• Title/Summary/Keyword: Ozone effect

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Effectiveness of Uniconazole(XE-1019) Treatment in Reducing Ozone Injury to Tomato Plant (Uniconazole(XE-1019) 처리가 토마토의 오존피해경감에 미치는 효과)

  • Won, Dong-Chan;Ku, Ja-Hyeong;KIm, Tae-Il
    • Korean Journal of Environmental Agriculture
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    • v.11 no.1
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    • pp.41-49
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    • 1992
  • To determine the efficacy of uniconzaole[(E)-1-(4-chlorophenyl)-4,4-dimethy 2-(1,2,4-triazol-1-yl)-1-penten-3-ol)](XE-1019) as a phytoprotectant against $O_3$ injury in tomato plants(Lycopersicon esculentum Mill. 'Pink Glory'), plants were given a 50ml soil drench of uniconazole solution at concentrations of 0.001, 0,01, 0.1 and 0.2mg/pot thirteen days prior to $O_3$ fumigation. All four uniconazole concentrations were effective in providing protection against $O_3$ exposure(16h at 0.3 ppm). Uniconazole treatment above 0.001 mg/pot significantly reduced stem elongation, leaf enlargement, leaf area and fresh weight of plant, whereas increased chlorophyll concentration. Transpiration rate on a whole plant basis was reduced by uniconazole treatment and $O_3$ exposure. Uniconazole reduced ethylene production induced by $O_3$ injury but had little or no effect on defoliation of cotyledons and leaf epinasty. Activities of peroxidase (POD) and superoxide dismutase(SOD) were slightly increased by application of uniconazole. With increasing exposure time, $O_3$ increased POD activity but decreased SOD activity. The phytoprotective effects of uniconazole were diminished by applying gibberellin at $10{\sim}20$ ppm. These results suggest that the phytoprotective effects of uniconazole are related to its role of increasing activities of free radical scavengers such as POD and SOD, in addition to growth-retardation as an anti-gibberellin.

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Distribution and Risk Assessment of Bisphenol-A in Tap Water from Rehabilitated Indoor Water Service Pipe (갱생 옥내급수관 수돗물에서 비스페놀-A 분포 및 위해성 평가)

  • Jeong, Gwanjo;Son, Boyoung;Lee, Inja;Ahn, Chihwa;Kim, Junil;Moon, Boram;Lee, Suwon;Ahn, Jaechan;Kim, Bogsoon;Chung, Deukmo
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.7
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    • pp.371-376
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    • 2016
  • In this study, the survey of bisphenol-A in indoor water service pipes rehabilitated with epoxy resin was conducted and the risk assessment was done to investigate the effect on the human health to drink tap water. Bisphenol-A in raw water was detected in a range of 50~118 ng/L in all samples, where the limit of quantification was 10 ng/L. This is caused by inflow of the sewage effluent or the tributaries of the surrounding area containing bisphenol-A. Bisphenol-A was not detected in finished water after the advanced water treatment process. It was achieved by its removal from the processes of flocculation-precipitation and oxidation of ozone and chlorine and by being changed to other by-product materials. For the indoor water service pipe, bisphenol-A was not detected in all cases which was not coated with epoxy resin. However, when epoxy resin is lined within the indoor water service pipe, bisphenol-A was identified at maximum level of 521 ng/L and was detected above the limit of quantitation at 68 percentages of all samples. The Hazard Quotient (HQ) at the maximum level (521 ng/L) of the detected bisphenol-A is 0.004, which is less than the reference value of 0.1 for the tap water intake. Therefore, it is considered that the detected levels of bisphenol-A in this study would be safe to drink tap water.

