• Title/Summary/Keyword: P&O

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Fabrication and Characteristics of $Al_2O_{3p}$/AC8A Composites by Pressureless Infiltration Process (무가압함침법에 의한 $Al_2O_{3p}$/AC8A 복합재료의 제조 및 특성)

  • 김재동;고성위;정해용
    • Composites Research
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    • v.13 no.6
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    • pp.1-8
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    • 2000
  • The fabrication Process of $Al_2O_{3p}$/AC8A composites by pressureless infiltration technique and the effects of additive Mg content and volume fraction of particulate reinforcement on mechanical and wear properties were investigated. It was found that the bending strength decreased with increasing volume fraction of $Al_2O_{3p}$ particles. Whereas hardness increased with volume fraction of $Al_2O_{3p}$ particles. The decrement of strength in case of high volume fraction of $Al_2O_{3p}$ particles was attributed to high porosity level. In terms of additive Mg content, $Al_2O_{3p}$/AC8A composites containing around 5~7wt% of additive Mg indicated the highest strength, and hardness values increased with additive Mg contents. Wear resistance of AC8A alloy were improved by reinforcement of $Al_2O_{3p}$ particles especially at high sliding velocity. Wear property of $Al_2O_{3p}$/AC8A composites and AC8A alloy exhibited different aspects. $Al_2O_{3p}$/AC8A composites indicated more wear loss than AC8A alloy at slow velocity region. However a transition point of wear loss was found at middle velocity region which shows the minimum wear loss and wear loss at high velocity region exhibited almost same value as at slow velocity region, whereas wear loss of AC8A alloy almost linearly increased with sliding velocity. It was found that $Al_2O_{3p}$/AC8A composites containing $Al_2O_{3p}$ volume fraction of 20% exhibited abrasive wear surface regardless of sliding velocity and $Al_2O_{3p}$/AC8A composites containing $Al_2O_{3p}$ volume fraction of 40% showed slightly adhesive wear surface at low sliding velocity, and it progressed to severe wear as increasing the sliding velocity.

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Effect of Zinc Vacancy on Carrier Concentrations of Nonstoichiometric ZnO

  • Kim, Eun-Dong;Bahng, Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05b
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    • pp.17-21
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    • 2001
  • We proposed that concentrations of cartier electron as well as ionized donor defects in nonstoichiometric ZnO are proportional to $P^{-1/2}_{O_2}$, whenever they ionizes singly or doubly, by employing the Fermi-Dirac (FD) statistics for ionization of the native thermal defects $Zn_i$ and $V_o$. The effect of acceptor defect, zinc vacancy $V_{Zn}$made by the Frenkel and Schottky disorder reactions, on carrier concentrations was discussed. By application of the FD statistics law to their ionization while the formation of defects is assumed governed by the mass-action law, the calculation results indicate; 1. ZnO shows n-type conductivity with $N_D>$N_A$ and majority concentration of $n{\propto}\;P^{-1/2}_{O_2}$ in a range of $P_{O_2}$, lower than a critical value. 2. As the concentration of acceptor $V_{Zn}$ increases proportional to $P^{1/2}_{O_{2}}$, ZnO made at extremely high $P_{O_{2}}$, can have p-type conductivity with majority concentration of p ${\propto}\;P^{-1/2}_{O_{2}}$. One may not, however, obtain p-type ZnO if the pressure for $N_{D}<$N_{A}$ is too high.

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Electric properties Analysis and fabrication of ZnO:As/ZnO:Al homo-junction LED (ZnO:As/ZnO:Al homo-junction LED의 제조와 전기적 특성 분석)

  • Kim, Kyeong-Min;So, Soon-Jin;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.55-56
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    • 2007
  • The p-type ZnO thin film, fabricated by means of the ampoule-tube method, was used to make the ZnO p-n junction, and its characteristics was analyzed. The ampoule-tube method was used to make the p-type ZnO based on the As diffusion, and the hall measurement was used to confirm that the p-type is formed. the current-voltage characteristics of the ZnO p-n junction were measured to confirm the rectification characteristics of a typical p-n junction and the low leakage voltage characteristics. Using the ampoule-tube to fabricate the p-type ZnO will provide a very useful technology for producing the UV ZnO LED and ZnO-based devices.

