• Title/Summary/Keyword: P Constant

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The operating characteristics of strain-compensated 1.3$\mu$m GaInAsP/InP uncooled-LD with the structure of multiple quantum well and separate confinement heterostructure layers (응력완화 1.3$\mu$m GaInAsP/InP uncooled-LD의 다중양자우물층과 SCH층 구조에 따른 동작 특성)

  • 조호성;박경현;이정기;장동훈;김정수;박기성;박철순;김홍만;편광의
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.7
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    • pp.185-197
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    • 1996
  • We have adopted the strain compensated PBH(planar buried heterostructure) - LD in which the MQW active layer consisted of 1.4% compressively strained GainAsP (E$_{g}$ = 0.905eV) wells and 0.7% tensile strained GaInAsP(E$_{g}$ = 1.107eV) barriers grown by metal organic vapor phase epitaxy (MOVPE). We hav einvestigated effects of number of wells and the structure of the separate confinement heterostructure (SCH) layer in the strain-compensated MQW-PBH-LD. The threshold current, the external quantum efficiency, the transparency current density J$_{o}$, and the gain constant .beta. have been evaluated for uncoated MQW-PBH-LD. As the number of wells increases, the internal quantum efficiency and the transparency current density decreases, whereas the gain contant increases. The small width of the SCH layer shows the large internal quantum efficiency. The small internal loss and the large gain constant have been obtained by inserting the large bandgap SCH layer.

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A Study on the pH Characterization for Microbial Fermentation in Tomato Juice (토마토 주스의 미생물 발효 산도 특성에 관한 연구)

  • Choi, S.M.;Supeno, D.;A., Okka;Chung, S.W.;Kim, H.S.;Kim, J.S.;Park, J.M.;Kwon, S.H.;Kwon, S.K.;Choi, Won Sik
    • Journal of the Korean Society of Industry Convergence
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    • v.17 no.3
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    • pp.170-177
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    • 2014
  • This study was conducted to know the behavior of pH behavior in the tomato juices to find out an effective medium for microbial cultivation. Bacterial culture media is a material consist a mixture of nutrients used to grow microorganisms on or in it. In addition, microbial culture media can also be used for isolation, propagation, testing the nature physiological, and calculation of the number of microorganisms. Fresh tomato juice is used for basic ingredient, therein added salt, sugar and EM (Effective Microbial). The fermented solution placed in a room with a temperature of 40oC. Data retrieval before the pH value reached a constant value is done every 12 hours, after constant rate data collection was done every 24 hours. The pH value has been steady after 372 hours of fermentation process (15.5 days). From the results obtained that the amount of additional ingredient which added into tomato juice does not affect final pH value of solution. Thereby the most effective treatment for microbial cultivation media is treatment number four.

Electrical Properties and Fabrication of Ultra-thin Films using p-HP Polymer (p-HP 고분자 LB초박막의 제작과 전기적 특성)

  • Yu, Seung-Yeop;Jeong, Sang-Beom;Park, Jae-Cheol;Gwon, Yeong-Su
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.7
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    • pp.287-291
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    • 2002
  • We fabricated the crosslinked films using p-hexadecoxyphenol (p-HP), which is amphiphilic and can form polyion complexes with formaldehyde at the air-water interface. The behavior of polyion complexation at the air-water interface and the surface structure of LB films was investigated by Brewster angle microscope(BAM) and scanning Maxwell-stress microscope (SMM), respectively. Also, the electrical properties for crosslinking in phenol-formaldehyde LB films were investigated by measuring conductivity and dielectric constant. The conductivities of p-HP LB films are as follows: heat-treatment of 1% formaldehyde subphase(3.76$\times$10$^{-15}$ ~4.76$\times$10$^{-1}$5[S/cm])$\times$10$^{-14}$ ~1.74$\times$10$^{-14}$ [S/cm]). Also, relative dielectric constants of p-HP LB films were reduced from 6.76~7.84 (pure water) to 2.97~3.25 (heat-treatment of 1% formaldehyde subphase))

Kinetics and Mechanism of Nucleophilic Substitution Reaction of 4-Substituted-2,6-dinitrochlorobenzene with Benzylamines in MeOH-MeCN Mixtures

