• Title/Summary/Keyword: P-M diagram

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A Study on the Lateral Flow in Polluted Soft Soils (오염된 연약지반의 측방유동에 관한 연구)

  • 안종필;박상범
    • The Journal of Engineering Geology
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    • v.11 no.2
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    • pp.175-190
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    • 2001
  • This study investigates the existing theoretical backgrounds in order to examine the behavior of lateral flow according to the plasticity of soils when unsymmetrical surcharge is worked on polluted soft soils by comparing and analyzing the results measured through model tests. Model tests are canied out as follows soil tank, bearing frame and bearing plate are made. By increasing unsymmetrical surcharge to the ground soils with the consistent water content and with gradually increased polluted materials at intervals, the amounts of settlement, lateral displacement and upheaval were respectively observed. In conclusion, the value of critical surcharge was expressed as q$_{cr}$=2.78$_{cu}$ which was similar to those Tschebotarioff(q$_{cr}$=3.0$_{cu}$) and Meyerhof(q$_{cr}$=(B/2H+$\pi$/2)$_{cu}$) had been proposed. The value of ultimate capacity was expressed as q$_{ult}$=4.84$_{cu}$ which was similar to that of Prandtl. The lateral flow pressure is adeQuately calculated by the eQuation(P$_{max}$=K$_o$ r H) and the maximum value of lateral flow pressure is found near O.3H of layer thickness(H) and is higher to ground surface than the ones in composition pattern, Poulos distribution pattern and softclay soils (CL, CH) which is not polluted. The stability control method used in this research followed the management diagram of Tominaga.Hashimoto, Shibata.Sekiguchi, Matsuo.Kawamura who use the amounts of plasticity displacement by lateral flow. As a result, the ultimate capacity values in the diagram {S$_v$-(Y$_m$/S$_v$)} of Matsuo.Kawamura and in the diagram {(q/Y$_m$)-q} of Shibata. Sekiguchi were smaller than in the ones of load-settlement curve (q-S$_v$).

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Design of a 2.5V 10-bit 300MSPS CMOS D/A Converter (2.5V 10-bit 300MSPS 고성능 CMOS D/A 변환기의 설계)

  • Kwon, Dae-Hoon;Song, Min-Kyu
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.39 no.7
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    • pp.57-65
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    • 2002
  • In this paper, a 2.5V 10-bit 300MSPS CMOS D/A Converter is described. The architecture of the D/A Converter is based on a current steering 8+2 segmented type, which reduces non-linearity error and other secondary effects. In order to achieve a high performance D/A Converter, a novel current cell with a low spurious deglitchnig circuit and a novel inverse thermomeer decoder are proposed. To verify the performance, it is integrated with $0.25{\mu}m$ CMOS 1-poly 5-metal technology. The effective chip area is $1.56mm^2$ and power consumption is about 84mW at 2.5V power supply. The simulation and experimental results show that the glitch energy is 0.9pVsec at fs=100MHz, 15pVsec at fs=300MHz in worst case, respectively. Further, both of INL and DNL are within ${\pm}$1.5LSB, and the SFDR is about 45dB when sampling, frequency, is 300MHz and output frequency is 1MHz.

Synthesis of High Tc Superconductor YBa2Cu3O7-$\delta$ by Oxalate Coprecipitation Method I. Theoretical Considerations based on Analytical Chemistry (옥살레이트 공침전법에 의한 고온 초전도체 YBa2Cu3O7-$\delta$의 합성 I. 분석화학적 측면의 이론적 고찰)

  • 김배환;김배연;김창은;최진호
    • Journal of the Korean Ceramic Society
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    • v.26 no.1
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    • pp.91-99
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    • 1989
  • The concentrations of hydroxide, carbonate and oxalate for Y(III), Ba(II) and Cu(II) ions in an aqueous solution have been theoretically calcuated with respect to pH and their solubility diagram could be obtained. The optimum pH ofr oxalate coprecipitates at room temperature was estimated as<4, which was not influenced by carbonates and hydroxides in H2O solvent. The yield is dependent on the concentration of added oxalic acid, but the concentration of oxalic acid was fixed as 0.1M in this calculation for simplicity.