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Electrochemical Properties of $Li_{2}O-P_{2}O_{5}-V_{2}O_{5}$ Glass-ceramics for cathode Material (정극재료용 $Li_{2}O-P_{2}O_{5}-V_{2}O_{5}$계 결정화 유리의 전기화학적 특성)

  • 손명모;이헌수;김종욱;김윤선;구할본
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.8
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    • pp.652-657
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    • 2001
  • Vanadate glasses containing 10~20mol% glass former, P$_2$O$_{5}$ were prepared by melting the batch in platinum crucible and quenching on the copper plate. Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics having LiV$_3$O$_{8}$ were obtained by heat-treatment of this glass in crystallization temperature. The glass-ceramics showed singnificantly good capacity and long cycles life according to heating condition. In this paper, we described electrochemical properties during crystallization process and found the best crystallizaton condition of Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass as cathode material. Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics heat-treated at 233$^{\circ}C$ for 3 hors showed good rechargeable capacity of 220mAh/g in the cycling range between 2.0 and 3.9V.en 2.0 and 3.9V.

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Analysis on the V-I Curve of ZnO:As/ZnO:Al homo-junction LED (ZnO:As/ZnO:Al homo-junction LED의 V-I 특성 분석)

  • Oh, Sang-Hyun;Jeong, Yun-Hwan;Liu, Yan-Yan;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.410-411
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    • 2007
  • To investigate the ZnO LED which are interested in the next generation of short wavelength LEDs and Lasers, the ZnO thin films were deposited by RF magnetron sputtering system. The p-type ZnO thin film, fabricated by means of the ampoule-tube method, was used to make the ZnO p-n junction, and its characteristics was analyzed. The ampoule-tube method was used to make the p-type ZnO based on the As diffusion, and the hall measurement was used to confirm that the p-type is formed. the current-voltage characteristics of the ZnO p-n junction were measured to confirm the rectification characteristics of a typical p-n junction and the low leakage voltage characteristics. Analysis of ZnO LED V-I curve will provide a very useful technology for producing the UV ZnO LED and ZnO-based devices.

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Electro-chemical properties of $Li_{2}O=P_{2}O_{5}-V_{2}O_{5}$ Glass-ceramics for Cathode Materials (정극재료용 $Li_{2}O=P_{2}O_{5}-V_{2}O_{5}$ 계 결정화 유리의 전기화학적 특성)

  • 손명모;이헌수;구할본;김윤선
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.295-298
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    • 2000
  • Vanadate glasses in the Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ system containing 10~20mo1% glass former, P$_2$O$_{5}$ were prepared by melting the batch in pt. crucible followed by quenching on the copper plate. We found that Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ g1ass-ceramics obtained from crystallization of glass showed significantly higher capacity and longer cycle life than Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ g1ass. In the present paper, we describe electro-chemical properties during crystallization process and find the best crystallization condition of Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ g1ass as cathod material. Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics shows superior rechargeable capacity of 220 mAh/g in the cycling between 2.0 and 3.9V. between 2.0 and 3.9V.

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Electrochemical properties and crystallization of $Li_{2}O-P_{2}O_{5}-Bi_{2}O_{3}-V_{2}O_{5}$ Glass ($Li_{2}O-P_{2}O_{5}-Bi_{2}O_{3}-V_{2}O_{5}$ 유리의 결정화와 전기화학적 특성 변화)

  • Son, Muong-Mo;Lee, Heon-Soo;Gu, Hal-Bon;Kim, Yun-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.550-553
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    • 2001
  • $Li_{2}O-P_{2}O_{5}-Bi_{2}O_{3}-V_{2}O_{5}$ glass containing glass former, $P_{2}O_{5}$ and $Bi_{2}O_{3}$ was prepard by melting the glass batch in pt. erucible followed by guenching on the copper plate. We found that $Li_{2}O-P_{2}O_{5}-Bi_{2}O_{3}-V_{2}O_{5}$ glass-ceramics obtained from the crystallization of glass showed signifieantly higher capacity and longer cycle life tham $LiV_{3}O_{8}$ made from powder synthesis. In this paper, we described crystallization process and $LiV_{3}O_{8}$ crystal growth in glass matrix by increasing temperature. The electrochemical properties were strongly affected by $LiV_{3}O_{8}$ crystal growth in matrix