  • Kim, Young-Sun;Choi, Ho-June;Yang, Ki-Yull;Park, Jong-Keun;Koo, In-Sun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3279-3282
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    • 2010
  • The reaction rates of 4-X-2,6-dinitrochlorobenzenes (X = $NO_2$, CN, $CF_3$) with Y-substituted benzylamines (Y = p-$OCH_3$, p-$CH_3$, H, p-Cl) in MeOH-MeCN mixtures were measured by conductometry at $25^{\circ}C$. It was observed that the rate constant increased in the order of X = $NO_2$ > CN > $CF_3$ and in the order of Y = p-$OCH_3$ > p-$CH_3$ > H > p-Cl. When the solvent composition was varied, the rate constant increased in the order of 100% MeOH < 50% (v/v) MeOH-MeCN < 100% MeCN. These results may be ascribed to the formation of hydrogen bonds between the alcoholic hydrogen and nitrogen of benzylamines in groud state (GS). We conclude that the reaction takes place via $S_NAr$ base on the transition state parameters ${\rho}x$, ${\rho}Y$, $\beta_{nuc}$, and solvent effects.

Determination of Dissociation Constant of Hydrogen Cupferrate in Methanol-Water and 2-Propanol-Water Solution (Methanol-물 및 2-Propanol-물의 混合溶媒에서의 Hydrogen Cupferrate의 酸解離常數의 決定)

  • Si-Joong Kim;Chang-Ju Yoon;In-Soon Chang
    • Journal of the Korean Chemical Society
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    • v.10 no.3
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    • pp.119-128
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    • 1966
  • The glass electrode was empirically calibrated in methanol-and 2-propanol-water mixed solvents, by means of which the pH-meter reading could be converted to stoichiometric hydrogen ion concentration. The thermodynamic dissociation constants of hydrogen cupferrate in methanol-and 2-propanol-water solution were potentiometrically determined with the changes in composition of organic solvents at 0.01 and 0.05 of the ionic strength and 25$^{\circ}C$. The empirical formula of the constants with mole fraction (n) of the organic solvent are as follow: methanol-water solution $pK_a$= 2.24n + 4.29 at ${\mu}$ = 0.01 n = 0.0476∼0.642 $pK_a$ = 2.35n + 4.38 at ${\mu}$ = 0.05 n= 0.0446~0.642 2-propanol-water solution $pK_a$= 5.50n + 4.48 at ${\mu}$ = 0.05 n = 0.0253~0.259 The relationships between $pK_a$ of acetic acid, propionic acid and HCup and dielectric constant of some mixed solvents were discussed. It would be considered that the factors effecting $pK_a$ value of weak acid in mixed-solvent are not only dielectric constants but acid-base character and solvation effect of the solvent, etc.

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The Clinical Outcomes of Arthroscopic Repair of Isolated type II SLAP Lesion in Non-athletes (비 운동선수에 있어 단독 제 2형 SLAP 병변의 관절경적 봉합수술의 임상적 결과)

  • Yoo, Jae-Chul;Ahn, Jin-Hwan;Koh, Kyoung-Hwan;Kim, Seung-Yeon
    • Journal of the Korean Arthroscopy Society
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    • v.12 no.3
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    • pp.185-190
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    • 2008
  • Purpose: The purpose of this study is to provide the clinical outcomes of arthroscopic type II SLAP repair in non-athletes, and to compare the clinical outcomes between those who had isolated type II SLAP lesion and those who had combined partial thickness supraspinatus tear that did not required a combined repair. Materials and Methods: From July 2005 to January 2007, 142 consecutive type II SLAP lesions were treated with arthroscopic surgery. The inclusion criteria for the study were; (1) younger than 50 years old; and (2) non-athletes. Exclusion criteria were; (1) prior surgery, fracture or combined recurrent dislocation history on the affected shoulder; (2) combined full thickness rotator cuff tear or PTST (>50% thickness) patient that needed repair; and (3) combined infection, arthritis or inflammatory disease. Remaining 19 patients meet the criteria. Among them, 13 had combined PTRCT that did not require repair (Group I), and 6 had isolated type II SLAP lesion without combined supraspinatus tear (Group II). The mean age was 36.7 years (29~49 years), mean symptom duration was 39.1 months (3~216 months) and mean follow-up was 19.0 months (12~27 months). In all patients, the range of motion of affected shoulder, pain and function visual analogue scale (PVAS, FVAS), the Constant score and UCLA score were evaluated preoperatively and postoperatively. Results: In group I, external rotation at side was decreased significantly (p=0.003),but there were no statistical significant change at the remains(p>0.05). And there were no differences between groups (p>0.05). At the final follow-up, all clinical outcome measurements improved after surgery with statistical significance (p<0.05): UCLA score, $22.8{\pm}5.2$ to $32.8{\pm}2.1$; Constant score, $79.4{\pm}8.6$ to $94.9{\pm}4.3$; PVAS $5.4{\pm}2.7$ to $1.1{\pm}1.4$; FVAS $63.2{\pm}15.3$ to $93.4{\pm}7.3$. But, in group comparison of the mean UCLA score and Constant score, there were no statistical significant differences between two groups. Conclusion: Arthroscopic repair of type II SLAP lesion provided good clinical outcomes in nonathletic population. Combined partial thickness supraspinatus tear does not seem to hamper the final outcome at minimal 1 year follow-up.

