Park, Na-ri;Chang, Hyang-Youn;Lim, Hyun-Man;Ahn, Kwang-Ho;Kim, Weon-Jae
Journal of Korean Society of Environmental Engineers
/
v.39
no.1
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pp.40-49
/
2017
In this study, we have made the annual total phosphorus (TP) mass balance diagrams for I wastewater treatment plant by utilizing the data of flow rate and TP of each process and tried to choose the optimum unit process empirically for phosphorus recovery. For the applicability evaluation, we have suggested several quantitative indices of flow rate, TP concentration, TP load and SS. Based on the analyses of TP mass balance, it became clear for reducing TP load of the wastewater treatment plant that it is efficient to recover phosphorus from the side stream in which the amount of flow rate is just 1/16, but TP concentration and load are 78 and 4.8 times larger than those of the influent of the plant. After the detailed applicability evaluation for the side stream, it could be concluded that the unit process of waste activated sludge thickener supernatant or dehydration filtrate are appropriate. Meanwhile, we did fundamental experiments utilizing the dewatering filtrate with TP concentration of 141.5 mg/L. After adjusting pH 10 and $Ca^{2+}$ concentration 250, 500, 1000 mg/L, it was stirred slowly. As a result, the $PO_4-P$ and TP removal efficiencies were above 95 percent; the results of the experiment imply the applicability of phosphorus recovery process in a wastewater treatment plant strongly.
Zerovalent iron (ZVI) has been widely used in the removal of environmental contaminants from water. The objective of this research was to assess the efficiency of ZVI for immobilization of As (V) in the contaminated water under various chemical conditions. Batch-type experiments showed that the immobilization process followed a first-order kinetic model. Rate constant (k) of the reaction increased consistently and proportionally as increasing ZVI concentrations from 1% (0.158 $hr^{-1}$) to 3% (0.342 $hr^{-1}$), and temperatures from $15^{\circ}C$ (0.117 $hr^{-1}$) to $35^{\circ}C$ (0.246 $hr^{-1}$), respectively. Whereas the rate constant decreased as increasing As (V) concentrations from 1 mg $\Gamma^{-1}$ (0.284 $hr^{-1}$) to 3 mg $\Gamma^{-1}$ (0.153 $hr^{-1}$), and the initial pH from 3 (0.393 $hr^{-1}$) to 9 (0.067 $hr^{-1}$), respectively. Results demonstrated that As (V) in an aqueous solution was rapidly immobilized by ZVI treatments. Zerovalent iron was fast method for remediation of As (V) contaminated water.
Much of the plastic film house soils in the southern part of the Korean peninsula are managed using a upland-paddy rotation culture system (hereafter, RS) to prevent salt accumulation in soil. However, information on the effects of RS on soil properties and environmental conservation is limited. In order to determine the effects of RS on soil properties, 22 fields under RS and 20 fields under a non-rotation system (hereafter, NRS) in plastic film houses were selected in Chinju, in southern Korea, and the P distribution characteristics were investigated, including the chemical properties. The RS contributed to the removal of water-soluble salts in the surface layer and to the redistribution of organic matter evenly in the soil profile. In the AP horizon, available phosphorus levels were $1,611mg\;kg^{-1}$ in RS and $1,789mg\;kg^{-1}$ in NRS, which markedly exceeds the optimum range for plant cultivation. Total P was lower in RS (average $4,593mg\;kg^{-1}$) than in NRS (average $5,440mg\;kg^{-1}$) and this decrease was taken to be an effect of RS. Inorganic P was the predominant form of P in both systems, followed by organic P and residual P. A soil profile showed that total and inorganic P concentrations decreased with depth in both systems. However, organic P increased withdepth in RS, which was in contrast to that noted in NRS. The increase in organic P with depth in RS implied that organically rather than inorganically derived phosphate moved through the soil. The concentrations of water-soluble P, Ca-P and Al-P were higher in NRS than in RS soil profiles, but the Fe-P concentration was higher in RS than in NRS, which might be affected by the anaerobic conditions found in paddy soils. In both systems, the Al-P form of extractable P predominated in the surface layer, followed by Ca-P, Fe-P and water-soluble P. With increasing depth, the composition rate of Ca-P to extractable P decreased to less than 10% in the 60-70cm depth, as Fe-P dominated at this level. The content of water-soluble P, potentially the main source of eutrophication, was higher in NRS than in RS. These results indicated that the RS used in plastic film houses contributed to the removal of water-soluble salts but only slightly decreased the phosphate concentration.