Variation of Pollutant Removal Efficiency and Backwashing Effect of BAC Basin in Advanced Water Treatment Processes (고도정수공정에서 오염물질 제거효율 변화특성과 BAC조의 역세척에 따른 영향)

  • Park, Soo-Yee;Lee, Sang-Bong;Sin, Sang-Min;Jun, Chang-Jea;Kim, Chang-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.1
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    • pp.45-53
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    • 2008
  • In this paper, the property of influent water and variations of removal efficiencies in each unit processes were studied based on the experiment data from the advanced water treatment plant in a city of Korea. The microbial species in the biological activated carbon(BAC) after backwashing of activated carbon filtration tank(ACFT) were also identified. The property and the removal efficiencies were evaluated by considering 8-9 items. The variations of 4 items were investigated from the influent and effluent of ACFT. SEM recording were conducted on BAC samples before and after backwashing. And the existence of attached microorganisms were identified through HPC(Heterotrophic Plate Counter) investigation. For the property of influent water, the concentrations of most items were maintained in the constant ranges, some items had seasonal properties. For the removal efficiencies, there were some items showing similar monthly-pattern and increasing with time, other items decreasing at the ozone contactor. Through these investigations, it was possible to distinguish the target items, which were removed by the advanced processes. The existence of microorganisms in ACFT could be predicted based on the variation curve of NH$_3$-N, and this fact were proved by SEM and HPC.

Consideration of UVR's Skin Damage and Study on Development of Oral Cosmetic - Focusing on Clinical Results of Calaguala (Polypodium leucotomos) - (자외선의 피부에 대한 유해성에 따른 경구용 화장품 개발에 대한 연구 - 칼라구알라(Polypodium leucotomos)의 임상연구를 중심으로 -)

  • Chung, Moon-Suk;An, Jong-Suk;Lee, Jeong-Man
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.38 no.1
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    • pp.91-101
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    • 2012
  • This study's purpose is to research the antioxidant power of Calaguala (Polypodium leucotomos, PL) as an oral supplement: Calaguala, a native of Central America, is a fern which belongs to the family polypodiaceae protecting the skin from the ultraviolet and active oxygen free radicals. The total 14 volunteers, each female 7 & male 7, were divided into 2 groups, then exposed to UV for 30 min after taking Calaguala and placebo. The total antioxidant capacity (TAC) was analyzed by taking the blood samples from anticubital vein 3 hours after UV exposure. First, Calaguala siginifcantly decreased the concentration of active oxygen free radicals 4 weeks later. The concentration of active oxygen free radical in PL group declined more than placebo group, when measured 30 min and 3 hours after UV exposure. Second, Calaguala did not significantly increase TAC 4 weeks later, but significantly decreased TAC 3 hours after exposure, when compared with placebo group. Now days, the photo allergy and photo aging caused by air pollution and ozone destruction have drastically increased, and thus the amount of UV radiation reaching the earth's surface increased. The increase of active free oxygen radicals resulted in accelerating the diseases and aging. The first superficial protecting protection by reflection & dispersion and the second body internal protection by taking oral photo antioxidant such as Calaguala should be continuously researched.

Effect of Freezing on the Physicochemical Properties of Semi-dried Red Pepper (냉동조건에 따른 반건조 홍고추의 물리.화학적 특성 변화)

  • Kim, Bo-Yeon;Lee, Kyoung-Hae
    • Food Science and Preservation
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    • v.16 no.3
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    • pp.362-370
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    • 2009
  • Quality changes in semi-dried red pepper (SRP) treated with ozone water were observed upon storage (at $-18^{\circ}C$) after freezing at $-10^{\circ}C$, $-20^{\circ}C$, and $-40^{\circ}C$. Drip loss after treatment was greater than in control peppers, but no significant difference was evident between treatments (p<0.05). We observed that differences between samples decreased as storage time increased. Texture after treatment did not change significantly over a 3-month period. The redness (a-value) after treatment was greater than in the control, but no sample showed significant color alteration after the 3-month period. The capsaicinoid content decreasedas storage time increased, and was also affected by the freezing temperature. However, carotenoid content was not influenced by freezing or storage temperature. Ascorbic acid and free sugar contents showed decreases of 47% and 6.5%, respectively, after semi-drying. The results of sensory evaluation indicated no significant difference between samples in terms of color appearance.

