• 대기
• /
• 제20권3호
• /
• pp.367-377
• /
• 2010

Variation of tracer distribution during the vortex-breakup period in the Antarctic region was observed by the data from the Improved Limb Atmospheric Spectrometer (ILAS) and ILAS-II. All four trace species including methane, nitrous oxide, ozone, and water vapor show similar patterns of vertical gradient in spite of different structures of zonal mean mixing ratio. Timings of vortex breakup on each level are estimated by two different methods, and they are compared with zonal standard deviations following the latitude circle of each trace species. Although the tracers have different chemical life times and sink/source, the zonal standard deviation patterns show remarkable similarities. The zonal standard deviation shown here to measure the zonal asymmetry of tracer distribution is believed to diagnose the timing of the Antarctic polar-vortex breakup reasonably well.

• 한국대기환경학회지
• /
• 제22권5호
• /
• pp.642-652
• /
• 2006

In order to understand the characteristics of surface ozone concentration and high $O_3$ concentration days, regional data from seven air quality monitoring stations which were operated by local governments were analyzed Regional characteristics of $O_3$ concentration were analyzed with the data of $O_3$ concentration and the characteristics of $O_3$ generation and weather conditions by the selection of the days in which the concentration was higher than 80 ppb. In the case of daily variation, the lowest $O_3$ concentration was shown in all regions from 7am to 8am and the highest around at 4 pm. The monthly variation of mean $O_3$ concentration and ${\Delta}O_3$ values revealed a reducing pattern in July and August following the peak in June, and again a gradual increasing trend in September and October. The result shows that the amount of ozone is dependent on photochemical reaction. The days of $O_3$ generated more than 80 ppb in the region of Gwangyang-bay were 544 days(1,760 hrs). The frequency of occurrence in the region revealed a strong pattern with the order of Samil-dong, Jinsang, and Gwangmu-dong stations in the Gwangyang region. However, Tein-dong, which is the nearest station to air pollution material generation source, showed the lowest frequency in the study area. Consequently, the meteorological parameters which can easily generate the high concentration of $O_3$ in the region of Gwangyang-bay are characterized as follows; atmospheric temperature which is higher than $19^{\circ}C$, relative humidity with the range of $60{\sim}85%$, the less average wind velocity than 5 m/s, cloud cover which is less than 5/10, and the more duration of sunshine than 8 hours.

• 한국대기환경학회지
• /
• 제24권1호
• /
• pp.91-99
• /
• 2008

A multilayer tower-type photoreactor, in which $TiO_2$-coated glass-tubes were installed, was used to measure the vapor-phase BTEX removal efficiencies by ozone oxidation ($O_3$/UV), photocatalytic oxidation ($TiO_2$/UV) and the combination of ozone and photocatalytic oxidation ($O_3/TiO_2$/UV) process, respectively. The experiments were conducted under various relative humidities, temperatures, ozone concentrations, gas flow rates and BTEX concentrations. As a result, the BTEX removal efficiency and the oxidation rate by $O_3/TiO_2$/UV system were highest, compared to $O_3$/UV and $TiO_2$/UV system. The $O_3/TiO_2$/UV system accelerated the low oxidation rate of low-concentration organic compounds and removed organic compounds to a large extent in a fixed volume of reactor in a short time. Therefore, $O_3/TiO_2$/UV system as a superimposed oxidation technology was developed to efficiently and economically treat refractory VOCs. Also, this study demonstrated feasibility of a technology to scale up a photoreactor from lab-scale to pilot-scale, which uses (i) a separated light-source chamber and a light distribution system, (ii) catalyst fixing to glass-tube media, and (iii) unit connection in series and/or parallel. The experimental results from $O_3/TiO_2$/UV system showed that (i) the highest BTEX removal efficiencies were obtained under relative humidity ranging from 50 to 55% and temperature ranging from 40 to $50^{\circ}C$, and (ii) the removal efficiencies linearly increased with ozone dosage and decreased with gas flow rate. When applying Langmuir-Hinshelwood model to $TiO_2$/UV and $O_3/TiO_2$/UV system, reaction rate constant for $O_3/TiO_2$/UV system was larger than that for $TiO_2$/UV system, however, it was found that adsorption constant for $O_3/TiO_2$/UV system was smaller than that for $TiO_2$/UV system due to competitive adsorption between organics and ozone.

• 한국대기환경학회:학술대회논문집
• /
• 한국대기환경학회 2006년도 춘계학술대회 논문집
• /
• pp.278-280
• /
• 2006

• 한국대기환경학회:학술대회논문집
• /
• 한국대기환경학회 2000년도 춘계학술대회 논문집
• /
• pp.58-59
• /
• 2000

오존은 공간적.시간적 변동이 매우 큰 대기오염물질로 서울시의 27개 대기오염 자동측정망에서 실시간으로 측정.감시되고 있으며, 오존의 농도가 높아지는 여름철에는 오존경보제를 실시하고 있다. 특히 오존의 농도는 일사, 풍향, 풍속 등의 기상인자, $NO_x$, VOCs 등 전구물질의 농도, 그리고 지형에 따라서 영향을 받는 것으로 알려져 있다. 따라서, 본 연구에서는 서울지역에 대한 기하학적 축소모형을 제작하여 풍동내에서 풍향.풍속을 측정하여 지형에 따른 바람의 특성을 파악하였다. (중략)

