• Journal of the Korean Society of Industry Convergence
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• v.10 no.1
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• pp.15-20
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• 2007

The aim of this study is to measure the removal characteristics of organic matter and bacteria with the use of ozone to reduce the problems caused by bacteria and organic matter which appear in sea-water is summer season. When the total input of ozone was $1.4mg/{\ell}O_3$, the removal rate of bacteria and E-coli from sea-water proved to be 100%. With the same input of ozone, on the other hand, the removal rate of COD turned to be relatively low, 50%, which was to the fact that sea-water consists of salt matter which is a kind of COD matter. This result supports the idea that we can keep using ozone steadily in the future to remove organic matters and bacteria from sea-water because ozone destructs relatively less salt matter in sea-water. Also, the treatment effect rate of SS, turbidity and organic matters such as $NH_3$-N, $NO_3$-N etc, was very high. As a result, we assume that the treatment of organic matter in sea-water with ozone is very effective

• Journal of Environmental Science International
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• v.26 no.5
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• pp.621-638
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• 2017

Meteorological characteristics related to variations in ozone ($O_3$) concentrations in the Korean peninsula before, during, and after Typhoon Talas (1112) were analyzed using both observation data and numerical modeling. This case study takes into account a high $O_3$ episode (e.g., a daily maximum of ${\geq}90ppb$) without rainfall. Before the typhoon period, high $O_3$ concentrations in the study areas (e.g., Daejeon, Daegu, and Busan) resulted from the combined effects of stable atmospheric conditions with high temperature under a migratory anticyclone (including subsiding air), and wind convergence due to a change in direction caused by the typhoon. The $O_3$ concentrations during the typhoon period decreased around the study area due to very weak photochemical activity under increased cloud cover and active vertical dispersion under a low pressure system. However, the maximum $O_3$ concentrations during this period were somewhat high (similar to those in the normal period extraneous to the typhoon), possibly because of the relatively slow photochemical loss of $O_3$ by a $H_2O+O(^1D)$ reaction resulting from the low air temperature and low relative humidity. The lowest $O_3$ concentrations during the typhoon period were relatively high compared to the period before and after the typhoon, mainly due to the transport effect resulting from the strong nocturnal winds caused by the typhoon. In addition, the $O_3$ increase observed at night in Daegu and Busan was primarily caused by local wind conditions (e.g., mountain winds) and atmospheric stagnation in the wind convergence zone around inland mountains and valleys.

• Asian Journal of Atmospheric Environment
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• v.12 no.1
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• pp.1-16
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• 2018

Ground-level ozone ($O_3$) can be a menace for vegetation, especially in Asia where $O_3$ levels have been dramatically increased over the past decades. To ensure food security and maintain forest ecosystem services, such as nutrient cycling, carbon sequestration and functional diversity of soil biota, in the over-populated Asia, environmental standards are needed. To set proper standards, dose-response relationships should be established from which critical levels are derived. The predictor of the response in the dose-response relationship is an $O_3$ metric that indicates the dose level to which the plant has been exposed. This study aimed to review the relevant scientific literature and summarize the $O_3$ metrics used worldwide to provide insights for Asia. A variety of $O_3$ metrics have been used, for which we discuss their strengths and weaknesses. The most widely used metrics are based only on $O_3$ levels. Such metrics have been adopted by several regulatory agencies in the global. However, they are biologically irrelevant because they ignore the plant physiological capacity. Adopting AOT40 ($O_3$ mixing ratios Accumulated Over the Threshold of $40nmol\;mol^{-1}$) as the default index for setting critical levels in Asia would be a poor policy with severe consequences at national and Pan-Asian level. Asian studies should focus on flux-based $O_3$ metrics to provide relevant bases for developing proper standards. However, given the technical requirements in calculating flux-based $O_3$ metrics, which can be an important limitation in developing countries, no-threshold cumulative exposure indices like AOT0 should always accompany flux-based indices.