A Study on Clean Agents for Halon Replacement in the Portable Extinguisher with CO2 as an Expellant Gas (이산화탄소를 가압원으로 하는 할론대체 소화기용 청정소화약제에 대한 연구)

  • Jeong, Keesin
    • Fire Science and Engineering
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    • v.33 no.3
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    • pp.51-55
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    • 2019
  • To prevent ozone depletion caused by CFCs, the replacement of Halon with clean agents has been developed in the fire protection field along with refrigerants, detergents, and foaming agents. The alternatives for Halon 1211 have been developed in the portable fire extinguisher area and HCFC-123 is used widely as a clean fire extinguishing agent. The type of expellant gas is important because their own vapor pressure is low. In this study, HCFC-123, HCFC-124, HFC-125, and Novec-1230 were selected as fire extinguishing agents and CO2, which is expected to improve the fire extinguishing ability, was chosen as the expellant gas. For each agent, experiments changing the agent and CO2 amount were carried out and HCFC-123 showed a good result, as expected. The extinguisher, HCFC-123 of 1.5 kg, showed the same ability to suppress a class A and B fire as the extinguisher, HCFC-123 of 2.5 kg, which is currently sold on the market. According to this result, the expellant gas has a subsidiary fire extinguish effect. This can reduce the amount of HCFC fire extinguishing agent, which is categorized in the phase-out alternatives, and is a more eco-friendly and economical fire extinguisher than the previous one. This study can also help solve the problems of CO2 fire extinguishers for class B and C fires, and can be used to extinguish electric and electron facilities fire, which contains large amounts of class A fire combustibles.

The Effects of SO2 and NH3 on the N2O Reduction with CO over MMO Catalyst (MMO 촉매와 CO 환원제에 의한 N2O 분해에서 SO2 및 NH3 영향 연구)

  • Chang, Kil Sang;You, Kyung-Chang
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.653-657
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    • 2009
  • Nitrous oxide is a typical greenhouse gas which is produced from various organic or fossil fuel combustion processes as well as chemicals producing plants. $N_2O$ has a global worming potential of 310 times that of $CO_2$ on per molecule basis, and also acts as an ozone depleting material in the stratosphere. However, its removal is not easy for its chemical stability characteristics. Most SCR processes with several effective reducing agents generally require the operation temperature higher than $450^{\circ}C$, and the catalytic conversion becomes decreased significantly when NOx is present in the stream. Present experiments have been performed to obtain basic design data of actual application concerning the effects of $SO_2$ and $NH_3$ on the interim and long term activities of $N_2O$ reduction with CO over the mixed metal oxide (MMO) catalyst derived from a hydrotalcite-like compound precursor. The MMO catalysts used in the experiments, have shown prominent activities displaying full conversions of $N_2O$ near $200^{\circ}C$ when CO is introduced. The presence of $SO_2$ is considered to show no critical behavior as can be met in the $NH_3$ SCR DeNOx systems and the effect of $NH_3$ is considered to play as mere an impurity to share the active sites of the catalysts.

Effects of Pre-Oxidation for Recirculation of Aquaculture Wastewater (양어용수 재이용을 위한 전 산화처리의 효과)

  • Lim, Jae-Lim;Shin, Hang-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.1
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    • pp.103-111
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    • 2000
  • Ozonation and advanced oxidation($H_2O_2/O_3$) process were investigated under various experimental conditions to improve the efficiency of biological filter used for the treatment of recycled wastewater from aquaculture. Ammonia removal followed the first-order reaction whose reaction rate constant(k) was $2.0{\times}10^{-2}min^{-1}$ in ozonation. The ammonia removal rate increased according as the bicarbonate alkalinity is increased. About 46% $NH_3$ was oxidized by ozone at 200 mg/L as $CaCO_3$. When alkalinity existed in wastewater, ammonia removal rate by advanced oxidation was very low due to the inhibition effect of bicarbonate. However, when initial pH was adjusted to about 8.2 by 0.1 N KOH, ammonia removal rate was improved higher than that by ozonation. Especially. ammonia removal rate was the highest at $H_2O_2/O_3$ of 0.25 and about 90% of ammonia was removed in 30 min at this ratio as pH was maintained over 9. In the case of wastewater containing ammonia and organic constituents, ammonia removal efficiency by both ozonation and advanced oxidation decreased seriously because organic constituents consumed the oxidant faster than ammonia. In addition the optimal $H_2O_2/O_3$ ratio was changed. Like ammonia removal, DOC(dissolved organic carbon) increased for first 10 min and then decreased slowly because the particulate organic constituents were oxidized rapidly and then produce DOC. Even when the ammonia concentration by twice, oxidation of DOC was not retarded.