• 한국대기환경학회:학술대회논문집
• /
• 한국대기환경학회 2002년도 춘계학술대회 논문집
• /
• pp.125-126
• /
• 2002

Fishman et al.(1987)의 연구를 시작으로 인공위성 자료를 이용하여 적도지역의 대류권 오존에 대한 연구가 활발해졌다. 적도지역의 대류권 오존의 분포는 Atlantic Ocean에서 최대값을 가지며 Pacific Ocean에서 최소값을 가지는 wave pattern을 보인다. S. America와 S. Africa에서 연중 dry season(6-9월)에 biomass burning로 인해 대류권 오존의 최대값이 나타난다. 인공위성 자료를 이용한 대류권 오존을 구하는 방법은 다음과 같다. (중략)

• 한국대기환경학회:학술대회논문집
• /
• 한국대기환경학회 2001년도 추계학술대회 논문집
• /
• pp.73-74
• /
• 2001

도시지역의 오존농도는 배출원 환경 및 지형과 국지 기상조건에 의해 크게 영향을 받게 된다. 일반적으로 도시내 공단과 교통량이 많은 지역에서는 다량의 NO 배출에 의한 오존의 감소가 일어나는 반면 도시플륨의 풍하측의 지역에서는 오존의 축적과 함께 고농가 발생하게 된다 (Wang et al., 2001; Bower et al., 1994; Mckendry). 특히 연안도시의 경우 여름철 주로 발생하는 국지순환인 해풍에 의한 고농도를 경험하게 되는데, 이는 수면의 낮은 오존침적으로 인해 소멸의 영향이 적고 (Entwistle, 1997), 해풍역전으로 인한 연직혼합의 제한으로 인해 발생한다고 볼 수 있다 (Lu and Turco, 1994). (중략)

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2005년도 학술대회 논문집 전문대학교육위원
• /
• pp.169-172
• /
• 2005

The simulation of Hydraulic pressure distribution of discharge tube with globular beads and the removal characteristic of Escherichia coli by the discharge tube with globular beads were estimated. The removal characteristic of Escherichia coli was related to the input voltage because the electric field is increased according to input voltage. As the passing amount of test water in discharge tube is increased, the removal ratio of Escherichia coli was increased because passing numbers of electric field section is increased.

• 한국환경과학회지
• /
• 제13권4호
• /
• pp.403-412
• /
• 2004

Waste water-soluble cutting oil was treated with WI type #1 and WI type #2. The properties of the original water-soluble cutting oil were pH=l0.4, viscosity=1.4cP, CODcr=44,750 ppm, and TOC=10,569 ppm. However, the properties of the oil used for more than 3 months were changed to pH=7.82, viscosity=2.1cP, CODcr=151,000 ppm, and TOC=74,556 ppm. It might be attributed to the fact that molecular chains were cut due to thermal oxidation and impurities such as metal chips were incorporated in to the oil during the operation processes. To prevent the putrefaction of oil, the sterilization effect of ozone and UV on the microorganism in the oil was investigated. Ozone treatment showed that 99.99% of the microorganism was annihilated with 30 minutes contact time and 60 minutes were necessary for the same effect when UV was used. Ozone treatment could cut molecular chains of the oil due to strong sterilization power, which was evidenced by the increase of TOC from 25,132 ppm at instantaneous contact to 28,888 ppm at 30 minutes contact time. However, UV treatment didn't show severe changes in TOC values and thus, seemed to cause of severe cut of molecular chains. When the activated carbon was used to treat the waste water-soluble cutting oil, TOC decreased to 25,417 ppm with 0.lg carbon and to 15,946 ppm with 5.0g carbon. This results indicated that the waste oil of small molecular chains could be eliminated by adsorption. From the results, it could be concluded that these treatment techniques could be proposed to remove the waste oil of small molecular chains resulting in the degradation of the oil properties. In addition, these experimental results could be used for the correlation with future works such as investigation of the molecular distribution according to the sizes, lengths, and molecular weight of the chains.

• 한국환경보건학회지
• /
• 제44권6호
• /
• pp.539-547
• /
• 2018

Objectives: Ozone ($O_3$) advisories are issued by provincial/prefectural and city governments in Korea and Japan when oxidant concentrations exceed the criteria of the related country. Advisories issued only after exposure to high $O_3$ concentrations cannot be considered ideal measures. Forecasts of $O_3$ would be more beneficial to citizens' health and daily life than real-time advisories. The present study was undertaken to present a simplified forecasting model that can predict surface $O_3$ concentrations for the afternoon of the day of the forecast. Methods: For the construction of a simple and practical model, a multivariate regression model was applied. The monitored data on gases and climate variables from Japan's air quality networks that were recorded over nearly one year starting from April 2016 were applied as the subject for our model. Results: A well-known inverse correlation between $NO_2$ and $O_3$ was confirmed by the monitored data for Iksan, Korea and Fukuoka, Japan. Typical time fluctuations for $O_3$ and $NO_x$ were also found. Our model suggests that insolation is the most influential factor in determining the concentration of $O_3$. $CH_4$ also plays a major role in our model. It was possible to visually check for the fit of a theoretical distribution to the observed data by examining the probability-probability (P-P) scatter plot. The goodness of fit of the model in this study was also successfully validated through a comparison (r=0.8, p<0.05) of the measured and predicted $O_3$ concentrations. Conclusions: The advantage of our model is that it is capable of immediate forecasting of surface $O_3$ for the afternoon of the day from the routinely measured values of the precursor and meteorological parameters. Although a comparison to other approaches for $O_3$ forecasting was not carried out, the model suggested in this study would be very helpful for the citizens of Korea and Japan, especially during the $O_3$ season from May to June.