$(0.74~0.83), $X_{Py}$ (0.07~0.12) and $X_{Mg}$ (0.12~0.08) and increasing $X_{grs}$(0.03~0.15) from core to rim. Metamorphic temperature and pressure of the charnockites estimated from orthopyroxene-garnet-plagioclase-quartz assemblages show wide range of variation of $600~900^{\circ}C$ and 2.5~7.5 kbar respectively. The results of P-T estimates indicate an anticlockwise P-T evolution path.

Facility Location Problem for Blood Logistics Center (혈액 물류센터 위치 선정 문제)

  • Lee, Sang-Un
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.12 no.2
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    • pp.135-143
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    • 2012
  • This paper suggests the optimal blood distribution center algorithm that satisfies the minimum total transportation cost and within the allowable distribution time $T^*$. Zhang and Yang proposes shifting the location of each point that has less than the average distance of two maximum distance points from each point. But they cannot decide the correct facility location because they miscompute the shortest distance. This algorithm computes the shortest distance $l_{ij}$ from one area to another areas. Then we select the $v_i$ area to thecandidate distribution center location such that $_{max}l_{ij}{\leq}L^*$ and the $v_i$ such that $l_{ij}-L^*$ area that locates in ($v_i,v_k$) and ($v_j,v_l$) from $P_{ij}=v_i,v_k,{\cdots},v_l,v_j$ path and satisfies the $_{max}l_{ij}{\leq}L^*$ condition. Finally, we decide the candidate distribution area that has minimum transportation cost to optimal distribution area.