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Analysis on Distribution Characteristics of Mammals in Relation to Altitude in Juwangsan National Park (주왕산국립공원에 서식하는 포유동물의 고도에 따른 분포 특징의 분석)

  • Chung, Chul-Un
    • Journal of Ecology and Environment
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    • v.29 no.6
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    • pp.511-520
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    • 2006
  • The study analyzed the distribution of mammalia per altitude in Gamebong, the highest trail of Juwangsan National Park and confirmed the inhabitation of 22 different species inhabiting in the park. Starting from 200 m to 800 m above the sea level was segmented into 100 m unit. The result of analysis has shown that the Tamias sibiricus is the dominant specie throughout in all segments. Species confirmed to be inhabiting in all segments of research areas were Mustela sibirica, Caproelus pygargus and squirrel. By analyzing the confirmed Field Sign basing from the observation point, it has shown close relations between types of species and population following the increase in altitude (y=-0.0234 + 25.552, $R^2$=0.9296, $F_{0.05}$(1,4)=7.71, p<0.05). However, the result of analysis targeting nine species inhabiting in at least five out of six 100 m segmented units has shown that only two species, Apodemus sgrarius (y=-0.034X+25.2, $R^2$=0.905, $F_{0.05}$(1, 4)=38.169, p<.0.01) and Sciurus vulgaris (y=-0.0154X+ 12.819, $R^2$=0.781, $F_{0.05}$(1, 4)=14.270, p<0.05) were affected by the altitude. Therefore, it is judged that the distribution of species does not follow the altitude variation but follows the food conditions and the structure of habitat. The result of analysis of Box and Whisker Diagram had shown lowest quartile deviation($Q_U-Q_L$) in Nature Restoration Area that is located in $200{\sim}300m$ above the sea level, where hikers are prohibited from entering. In $500{\sim}600m$ above the sea level segment that has similar food environment and trail, it has shown the widest distribution. Further research is required on this segment for the excretion drops of Prionailurus bengalensis, a Grade II class of endangered species, were found on the trails.

Synthesis of $\beta$-Alumina By Oxalate Coprecipitation Method and Its Crystallization Behavior (Oxalate 공침법에 의한 $\beta$-Alumina 합성과 결정화 거동)

  • 박용민;양유철;김형욱;박성수;손영국
    • Journal of the Korean Ceramic Society
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    • v.32 no.4
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    • pp.455-461
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    • 1995
  • To investigate the synthesis of $\beta$-Al2O3 and its crystallization behavior by oxalate coprecipitation method, the optimum pH range for oxalate coprecipitates has been theoretically calculated from the solubility products and the equilibrium constans of each metal ionic species and their solubility diagram wa obtained. The optimum pH range for oxalate coprecipitates at room temperature was estimated as <4. In experiment, we found that the optimum condition for oxalate coprecipitates was pH<1, which was not doped with pH controller. The Na+ ions were easily exchanged for the NH4+ ions of NH4OH which was used as pH controller, and those NH4+ ions were supposed to affect the crystallization behavior of $\beta$-Al2O3. The thermal decomposition of all complexes was almost complete below 40$0^{\circ}C$. The primary product of the decomposition process was m-Al2O3, which transformed to $\beta$"- or $\beta$-Al2O3 at temperature higher than 100$0^{\circ}C$. We found that the powder prepared at 120$0^{\circ}C$ had only $\beta$"- and $\beta$-Al2O3.EX>-Al2O3.