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Electrochemical properties and crystallization of $Li_{2}O-P_{2}O_{5}-Bi_{2}O_{3}-V_{2}O_{5}$ Glass ($Li_{2}O-P_{2}O_{5}-Bi_{2}O_{3}-V_{2}O_{5}$유리의 결정화와 전기화학적 특성 변화)

  • 손명모;이헌수;구할본;김윤선
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.550-553
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    • 2001
  • Li$_2$O-P$_2$O$_{5}$-Bi$_2$O$_3$-V$_2$O$_{5}$ glass containing glass former, P$_2$O$_{5}$ and Bi$_2$O$_3$ was prepard by melting the glass batch in pt. erucible followed by quenching on the copper plate. We found that Li$_2$O-P$_2$O$_{5}$-Bi$_2$O$_3$-V$_2$O$_{5}$ g1ass-ceramics obtained from the crystallization of glass showed significantly higher capacity and longer cycle life tham LiV$_3$O$_{8}$ made from powder synthesis. In this paper, we described crystallization process and LiV$_3$O$_{8}$ crystal growth in glass matrix by increasing temperature. The electrochemical properties were strongly affected by LiV$_3$O$_{8}$ crystal growth in matrix.rowth in matrix.

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Dissolution Properties of $K_2O$-CaO-$P_2O_5$ Glasses With Fe, Cu, Zn ($K_2O$-CaO-$P_2O_5$계 유리의 Fe, Cu, Zn 첨가에 따른 용출 특성)

  • Kim, Ki-Min;Kang, Won-Ho
    • Proceedings of the KAIS Fall Conference
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    • 2008.11a
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    • pp.459-462
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    • 2008
  • 본 논문에서는 $10K_2O$-30CaO-$60P_2O_5$ mol%를 기본조성으로 하여 Fe, Cu, Zn의 미량성분을 첨가하여 유리를 제조하고 용출 특성을 평가 하였다. 제조된 유리는 미량성분의 첨가량에 따라 유리의 투명도가 변하는 것이 관찰되었다. 용출특성은 측정 4시간 뒤 pH값 증가되는 것으로 16시간 후 pH가 증가하는 것으로 관찰되었다. 여기서 pH의 증가는 염기성산화물이 용출되는 것으로, 감소는 $P_2O_5$구조인 망목형성구조가 붕괴되어지면서 산성이온이 용출되어지는 것으로 판단되어진다. ICP관찰시에는 함량이 증가하면서 K, Ca, P이온의 용출량이 감소되었고, Zn, Cu, Fe이온의 용출량이 증가하는 경향이 관찰되었다.

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Studies on the N , $P_2O_5$ and $K_2O$-Application in the Mixed Sward of Alfalfa-Grass II. Effect of Phosphate fertilization levels on dry matter and nutrition yeild of forage in the mixed sward alfalfa-grasses (Alfalfa-Grass 혼파초지에 대한 3요소 시비 연구 II. 인산질비료의 시용수준이 alfalfa-grass 혼파초지의 건물 및 양분수량에 미치는 영향)

  • 박근제;김영진;최기준;이필상
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.16 no.1
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    • pp.47-52
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    • 1996
  • To investigate the effects of phosphate($P_2O_5$) fertilization levels on the dry matter(DM) yield, nutrition yield, and $P_2O_5$ efficiency of forages in mixed sward of alfalfa-grasses, a field experiment arranged by randomized complete block design with five treatments(0, 50, 100, 150 and 200kg $P_2O_5$/ha) was conducted at Livestock Experiment Station in Suwon, September, 1990 to Feb~ary, 1993. During two years, average DM yields of forages increased as $P_2O_5$ fertilization level was increased, but no significant difference was found between DM 10,754kg of $P_2O_5$ 150kg/ha and DM 10,845kg of $P_2O_5$ 200kg/ha. Cmde protein and energy productivity of forages increased as $P_2O_5$ fertilization level was increased, and the increasing degree was highest between $P_2O_5$ l00kg and 150kg/ha feriilization. With increasing $P_2O_5$ fertilization, mineral contents tended to increase in P, K and WCa+ Mg equivalent ratio, but not to be regular in the other elements. Efficiency of $P_2O_5$ was highest at $P_2O_5$ 150kg/ha fertilization, which produced DM 12.8kg. net energy lactation 75.4MJ. starch equivalent 6.lkStE, and total digestible nutrients 8.6kg per Ikg $P_2O_5$.

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