• Title/Summary/Keyword: Ozone recycling system

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Development of a Micro-Bubble System for Ozone Off-Gas Recycling in the Ozone Treatment Process (오존처리공정의 배오존 재활용 마이크로버블시스템 개발)

  • Young-Man, Cho;Jae-Ouk, Jung;Kwang-Heon, Lee;Yong-Jun, Jung
    • Journal of Environmental Science International
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    • v.31 no.12
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    • pp.1061-1068
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    • 2022
  • The purpose of this study was to develop a recycling system for ozone off-gas. Although the ozone transmission rate of the injector method differs slightly depending on the ozone injection rate, it reaches approximately 99%, which is very high. During the increase in water inflow to the ozone recycling system from 2 L/min to 10 L/min, the average ozone recycling rate was 99.4% at a 1 ppm ozone injection rate, 98.6% at a 2 ppm ozone injection rate, 98.1% at a 3 ppm ozone injection rate. Ozone treatment facility operating costs can be divided into the costs of pure oxygen production, ozone production, and maintenance. The annual operating costs of ozone treatment facilities in Korea are estimated to be approximately 38.9 billion won. The annual savings are estimated to be approximately 5.8 billion won when the ozone transfer rate of the diffuser method, which is mostly employed in domestic water treatment plants, is 85% and 15% of the ozone is recycled.

Effect of Wet Milling on Scum Generation and Solubilization in Batch Ozone Reaction Using Digested Sludge (소화슬러지를 이용한 회분식 오존반응 시 습식분쇄가 스컴 생성과 가용화에 미치는 영향)

  • Hong, Seong-Min;Lee, Dong-Hoon;Kim, Choong-Gon;Shin, Hyun-Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.2
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    • pp.13-18
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    • 2019
  • Sewage sludge treatment is increasing every year due to improvement of living and urbanization. However, interest in anaerobic digestion which is one of the recycling technology. There is anaerobic digestion of increasing due to limitations of ocean dumping and final disposal. But, the limit of anaerobic digestion efficiency due to the advanced treatment of sewage has been limited, and studies for solubilization technology have been actively conducted. Therefore, in this study, we aimed to investigate the variation of generation of scum and the solubilization efficiency in the application of pre-treatment of ozone reaction and the change of properties of digested sludge with wet milling. There are results of VS/TS increased by 4.4% and $SCOD_{cr}/TCOD_{cr}$ increased by 9.4% by wet milling alone. In addition, the increase of the specific surface area due to which the reduction of the particle size of the solid content of the sludge in the ozone reaction caused by wet milling decreased the generation rate of scum at 14.3% and increased VS/TS at 2.1%, compared with the ozone reaction alone. From these results, it is expected that the application of wet milling can be increased the contact efficiency with solids in the sludge during ozone reaction with suppress scum and increase the efficiency of the subsequent process in anaerobic digestion.

Development of Institutional System for Efficient Recycling of Waste Plastic (폐플라스틱 재자원화 활성화를 위한 제도 개선 방안에 관한 연구)

  • Chung, Jae-Chun;Park, Chan-Hyuk;Lee, Jae-Woong;Kim, Young-Jun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.11 no.1
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    • pp.138-148
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    • 2003
  • In the study, current status of waste plastic recycling was investigated. Some factors to obstruct recycling of waste plastic was analyzed. These factors include the difficulty of obtaining location and man power, unclear marking of recyclable plastic and inefficient rate in producer and consumer deposit system. Life cycle assessment(LCA) study was performed to investigate the environmental impact of waste plastic(PET) recycling. When the recycled raw plastic material is used together with the virgin raw plastic material, all the environmental impact showed (-) value except ozone depletion impact category. The environmental avoided impact was the greatest in the global warming impact category. For active promotion of recycling activity, source separation system of waste plastic should be established first of all. Also, marking system of the recycling waste plastic should be made more clear so that consumers can understand it easily. Other strategies include the determination of decent rate for producer and consumer deposit system, establishment of infrastructure and information system for waste plastic recycling and citizen's cooperation through intensive public education.

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Control of Soybean Sprout Rot Caused by Pythium deliense in Recirculated Production System

  • Yun, Sung-Chul
    • The Plant Pathology Journal
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    • v.19 no.6
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    • pp.280-283
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    • 2003
  • A soybean-sprout rot epidemic occurred in a mass production soybean sprout factory in 2000 and 2001 in Korea, which caused up to 20% production loss. Among the causal pathogenic bacteria and fungi, Pythium deliense was found to be the dominant pathogen of severe root and hypocotyls rot, particularly in recirculating water system. An average of 90% of the isolated fungi from the rotted sprout on potato dextrose agar were Pythium sp. The fungal density of Pythium in the sampled water was monitored in the recycled water system for 1 year using a selective medium (com meal agar with Pimaricin, 10 mg; Rifampicin, 10 mg; and Ampicillin, 100 mg per 1 liter). The drained water from the soybean-sprout cultivation always had a certain amount of fungus in it. The removal of Pythium from the recycling water system must be thorough, safe, and environment friendly. However, the pathogen in the water was easily found even after ozone and chlorine treatments, which were devised on the recycling system for the removal of microorganisms. 5-$\mu\textrm{m}$ pore size filter was applied and was able to successfully control the disease. As the sprout industry increasingly shifts into mass production, the demand for water will increase continuously. Recycling water for sprout production is eco-friendly. However, a process must be devised to be able to first decompose organic matters before Pythium zoospores are filtered.