• Journal of Environmental Science International
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• v.21 no.2
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• pp.153-163
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• 2012

The seasonal variations of ozone ($O_3$) concentrations were investigated with regard to the relationship between $O_3$ and wind distributions at two different sites (Jung Ang (JA): a semi-closed topography and Seo Chang (SC): a closed topography) within a valley city (Yangsan) and their comparison between these sites (JA and SC) and two non-valley sites (Dae Jeo (DJ) and Sang Nam (SN)) located downwind from coastal cities (Busan and Ulsan). This analysis was performed using the data sets of hourly $O_3$ concentrations, meteorological factors (especially, wind speed and direction), and those on high $O_3$ days exceeding the 8-h standard (60 ppb) during 2008-2009. In summer and fall (especially in June and October), the monthly mean values of the daily maximum $O_3$ concentrations and the number of high $O_3$ days at JA (and SC) were relatively higher than those at DJ (and SN). The increase in daytime $O_3$ concentrations at JA in June was likely to be primarily impacted by the transport of $O_3$ and its precursors from the coastal emission sources in Busan along the dominant southwesterly winds (about 5 m/s) under the penetration of sea breeze condition, compared to other months and sites. Such a phenomenon at SC in October was likely to be mainly caused by the accumulation of $O_3$ and its precursors due to the relatively weak winds under the localized stagnant weather condition rather than the contribution of regional transport from the emission sources in Busan and Ulsan.

• Asian Journal of Atmospheric Environment
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• v.2 no.2
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• pp.81-89
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• 2008

The numerical simulation of wind and ozone ($O_3$) transport in mountainous regions was performed with a computational fluid dynamics technique. A dry deposition model for $O_3$ was designed to estimate $O_3$ deposition in complex terrain, and the qualitative validity of the predicted $O_3$ concentration field was confirmed by comparison with observed data collected with passive samplers. The simulation revealed that wind velocity increases around ridge lines and peaks of mountains. The areas with strong wind corresponded well with the sites of tree decline at high altitudes, suggesting that it is an important factor in the localization of tree/forest decline. On the other hand, there is no direct relationship between forest decline and $O_3$ concentration. The $O_3$ concentration, however, tends to increase as wind velocity becomes higher, thus the $O_3$ concentration itself may be a potential secondary factor in the localized decline phenomena. While the diffusion flux of $O_3$ is not related to localized tree decline, the pattern of advection flux is related to those of high wind velocity and localized tree decline. These results suggest that strong wind with large advection flux of $O_3$ may play a key role in the promotion of tree/forest decline at high mountain ridges and peaks.

• Asian Journal of Atmospheric Environment
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• v.9 no.2
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• pp.114-127
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• 2015

In the Mexico City Metropolitan Area (MCMA), ozone ($O_3$) concentration is still higher than in other urban areas in developed countries. In order to reveal the current state of photochemical air pollution and to provide data for validation of chemical transport models, vertical profiles of meteorological parameters and ozone concentrations were measured by ozonesonde in two field campaigns: the first one, during the change of season from wet to dry-cold (November 2011) and the second during the dry-warm season (March 2012). Unlike previous similar field campaigns, ozonesonde was launched twice daily. The observation data were used to analyze the production and distribution of ozone in the convective boundary layer. The observation days covered a wide range of meteorological conditions, and various profiles were obtained. The evolution of the mixing layer (ML) height was analyzed, revealing that ML evolution was faster during daytime in March 2012 than in November 2011. On a day in November 2011, the early-morning strong wind and the resulting vertical mixing was observed to have brought the high-ozone-concentration air-mass to the ground and caused relatively high surface ozone concentration in the morning. The amount of produced ozone in the MCMA was estimated by taking the difference between the two profiles on each day. In addition to the well-known positive correlation between daily maximum temperature and ozone production, effect of the ML height and wind stagnation was identified for a day in March 2012 when the maximum ground-level ozone concentration was observed during the two field campaigns. The relatively low ventilation coefficient in the morning and the relatively high value in the afternoon on this day implied efficient accumulation of the $O_3$ precursors and rapid production of $O_3$ in the ML.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.11a
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• pp.331-332
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• 2005

Ozone is ambient gas which is useful for the fabrication of metal oxide thin films under conditions of molecular beam epitaxy. Ozone is condensed by the adsorption method and its concentration is analyzed using the thermal decomposition method. The concentration of ozone exceeds 90 mol% and ozone is supplied for a sufficiently long time to grow oxide thin films. The ozone concentration is also evaluated using a quadrupole mass analyzer and the accuracy of this method is compared with the results of the thermal decomposition method.