An annular flow type of copper electrolysis reactor was setup in order to generate the copper ions to remove algae in water. The operating characteristics of the reactor and the effect of copper ion on algae have been considered. By controling the applied current, the copper ion concentration could be obtained as desired level and the faradaic efficiency was above 90%. When the flow rate was increased, the copper ion concentration was linearly decreased due to the dilution effect and the effect of concentration overpotential was insignificant. With the increase of pH in water, the copper ion concentration was linearly decreased and not affected by the conductivity of the water. The concentration of chlorophyll-a was sharply decreased with the increase of copper ion concentration. The algae was effectively removed as the copper ion concentration was above 0.2 ppm. There was no difference between the copper ions obtained by dissolving copper sulfate and those produced by copper electrolysis. The algae removal efficiency was above 90% after 5 days as the copper ion concentration was above 0.4 ppm.
Jeong, Joo Young;Park, Jeong Ho;Choi, Won Ho;Park, Joo Yang
KSCE Journal of Civil and Environmental Engineering Research
/
v.31
no.2B
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pp.187-192
/
2011
Nitrate nitrogen is common contaminant in groundwater aquifers, its concentration is regulated many countries below 10 mg/L as N (As per WHO standards) in drinking water. An attempt was made to get optimal results for the treatment of nitrate nitrogen in groundwater by conducting various experiments by changing the experimental conditions for ZVI bipolar packed bed electrolytic cell. From the experimental results it is evident that the nitrate nitrogen removal is more effective when the reactor conditions are maintained in acidic range but when the acidic environment changes to alkaline due to the hydroxide formed during the process of ammonia nitrogen there by increasing the pH reducing the hydrogen ions required for reduction which leads to low effectiveness of the system. In the ZVI bipolar packed bed electrolytic cell, the packing ratio of 0.5~1:1 was found to be most effective for the treatment of nitrate nitrogen because ZVI particles are isolated and individual particle act like small electrode with low packing ratio. It is seen that formation of precipitate and acceleration of clogging incrementally for packing ratio more than 2:1, decreasing the nitrate nitrogen removal rate. When the voltage is increased it is seen that kinetics and current also increases but at the same time more electric power is consumed. In this experiment, the optimum voltage was determined to be 50V. At that time, nitrate nitrogen was removed by 94.9%.
Between December 1979 and September 1989, 23 patients with craniopharyngioma who underwent surgery and postoperative radiation therapy were retrospectively evaluated to assess the efficacy of this management at the Department of Therapeutic Radiology, Seoul National University Hospital. Total removal of tumor was attempted in all patients. Of these, surgeons tried total removal in eight patients, but revealed residual mass by postoperative CT, and partial removal was done in 15 patients. The morphology of tumor on the operative finding was grouped into three types: cystic 13 ($57{\%}$), solid 4 ($17{\%}$), and mixed 6 ($26{\%}$). Cystic type was predominant in$\leq$20 years old group. Actuarial overall survival rates at 5 and 10 years were $95{\%}$ and $81{\%}$ respectively and actuarial tumor control rates were $74{\%}$ and $50{\%}$. Surgical extent was not related to the survival rates (p=0.41). Pediatric and adolescent patients (age of$\leq$20 years) had a trend of better survival than that of adult patients (p=0.10). The results indicated that limited surgical excision followed by radiation therapy is recommended when total excision is not possible.
A study on the purification of the surf clam Mactra Sulcataria REEVE for the remove of sand and fecal piles was conducted in the laboratory. The sand was mostly distributed around the inhalent and exhalent siphon, mantle and gill, and were also distributed in the digestive tract including the mid-gut gland. The sand particles in the digestive tract were extremely small and their sizes were about $180\times10\mu\;to\;550\times200\mu$. It could be seen that there was little, if any, difference in the rate of sand removal when either the hanging Purification method was used or the method of laying the surf clams in thick or thin layers on the bottom of the experimental vessel was used. The surf clam removed about $50\%$ of its sand during the first hour of purification. The weight of the removed sand and fecal piles on a dry basis reached a constant value after 22 to 26 hours of purification. After 42 hours of Purification, no sand could be seen in the fecal piles. The surf clam removed the sand in its body more rapidly when it was in sea water with the pH of 8.75 than when it was in natural sea water. Also high temperature had a much greater depressing effect upon the removal of sand In the surf clam than did natural sea water. Also low salinity had greater accelerating effect upon the removal of sand in the body than did natural sea water. However the surf clam died when the salinity was $8.19\%_{\circ}$.