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Bactericidal Efficacy of Non-thermal DBD Plasma on Staphylococcus aureus and Escherichia coli (비열 유전체장벽방전 플라즈마의 포도상구균 및 대장균 살균효과)

  • Kim, Keyyoung;Paik, Namwon;Kim, Yonghee;Yoo, Kwanho
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.28 no.1
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    • pp.61-79
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    • 2018
  • Objectives: The objective of this study was to examine the effect of non-thermal dielectric barrier discharge(DBD) plasma on decontamination of Staphylococcus aureus(S. aureus) and Escherichia coli(E. coli) as common pathogens. Methods: This experiment was carried out in a chamber($0.64m^3$)designed by the authors. The plasma was continuously generated by a non-thermal DBD plasma generator(Model TB-300, Shinyoung Air tech, Korea). Suspensions of S. aureus and E. coli of 0.5 McFarland standard($1.5{\times}10^8CFU/mL$) were prepared using a Densi-Check photometer(bio $M{\acute{e}}rieux$, France). The suspensions were diluted1:1000 in sterile PBS solutions(approximately$10^{4-5}CFU/mL$) and inoculated on tryptic soy agar(TSA) in Petri dishes. The Petri dishes(80mm internal diameter)were exposed to the non -thermal DBD plasma in the chamber. Results: The results showed that 95% of S. aureus colonies were killed after a six-hour exposure to the DBD plasma. In the case of E. coli, it took two hours to kill 100% of the colonies. The gram-negative E. coli had a greater reduction than the gram-positive S. aureus. This difference may be due to the structure of their cell membranes. The thickness of gram-positive bacteria is greater than that of gram-negative bacteria. The S. aureus is more resistant to DBD plasma exposures than is E. coli. It should be noted that average concentrations of ozone, a byproduct of the DBD plasma generator, were monitored throughout the experiment and the results were well below the criteria, 50 ppb, recommended by the Korean Ministry of the Environment. Thus, non-thermal DBD plasma is deemed safe for use in hospital and public facilities. Conclusions: There was evidence that non-thermal DBD plasma can effectively kill S. aureus and E. coli. The results indicate that DBD plasma technology can greatly contribute to the control of infections in hospitals and other public and private facilities.

A Study on Animal Skin Irritation Measurement of Ozoneized Olive Oil for Cosmetic Ingredients (화장품원료를 위한 오존화 올리브오일의 동물 피부자극 측정에 관한 연구)

  • Kim, Ducksool
    • Journal of the Institute of Convergence Signal Processing
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    • v.22 no.1
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    • pp.14-19
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    • 2021
  • This study has attempted to use ozone for the treatment of skin diseases as research results that ozonated olive oil has an excellent therapeutic effect on skin diseases are known. However, there is hardly any accurate data in Korea. Usually, animal tests related to cosmetics are not performed, but toxicity tests were conducted because they were absolutely necessary. In general, there are not many cases of measuring actual data through animal tests for the purpose of confirming the performance of cosmetics, but in the case of toxicity tests, it is recommended to accurately measure skin reactions, so this experiment was conducted. In this experiment, in order to evaluate the skin irritation of ozonated oil (high concentration) on the rabbit, the test substance was applied to the back of the rabbit for 24 hours, and then mortality, general symptoms and skin irritation were evaluated. Experimental Results As a result of evaluating the treatment site of the test substance after a certain period of time, no skin irritation was observed in all animals.