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Change in Opto-electrical Characteristics in Poly[3-octylthiophene-co-3-(4-fluorophenyl)thiophene] according to the Copolymerization Ratio (Poly[3-octylthiophene-co-3-(4-fluorophenyl)thiophene]에서 공중합 비율에 따른 전기 광학적 특성의 변화)

  • 신선호;정애영;김주현;이후성;김동표
    • Polymer(Korea)
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    • v.25 no.3
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    • pp.399-405
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    • 2001
  • Poly[3-octylthiophene-co-3-(4-fluorophenyl)thiophene]s were synthesized in 2:1, 1:1, and 1:2 mole ratios, and organic electroluminescent devices were fabricated using the copolymers. The opto-electrical properties of the copolymers were studied by PL, EL spectra, I-V, and V-L curves of the organic electroluminescent devices in conjunction with the energy band diagrams which were obtained from the cyclic voltammogram and the electronic absorption spectra. The LUMO energy level of P(OT/FPT)(1:1) is the lowest as -3.35 eV. In the copolymers P(OT/FPT)(2:1) and P(OT/FPT)(1:1) the ${\lambada}_{max}$ in the PL and EL spectra red-shifted as the mole ratio of fluorophenyl group increased while in P(OT/FPT)(1:2) it showed a blue-shift. This indicates that the backbone chain is twisted due to the steric hinderance of the fluorophenyl group leading to shorter ${\pi}$-conjugation length. P(OT/FPT)(1:1) showed the highest EL intensity and the highest power efficiency among the three copolymers. In P(OT/FPT)(1:2) the roughness of the film surface causes unusually high local leakage current leading to the low efficiency of electroluminescence.

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Petrochemical study on the Daejeon-sa basalt in the Mt. Juwang area, Cheongsong (청송 주왕산지역 대전사 현무암의 암석화학적 연구)

  • 윤성효;이문원;고정선;김영라;안지영
    • The Journal of the Petrological Society of Korea
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    • v.9 no.2
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    • pp.84-98
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    • 2000
  • Daejeon-sa basalt in the Mt. Juwang area composed of 12 basalt flows alternate with 9 peperites and each basalt and peperite has the variety of thickness. Peperites yielded in Daejeon-sa basalt are mixed of basalt with reddish shale, of which textural type is globular peperite. Basalts yielded in Daejeon-sa basalt are massive basalt without vesicule, although sometimes vesicules are founded in upper within a flow unit. The basalt has mainly pseudomorph of olivine as phenocryst, and also plagioclase and clinopyroxene phenocryst. Matrix is mainly subophitic texture. The plotting result on the TAS diagram shows these basalts belong to the sub-alkaline, and it can be subdivided into calc-alkaline series on the basis of the diagram of Si02 vs. K20 and of alkali index vs. A1203 diagram. According to plots of wt.% oxides vs. wt.% MgO, abundances of A1203 and CaO increase with decreasing MgO while F ~ dOecre~ase . With decreasing MgO compatible elements decrease while incompatible elements increase. In spider diagram of MORB-normalized trace element patterns, HFS elements are nearly similiar with MORB, but LIL elements are enriched. Especially, contents of Ce, F: and Sm are enriched but Nb is depleted. In the chondrite-normalized REE patterns light REEs are enriched than heavy REEs. Tectomagmatic discrimination diagrams shows basalts in the study area are formed in the tectonomagmatic environment of subduction zone under continental margin. This result accord with characters of chemical composition mentioned above. Cr vs. Y diagram and CeM, vs. Ce diagram show that the primary magma of the basalts may formed by the about 15% partial melting of garnet-peridotite in the mantle wedge. After then, Daejeon-sa basalts may formed from evolved magma undergone mainly olivine fractional crystallization and contarnination of crustal materials before eruption.

