• 환경위생공학
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• 제15권2호
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• pp.27-32
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• 2000

The hydrolysis of pesticides by ozone was studied using the ozone generator manufactured for home appliance. Ozone was treated to remove the residual pesticides in the vegetables such as lettuce, cabbage, spinach and Japanses parsely. The experimental results were optimistic with removal efficiency of more than 50%, but its achievement depends on the operational hours of zone generator and chemical structures of pesticides. This report was determined as an optimal conditions for the removal rate of pesticides as follows: ozone input concentration in the contactor was $2mg/{\ell}$, ozone contact time was at least 30 min without washing vegetables, but it was OK at 10 min in case that number of washing increases.

• 자연과학논문집
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• 제10권1호
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• pp.93-102
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• 1998

오존을 이용한 마직물의 표백효과를 연구하기 위하여 오존 발생 장치에 의해서 생성된 오존을 물에 용존시킨 오존처리액으로 마직물을 처리하였다. 마직물의 오존처리를 위하여 오존 발생기와 오존 용존조를 사용하였고, 표백 효과를 측정하기 위하여 오존으로 처리된 마직물을 Hunter의 백도, 인장강도, SEM사진을 측정하였다. 발생 오존의 농도는 전압이 높을수록, 원료 산소가스의 유량이 적을수록 증가하였다. 처리포의 표백효과는 오존의 순수 농도가 증가함에 따라 증가하였다. 처리포의 백색도는 처리온도가 $0-15^{\circ}C$, 처리시간이 20분일 때가 최적의 상태를 나타내었다. 처리포의 인장강도는 처리시간이 길수록, 온도를 높여줌에 따라 저하하였다.

• 한국염색가공학회지
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• 제5권4호
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• pp.49-59
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• 1993

In order to study the bleaching of cotton fabrics, ozone which has been produced by an ozone generator, has been contacted with cotton fabrics in water at various conditions. The equipments used for the ozone treatment of cotton fabrics were the ozone generator and a liquor/ozone contactor. For the examination of the ozone bleaching effect on cotton fabrics the whiteness, tensile strength, wettability and clark softness of the ozone treated cotton fabrics were measured. The conclusion obtained were, ozone concentration was increased, as the voltage was increased and flow rate was decreased and oxygen amount was increased. Bleaching effect of treated fabrics increased with increasing attributed more the net concentration of ozone rather than the total ozone amount of produced. The whiteness of treated fabrics was found to be best when treating temperature was 15~20<$^{\circ}C$, in acidic condition. The tensile strength of treated fabrics decreased as the treating time increased, and as the temperature raised, and the acidity increased. The wicking distance of treated fabrics increased slightly with increasing the treating time and the temperature. Clark softness of treated fabrics was not changed until passing 30min. of the treating time, then it decreasing linealy with increasing the treating time.

• 한국물환경학회지
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• 제20권1호
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• pp.78-85
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• 2004

As an ozone contactor, we newly adopted HJLR (High-performance Jet Loop Reactor) for the decolorization of Reactive black 5 and the mineralization of oxalic acid, which has been applied exclusively in biological wastewater treatments and well-known for high oxygen transfer characteristics. The ozonation efficiency for organic removals and ozone utilization depending on the mass transfer rate were compared to those of Stirred bubble column reactor, which was controlled by varing energy input in the HJLR and Stirred bubble column reactor. The results were as follows; first, the decolorization rate of Reactive black 5 in the HJLR reactor was nearly proportional to the increasing $k_La$. When the $k_La$ was increased by 25 % from $13.0hr^{-1}$ to $16.4hr^{-1}$, 30 % of the k' (apparent reaction rate constant) was increased from 0.1966 to $0.2665min^{-1}$ (Stirred bubble column; from 0.1790 to $0.2564min^{-1}$). Ozone transfer was found to be a rate-determining step in decolorizing Reactive black 5, which was supported by that no residual ozone was detected in all of the experiments. Second, the mineralization of oxalic acid was not always proportional to the increasing $k_La$ in the RJLR reactor. The rate-determining step for this reaction was OH(OH radical) production with ozone transfer, because residual ozone was always detected during the ozonation of oxalic acid in contrast with Reactive black 5. This result indicates that the increase of $k_La$ in the HJLR reactor is beneficial only when there are in ozone transfer limited regions. In addition, regardless of $k_La$, the mineralization of oxalic acid was nearly accomplished within 60 minutes. It was interpreted as that the longer staying of residual ozone by whirling liquid in the HJLR reactor contributed to an high ozone utilization(83-94%), producing more OR radicals.