• Environmental Engineering Research
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• v.11 no.6
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• pp.293-302
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• 2006

The reaction of ozone with NOM (Natural Organic Matter) can occur by two different pathways: that involving molecular ozone and by way of reactions with hydroxyl radicals which are produced from the decomposition of molecular ozone. As such, the formation of ketoacids and Assimilable Organic Carbon (AOC) can be controlled by controlling the pathway by which ozone reacts with NOM. The ratios of $[OH{\cdot}]/[O_3]$ ($R_{CT}$ values) were determined under the various ozonation conditions. The $R_{CT}$ values increased with increasing initial ozone concentration. The $R_{CT}$ values (ranges from 10 to $35^{\circ}C$) increased linearly as temperature increased (within the range from 10 to $35^{\circ}C$). However, $R_{CT}$ was independent of hydraulic retention time (HRT). Operational conditions were found to affect the formation of AOC. The conditions where the molecular ozone reaction predominated resulted in an increase in the formation of AOC.

• Asian Journal of Atmospheric Environment
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• v.9 no.4
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• pp.259-271
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• 2015

This study conducted analyses on biogenic volatile organic compounds (BVOC) emission sources contributing to urban ozone ($O_3$) concentration in Osaka Prefecture, Japan in summer 2010 by using the Weather Research and Forecasting model (WRF) version 3.5.1 and the Community Multiscale Air Quality model (CMAQ) version 5.0.1. This prefecture is characterized by highly urbanized area with small forest area. The contributions of source regions surrounding Osaka were estimated by comparing the baseline case and zero-out cases for BVOC emissions from each source region. The zero-out emission runs showed that the BVOC emissions substantially contributed to urban $O_3$ concentration in Osaka (10.3 ppb: 15.9% of mean daily maximum 1-h $O_3$ concentration) with day-by-day variations of contributing source regions, which were qualitatively explained by backward trajectory analyses. Although $O_3$ concentrations were especially high on 23 July and 2 August 2010, the contribution of BVOC on 23 July (35.4 ppb: 25.6% of daily maximum $O_3$) was much larger than that on 2 August (20.9 ppb: 14.2% of daily maximum $O_3$). To investigate this difference, additional zero-out cases for anthropogenic VOC (AVOC) emissions from Osaka and for VOC emissions on the target days were performed. On 23 July, the urban $O_3$ concentration in Osaka was dominantly increased by the transport from the northwestern region outside Osaka with large contribution of $O_3$ that was produced through BVOC reactions by the day before and was retained over the nocturnal boundary layer. On 2 August, the concentration was dominantly increased by the local photochemical production inside Osaka under weak wind condition with the particularly large contribution of AVOC emitted from Osaka on the day.

• Korean Journal of Materials Research
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• v.14 no.5
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• pp.353-357
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• 2004

The influences of the ozone oxidation, reaction temperature and NaOH equivalent ratio on the iron oxide formation were studied with fixed ferrous sulfate concentration(0.5M $FeSO_4$ㆍ$7H_2$O). Geothite($\alpha$-FeOOH) and/or Magnetite ($Fe_3$$O_4$) were synthesized depending on the reaction conditions. The characteristics of the synthesized powders were evaluated by XRD, SEM and quantitative phase analysis. The synthetic conditions to get Goethite were quite different from the results of Kiyama's and the Goethite was conveniently synthesized at low temperature and at low NaOH equivalent ratio.