Effect of Ozone Application on Sulfur Compounds and Ammonia Exhausted from Aerobic Fertilization System of Livestock Manure (가축분뇨 호기적 퇴.액비화시 발생하는 기체 중의 황 화합물과 암모니아에 대한 오존처리 효과)

  • Jeong, Kwang Hwa;Whang, Ok Hwa;Khan, Modabber Ahmed;Lee, Dong Hyun;Choi, Dong Yoon;Yu, Yong Hee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.20 no.4
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    • pp.118-126
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    • 2012
  • In this study, two types of ozone generating experimental instrument were installed in commercial livestock manure fertilization facility, which can treat hundred tons of pig manure in a day. Gas samples to be treated were collected from the upper part of the liquid fertilization system and composting system of the commercial livestock manure fertilization facility. The gas sample was flowed to oxidation reactor through pipe line by suction blower, therefore, contacted with ozone. Ammonia and sulfur compounds of gas samples collected from the inlet and outlet point of the experimental instrument were analyzed. The oxidation effect by the contact with ozone was higher in sulfur compounds than ammonia. Ammonia content was reduced about 10% by ozone contact. Sulfur compounds, on the other hand, reduced significantly while treated with ozone. In case of gas sample collected from liquid fertilization system, the concentrations of hydrogen sulfide ($H_2S$), methyl mercaptan (MM), dimethyl sulfide (DMS), and dimethyl disulfide (DMDS) of inlet gas were 50.091, 4.9089, 27.8109 and 0.4683 ppvs, respectively. After oxidized by ozone, the concentrations of sulfur compounds were 1.2317, 0.3839, 14.7279 and 0.3145 ppvs, respectively. Another sample collected from aerobic composting system was oxidized in the same conditions. The concentrations of $H_2S$, MM, DMS and DMDS of the sample collected from inlet point of the reactor were 40.6682, 1.3675, 24.2458 and 0.8289 ppvs, respectively. After oxidized, the concentrations of $H_2S$, MM, DMS, and DMDS were reduced to 3.013, ND, 8.8998 and 0.3651 ppvs, respectively. By application of another type of ozone, the concentrations of $H_2S$, MM, DMS and DMDS of inlet gas were reduced from 43.397, 1.4559, 3.6021 and 0.4061 to ND, ND, ND, and 0.21ppvs, respectively.

Analysis of Monitoring and Recycling Technology Technologies of Cleaning Solution and Rinse Water in the Aqeous Cleaning System (수계 세정시스템의 세정액/헹굼수의 모니터링 및 재활용 기술 분석)

  • Han, Sang-Won;Lee, Ho Yeoul;Bae, Jae-Heum;Ryu, Jong-Hoon;Park, Byeong-Deog;Jeon, Sung-Duk
    • Clean Technology
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    • v.7 no.4
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    • pp.225-242
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    • 2001
  • Cleaning process is necessary for machining parts or manufacturing finished products in the industry. Most of domestic and foreign companies are now trying to adopt environment-friendly aqueous cleaning agents instead of CFC-113 and 1,1,1-TCE which are ozone-depleting substances. However, the aqueous cleaning system has a disadvantage due to its generation of lots of waste water since the system utilizes water in cleaning and rinsing processes. Thus, it is very important that monitoring and recycling technologies of the cleaning solution and the rinse water should be introduced in the aqueous cleaning system in order to minimize generation of waste water and to maintain its cleaning performance for a quite long time. In this paper, the cleaning agents utilized in the aqueous cleaning system and cutting oils which are main contaminants were examined and analyzed. And the monitoring and recycling technologies of the aqueous cleaning system which can be employed in the industrial fields were also reviewed and evaluated.

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Effect of Ozone Concentration on AOP Efficiency of Secondary Effluent from Pig Slurry Purification System (오존 접촉농도가 양돈슬러리 2차 처리수의 고도처리 효율에 미치는 영향)

  • Jeong, K.H.;Jeon, S.K.;Ryu, S.H.;Kim, J.H.;Kwag, J.H.;Ann, H.K.;Jeong, M.S.;Yoo, Y.H.
    • Journal of Animal Environmental Science
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    • v.17 no.3
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    • pp.181-188
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    • 2011
  • With an increasing livestock population, animal manure production has been steadily increasing in Korea. This trend has forced farmers to spend more money for animal manure treatment in their farm. Therefore, research utilizing animal manure as a renewable resources has become increasingly important. The purpose of this study was to develop a stable advanced wastewater treatment system can be applied to conventional animal wastewater treatment processes and evaluate its contribution to reduce effluent discharge volume by recycling as flushing water. AOP (advanced oxidation process) process improved wastewater treatment efficiency in terms of color, suspended solids (SS) and chemical oxygen demand (COD). Due to the addition of Hydrogen peroxide ($H_2O_2$), pathogens, Salmonella and E. coli, reduction was accomplished. To enhance ozone treatment effect, three levels of ozone test on secondary effluent of pig slurry purification system were conducted. At the level of 5 g/hr, 6.7 g/hr and 8.4 g/hr color of secondary effluent of pig slurry purification system were decreased from 2,433 to 2,199, 2,433 to 1,980 and 2,433 to 243, respectively.