Constructed wetland system was studied to treat wastewater from industrial complex in rural area. Pilot plant at the Baeksuk Nongkong Danzi in Chunahn-City was used for field study. For the DO, the effluent concentration was higher than the influent concentration and it implies that natural reaeration supplies enough oxygen to the system. For the SS, the effluent concentration was consistently lower than the water quality standard even though the influent concentration varied significantly, which showed that SS was removed by the system effectively which is consist of soil and plants. For the BOD and COD, the average removal rate of them were 56% and 43%, respectively, therefore, the effluent concentration could not meet water quality standards when influent concentration was high. The removal rate of BOD and COD can be improved by supplemental treatment in addition to this system if necessary. For the T-N and T-P, the influent concentration of them were lower than the water quality standards than no further treatment was needed. Overall, the result showed that constructed wetland system is a feasible alternative for the treatment of wastewater from industrial complex in rural area. For actual application of this system, further study on design factors including loading rate, removal mechanism, and temperature effects is required to meet water quality standard consistently. Compared to existing systems, this system is quite competitive because it requires low capital cost, almost no energy and maintenance, and therefore, very cost effective.
This study carried out submerged area due to Dam construction in the near future. It includes species classification of plant, survey of community structure, examination of pollutant load and assessment of water quality impact. The vascular plants of this area are listed 224 taxa; 64 families, 168 genera, 193 species, 30 varieties and 1 form. This study area is classified into total 21 communities, most community was consist of grass vegetation. Among the communities, Erigeron annuus ($869,286m^2$, 22%) community was dominant and Erigeron annuus-Avena fatua comminity (16%) was subdominant until May, and then Erigeron canadensis community occupied most area to $1,774,985m^2$ (32%) from May to July. For the evaluation of water quality impact due to submerged macrophyte, nutrient release test was conducted both dead body macrophyte and living body macrophyte. The results of release test show that T-N is not released at dead body macrophyte, but it is released at living body macrophyte, especially living body Artemisia priceps var. orientalis shows 1.436mgN/g. At release test of dead body macrophyte, T-P release rate of Erigeron annuus shows 0.500mgP/g at the top of them and it also shows 0.436mgP/g at Erigeron annuus of living body macrophyte. T-N load of submerged macrophyte shows 0.76% by comparison of total load on watershed and T-P load of that shows 3.61%. In case of removal macrophyte for reduction of pollutant load in submerged area, T-N load of submerged macrophyte changes from 0.76% to 0.15% by comparison of total load on watershed and T-P load of that changes from 3.61% to 0.72%.
In this study, the distribution characteristics according to the type of BOD and the effect of nitrogenous oxygen demand (NOD) and algal oxygen demand on BOD in three streams (Bokhacheon, Byeongseongcheon, and Gulpocheon) were evaluated. Although the BOD and NOD concentrations demonstrated a difference in the three streams, the carbonaceous BOD(CBOD)/BOD ratio was 0.75 (p=0.053, one-way ANOVA), and there was no significant difference in the three streams (r2≥0.92, p<0.0001). The NOD concentration of the Bokhacheon with high NH3-N was 1.7±1.3 mg/L, which was the highest among the three streams and showed a significant correlation with BOD. Seasonal variations in NOD in the three streams did not show a significant correlation with changes in NH3-N concentration (r2<0.28, p≥0.1789), and there was no significant difference in NOD even though NH3-N concentration in Gulpocheon was about twice that of Byeongseongcheon (p=0.870, one way ANOVA). The particulate CBOD(PCBOD)/CBOD ratio of the three streams was 0.55~0.64, and about 60% of the biodegradable organic matter was present in the particulate form. When the Chl.a concentration in the stream was more than 7 ㎍/L, the PCBOD tended to increase with the Chl.a concentration (r2=0.61, p=0.003). In the three streams, particulate NOD accounted for 81% of NOD; however, despite the large variation in NH3-N concentration (0.075~3.182 mg/L), there was no significant difference in soluble NOD(SNOD) concentration that ranged from 0.1 to 0.3 mg/L. In this study, the low contribution rate of SNOD to NOD is considered as a result of the removal of nitrifying bacteria along with the particles during the filtration process.
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