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Preparation and Characterization of Liquefied Ibuprofen Using Self-Microemulsion Drug Delivery System (SMEDDS) (자가미세유화를 이용한 이부프로펜 액상제제의 제조와 특성)

  • Ahn, Yong-San;Song, Ji-Hee;Kang, Bok-Ki;Kim, Moon-Suk;Cho, Sun-Hang;Rhee, John-M.;Lee, Hai-Bang;Khang, Gil-Son
    • Journal of Pharmaceutical Investigation
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    • v.34 no.1
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    • pp.35-42
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    • 2004
  • Ibuprofen (IBU), is a non-steroidal anti-inflammatory drug, used to treat rheumatoid arthritis, removal of fever and mild to moderate pain. Because of small dosage and very low accumulation in the body, IBU has been used to heal children's fever. However, IBU was very low solubility in a low pH and water (in water $0.03{\sim}2.5$ mg/ml). A nanoemulsion containing IBU by means of self-microemulsion drug delver system (SMEDDS) was prepared in order to enhance the solubility of IBU. The SMEDDS was composed of cosurfactant, oil and surfactant The solubility of IBU in various components such as cosurfactant, oil and surfactant was examined. $Carbitol^{\circledR}\;(386.99{\pm}20.5\;mg/ml)$ as a cosurfactant, $Labrafil^{\circledR}$  M1944CS $(90.16{\pm}1.60mg/ml)$ as an oil and $Cremopher^{\circledR}$  RH-40 $(239.01{\pm}2.8\;mg/ml)$ as a surfactant were used in this study for preparing SMEDDS. Optimized formulation of SMEDDS was obtained by phase diagram which express the section of nanoemulsion formation. The SMEDDS containing IBU had higher dissolution rate than conventional IBU sirups. Thus the SMEDDS was a potential candidate of stable conventional and effective oral dosage form for IBU.

Evolutionary properties of red supergiants with MESA

  • Chun, Sang-Hyun;Jung, Moo-Keon;Kim, Dong uk;Kim, Jihoon;Yoon, Sung-Chul
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.1
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    • pp.42.1-42.1
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    • 2017
  • We investigate the evolutionary properties of red supergiant stars (RSGs), using stellar evolution model of Modules for Experiments in Stellar Astrophysics (MESA). In this study, we calculate models with mass range of 9-39M_sun and several different convection parameters (e.g. mixing length, overshooting, and semiconvection) at SMC, LMC, Milky Way, and M31 metallicities. We compare the calculated evolutionary tracks with observed RSGs in SMC, LMC, Milky Way and M31, and discuss appropriate input physical parameters in model calculation. We find that a larger mixing length parameter is necessary for M31 metallicity to fit the positions of RSGs in H-R diagram, compared to lower metallicity environments. Theoretically predicted numbers of yellow supergiant stars (YSGs) are also compared with the observed population. We find that Ledoux models with semiconvection can better explain the number of YSGs. Finally, we investigate the final radius, final star mass, and final hydrogen envelope mass of RSGs and discussed the their properties as type II-P supernova progenitors.

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The Separation and Recovery of Nickel and Lithium from the Sulfate Leach Liquor of Spent Lithium Ion Batteries using PC-88A

  • Nguyen, Viet Tu;Lee, Jae-Chun;Jeong, Jinki;Kim, Byung-Su;Pandey, B.D.
    • Korean Chemical Engineering Research
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    • v.53 no.2
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    • pp.137-144
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    • 2015
  • The present paper deals with the extractive separation and selective recovery of nickel and lithium from the sulfate leachate of cathode scrap generated during the manufacture of LIBs. The conditions for extraction, scrubbing and stripping of nickel from lithium were optimized with an aqueous feed containing $2.54kg{\cdot}m^{-3}$ Ni and $4.82kg{\cdot}m^{-3}$ Li using PC-88A. Over 99.6% nickel was extracted with $0.15kmol{\cdot}m^{-3}$ PC-88A in two counter-current stages at O/A=1 and pH=6.5. Effective scrubbing Li from loaded organic was systematically studied with a dilute $Na_2CO_3$ solution ($0.10kmol{\cdot}m^{-3}$). The McCabe-Thiele diagram suggests two counter-current scrubbing stages are required at O/A=2/3 to yield lithium-scrubbing efficiency of 99.6%. The proposed process showed advantages of simplicity, and high purity (99.9%) nickel sulfate recovery along with lithium to ensure the complete recycling of the waste from LIBs manufacturing process.