• 수도
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• 제24권6호통권87호
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• pp.23-31
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• 1997

Ozonation is an effective process in providing microbiologically safe drinking water. The operation of the ozonation stage is often based on disinfection criteria which include security factors, such as the CT criterion. This type of ozonation management, which mat include large safety margins, will no longer be possible, since formation of ozonation byproducts has to be avoided. In order to reduce the security factor, a computerized tool to predict with more accuracy inactivation of micro-organisms in the ozonation process has been developed.

• 한국양식학회지
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• 제13권2호
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• pp.137-145
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• 2000

삼상 유동층 반응조의 수처리 효율을 검토하기 위해 해수 순환여과 시설을 운전하였다. 수처리 시스템은 유동층 반응조, 카트리지 필터, 오존접촉조로 구성되어 있고, 전체 운전기간동안 사육조내 수질인자별 평균농도는 각각 COD 9mg/L, 총암모니아(TAN) 0.22mg/L, 아질산성 질소 0.05mg/L, 질산성 질소 20mg/L, 탁도 3.64 NTU, SS 9.5mg/L, pH 7.6, 알칼리도 70mg/L 등으로 나타나 양호한 수질조건을 유지할 수 있었다. 유동층 반응조의 TAN 부하량 범위는 4.3~32.9 g/$m^3$/day였고, 평균 제거율은 20 g/$m^3$/day으로 나타났다. 각 반응조의 TAN 제거율은 47~60%로 나타나 해수에서도 효과적인 암모니아 제거 특성을 나타내었다. 또한 유출수의 비이온성 암모니아 농도는 0.002 mg/L이하로 유지 할 수 있었다

• 대한환경공학회지
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• 제30권1호
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• pp.45-53
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• 2008

본 연구에서는 국내 한 정수장의 고도정수처리공정의 실험분석 자료를 바탕으로 정수장으로 유입되는 원수의 수질특성과 처리공정별 오염물질 제거효율의 변화특성을 연구하였고, 활성탄여과조의 역세척에 따른 BAC 내의 미생물 거동을 추적하였다. KMnO$_4$ 소비량 등 8$\sim$9개의 주요 항목을 중심으로 제거특성이 연구되었고, 활성탄여과조의 유입 유출수에 대하여 NH$_3$-N 등 4항목의 농도변화를 추적하였다. 역세척 전 후의 활성탄 시료의 SEM 사진을 촬영하였고, 미생물 생체량(HPC) 조사를 통해 활성탄 부착미생물의 존재를 확인하고자 하였다. 유입원수의 특성은 대부분의 조사항목이 일정한 농도범위로 유입되었고 그 중 계절적 일관성을 갖는 항목이 있었다. 공정별 제거효율 변화특성은 월별 일정한 유형을 갖는 것, 공정진행에 따라 지속적으로 제거되는 것, 오존접촉조에서 제거효율이 떨어지는 것 등으로 분류되었고, 현재 운전되고 있는 고도처리공정에서 제거되는 주요 대상오염물질을 구별할 수 있었다. NH$_3$-N의 농도변화 곡선으로 활성탄여과조 내에 미생물이 존재함을 예측하여 SEM 사진과 HPC 측정으로 이를 확인하였다.