Leaching of Ruthenium by Electro-generated Chlorine Gas by Electrochemical Method (전기화학법(電氣化學法)에 의해 생성(生成)된 전해생성(電解生成) 염소(鹽素)를 이용한 루테늄의 침출(浸出))

  • Ahn, Jong-Gwan;Lee, Ah-Rum;Kim, Min-Seuk;Ahn, Jae-Woo;Lee, Jae-Ryeoung
    • Resources Recycling
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    • v.22 no.6
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    • pp.55-63
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    • 2013
  • In this study, a electrochemical-chemical combined dissolution technology was conducted by electro-generated chlorine to obtain ruthenium solution from ruthenium metal. To find out the optimum leaching conditions of ruthenium in chloride solution, this leaching process was carried out on the variation of pH, reaction time, temperature and applied voltage at the electro-generated chlorine system in the reaction bath. Also, ozone generator was used to obtain ruthenium(III) chloride solution to increase the leaching rate. The optimum condition was observed at pH 10.0, $40^{\circ}C$ within 1 hr of reaction time that more than 88% of ruthenium(III) chloride dissolved.

A Study on the Water Reuse Systems (중수도개발연구(中水道開發研究))

  • Park, Chung Hyun;Lee, Seong Key;Chung, Jae Chul
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.4 no.4
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    • pp.113-125
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    • 1984
  • Water supply has been mainly dependent on the construction of the dams in Korea. It is difficult, however, to continue to construct dams for many reasons, such as the decrease of construction sites, the increase of construction costs, the compensation of residents in flooded areas, and the environmental effects. Water demands have increased and are expected to continue increasing due to the concentration of people in the cities, the rise of the living standard, and rapid industrial growth. It is acutely important to find countermeasures such as development of ground water, desalination, and recycling of waste water to cope with increasing water demands. Recycling waste water includes all means of supplying non-potable water for their respective usages with proper water quality which is not the same quality as potable water. The usages of the recycled water include toilet flushing, air conditioning, car washing, yard watering, road cleaning, park sprinkling, and fire fighting, etc. Raw water for recycling is obtained from drainage water from buildings, toilets, and cooling towers, treated waste water, polluted rivers, ground water, reinfall, etc. The water quantity must be considered as well as its quality in selecting raw water for the recycling. The types of recycling may be classified roughly into closed recycle systems and open recycle systems, which can be further subdivided into individual recycle systems, regional recycle systems and large scale recycle system. The treatment methods of wastewater combine biochemical and physiochemical methods. The former includes activated sludge treatment, bio-disc treatment, and contact aeration treatment, and the latter contains sedimentation, sand filtration, activated carbon adsorption, ozone treatment, chlorination, and membrane filter. The recycling patterns in other countries were investigated and the effects of the recycling were divided into direct and indirect effects. The problems of water reuse in recycle patterns were also studied. The problems include technological, sanitary, and operational problems as well as cost and legislative ones. The duties of installation and administrative organization, structural standards for reuse of water, maintenance and financial disposal were also studied.

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Design and Operation of the Rainwater-Greywater Hybrid System : SNU No. 39 Building (빗물-저농도 오수 하이브리드 시스템의 설계 및 운전 평가 : 서울대 39동)

  • Shim, In-tae;Park, Hyun-ju;Kim, Tschung-il;Jung, Sung-un;Han, Moo-young;Namkung, Eun
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.12
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    • pp.676-682
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    • 2016
  • In this study, rainwater-greywater hybrid system was installed and operated for 1 year in order to evaluate its water quantity, water quality, and economic efficiency in building no. 39. This system was expected to overcome each disadvantages of and maximize each advantages. Low-greywater that was washed up from shower room was treated by MBR (Membrane Bioreactor) and ozone oxidation. Rainwater that was collected from the rooftop was stored in a reservoir, and then transferred to the storage tank that was mixed with treated greywater. After 1 year operating in building no. 39, rainwater and greywater was used to supply $2,599m^3$ of toilet flushing water. In terms of water quality, rainwater was satisfied far the greywater reuse standards except for E.coli. Moreover, low greywater quality was acceptable except for E. coli, BOD, SS, and turbidity. In addition, economic analysis was obtained from benefit-cost ratio (B/C) with 1.11. It implies that the feasibility of the project was reasonable. Furthermore, various research and policy to improve the economic efficiency of water recycling facilities is required to expand the use of water recycling facilities.