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L2-NORM ERROR ANALYSIS OF THE HP-VERSION WITH NUMERICAL INTEGRATION

  • Kim, Ik-Sung
    • Bulletin of the Korean Mathematical Society
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    • v.39 no.1
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    • pp.9-22
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    • 2002
  • We consider the hp-version to solve non-constant coefficient elliptic equations with Dirichlet boundary conditions on a bounded, convex polygonal domain $\Omega$ in $R^{2}.$ To compute the integrals in the variational formulation of the discrete problem we need the numerical quadrature rule scheme. In this paler we consider a family $G_{p}= {I_{m}}$ of numerical quadrature rules satisfying certain properties. When the numerical quadrature rules $I_{m}{\in}G_{p}$ are used for calculating the integrals in the stiffness matrix of the variational form we will give its variational fore and derive an error estimate of ${\parallel}u-\tilde{u}^h_p{\parallel}_0,{\Omega}'$.

A Study on the Effects of the Dissociation Constant of Edible Tar Pigment. I (혼합용매중(混合溶媒中)에서의 식용(食用) Tar색소(色素)의 해리정수(解離定數)에 관(關)한 연구(硏究) (제 1 보)(第 1 報) -2',4',5',7'- Tetraiodofluorescein Sodium염(鹽)에 대(對)하여-)

  • Kim, Bak-Kwang;Lee, Min-Hwa;Cho, Young-Mee;Kim, Kil-Su;Moon, Dong-Chul
    • Journal of Pharmaceutical Investigation
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    • v.10 no.3
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    • pp.14-19
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    • 1980
  • The dissociation constant of erythrosine in the mixed solvent systems of water-alcohols and water-acetone at various pH and in concentration media were determined by spectrophotometric method. Methanol, ethanol, and acetone were employed as solvents and studied the changes of pK values of erythrosine according to the kind and change of concentration of organic solvent which is mixed into water solution. The effect of organic solvent on pK is negligible at 40% while in the case of above 40% mixing, it is not negligible.

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Study on the Rheological Properties of Saccharide Solutions (당용액(糖溶液)의 유동학적(流動學的) 성질(性質)에 관(關)한 연구(硏究))

  • Yu, Bong-Shin
    • Journal of Pharmaceutical Investigation
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    • v.5 no.3
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    • pp.43-49
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    • 1975
  • The rheological properties of seven mixed sugar solutions of glucose, fructose, maltose, sucrose, and two kinds of honey, the chestnut and the acacia, were discussed. The fluidity of the above samples were studied by using the applied pressure horizontal viscometer with which glycerine was confirmed to be a Newtonian flow at $25^{\circ}C$. Time required to pass the constant volume of the sample fluids through the capillary was measured at various pressure differences, ${\Delta}p$, and the ${\Delta}p$ vs ${\Delta}p{\cdot}t$ in the Poiseuille equation was plotted. Shear rate against shearing stress, on the other hand, was plotted for the sample fluids and it was found that all the sample fluids have shown a Newtonian behavior. It was interesting to note that the shear viscosity increased as the concentration of sugar solutions increased, and as the concentration of sucrose became higher than that of maltose, although the total concentration of sugar solution is constant.

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Anisotropic stress Effects in p-n junction (p-n 접합에 있어서의 비등방성 응력효과)

  • 손병기;이건일
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.11 no.3
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    • pp.22-26
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    • 1974
  • The effects of anisotropic mechanical stress applied normal to the surface of p-n junctions have been investigated. As the stress increased, the breakdown voltage was decreased and the breakdown mode became softer. Within a certain limitation in the applied stress, the above phenomena werw reversibbe, though relaxation and hysteresis phenomena were observed. The time constant of relaxation depended upon the shape of the stressing tip, but for the given tip and device a unique time constant was obtained. The stress.dependence of breakdown voltage showed a good linearity up to about 3.0${\times}10^4$ kgw/$\textrm{cm}^2$, when the flat tip of radius 15$\mu$ was used, and the temperatere-dependence of breakdown voltage under the stress also showed a good linearity in the temperature range of 100 to $300^{\circ}K$.

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