• 제목/요약/키워드: Oxygen-plasma treatment

검색결과 332건 처리시간 0.029초

플라즈마 표면개질에 따른 FRP의 자외선 열화 특성에 관한 연구 (A Study on the UV Degradation characteristics of FRP by Plasma Surface Modification)

  • 임경범;이상희;유도현;황명환;임응춘;조기선;이덕출
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 하계학술대회 논문집 C
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    • pp.1544-1546
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    • 2003
  • In this study, composite materials were put to dry interfacial treatment by use of plasma technology. It has been presented that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system Pressure, 100 W of discharge power, and 3 minutes of discharge time. The decrease in surface potential of charged samples by corona discharge indicates that the amount of accumulated electrical charges reduces and the charges that have been injected lessen rapidly when the duration of UV irradiation increases. The surface resistivity and the tensile strength of plasma treated samples, a longer UV irradiation time resulted in decreased insulation.

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코로나 방전처리에 의한 폴리에스테르 및 P/C 혼방직물의 복합기능화 가공(II) - 복합 기능화 가공 - (Multi-Functional Finish of Polyester and P/C blend Fabrics by Corona Discharge(II) - Multifunctional finish-)

  • Lee, Bang One;Pak, Pyong Ki;Yeo, Joo Hong;Lee, Hwa Sun
    • 한국염색가공학회지
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    • 제9권3호
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    • pp.1-9
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    • 1997
  • Plasma techniques permit modification of the surface layers of the substrate while maintaining its bulk properties. The use of plasma treatment on textile fibers and fabrics is very limited, however, the limitations, plasma treatments have been used to modify surface properties of textiles. In this study, multifunctional finish was performed by corona discharge technique for surface functionalization. Electron spectroscopy for chemical analysis(ESCA) was used to determine the ratios of carbon, oxygen, nitrogen, and phosphor at a 20$\AA$ sampling depth. K/S value and limiting oxygen index(LOI) value were used to obtain information on the effect of the finished fabrics. The mechanism of the flame retardancy was analyzed by the thermogravimetry-and the residue number. In ESCA, relative N1s intensity increased in case of mixtrure. The flame retardancy of the polyester and polyester/cotton fabrics treated with JA-6034 and JA-6050 was found to be operative mainly in the condensed phase mechanism. The multifunctional finish was better effect for the post treated finish agent.

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금속재와 폴리에틸렌 재료간의 접착강도 향상에 대한 연구 (A Study on the Improvement of Adhesive Strength of Between Metal and Polyethylene Materials)

  • 이지훈;김현주;정동호;이경엽
    • 한국정밀공학회지
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    • 제24권12호
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    • pp.143-148
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    • 2007
  • Polyethylene is a typical hydrophobic material and it is difficult to bond the polyethylene material with metal material. Thus, it is important to modify the surface of polyethylene material to improve the bonding strength between the polyethylene and the metal materials. In this study, the surface modification of polyethylene material was investigated to improve the interfacial strength between the polyethylene and the steel materials. Polyethylene material was surface-modified in a plasma cleaner using an oxygen gas. Two cases of composites (surface-modified pelyethylene/steel composite and regular (as-received) pelyethylene/steel composite) were fabricated using a secondary bonding method. Shear and bending tests have been performed using the two cases of composites. The results showed that the contact angle did not change much as the modification time increased. However, the contact angle decreased from ${\sim}76^{\circ}\; to\;{\sim}41^{\circ}$ with the modification. The results also showed that the shear strength and the bending strength were improved about 3030 % and 7 %, respectively when the polyethylene was plasma-modified using an oxygen gas.

유도결합 플라즈마 스퍼터링을 이용한 플라스틱 기판 상의 Al이 도핑된 ZnO 박막 증착 (Deposition of Al Doped ZnO Films Using ICP-assisted Sputtering on the Plastic Substrate)

  • 정승재;한영훈;이정중
    • 한국표면공학회지
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    • 제39권3호
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    • pp.98-104
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    • 2006
  • Al-doped ZnO (AZO) films were deposited on the plastic substrate by inductively coupled plasma (ICP) assisted DC magnetron sputtering. The AZO films were produced by sputtering a metallic target (Zn/Al) in a mixture of argon and oxygen gases. AZO films with an electrical resistivity of ${\sim}10^3\;{\Omega}cm$ and an optical transmittance of 80% were obtained even at a low deposition temperature. In-situ process control methods were used to obtain stable deposition conditions in the transition region without any hysteresis effect. The target voltage was controlled either at a constant DC power. It was found that the ratio of the zinc to oxygen emission intensity, I (O 777)/I (Zn 481) decreased with increasing the target voltage in the transition region. The $Ar/O_2$ plasma treatment improve the adhesion strength between the polycarbonate substrate and AZO films.

Characteristics of Bovine Teeth Whitening in Accordance with Gas Environments of Atmospheric Pressure Nonthermal Plasma Jet

  • Sim, Geon Bo;Kim, Yong Hee;Kwon, Jae Sung;Park, Daehoon;Hong, Seok Jun;Kim, Young Seok;Lee, Jae Lyun;Lee, Gwang Jin;Lim, Hwan Uk;Kim, Kyung Nam;Jung, Gye Dong;Choi, Eun Ha
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.250.2-250.2
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    • 2014
  • Currently, teeth whitening method which is applicable to dental surgery is that physician expertises give medical treatment to teeth directly dealed with a high concentration of hydrogen peroxide and carbamide peroxide. If hydrogen peroxide concentration is too high for treatment of maximized teeth whitening effect [1], it is harmful to the human body [2]. To the maximum effective and no harmful teeth whitening effect in a short period of time at home, we have observed the whitening effect using carbamide peroxide (15%) and a low-temperature atmospheric pressure plasma jet which is regulated by the Food and Drug Administration. The gas supplied conditions of the non-thermal atmospheric pressure plasma jet was with the humidified (0.6%) gas in nitrogen or air at gas flow rate of 1000 sccm. Also, the measurement of chemical species from the jet was carried out using the optical emission spectroscopy (OES), the evidence of increased reactive oxygen species compared to non-humidified plasma jet. We have found that the whitening effect of the plasma is very excellent through this experiment, when bovine teeth are treated in carbamide peroxide (15%) and water vapor (0.2 to 1%). The brightness of whitening teeth was increased up to 2 times longer in the CIE chromaticity coordinates. The colorimetric spectrometer (CM-3500d) can measure color degree of whitening effect.

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플라즈마 고분자 코팅에 의한 강철 타이어 코드의 표면 개질 : 제1부. 타이어 코드의 접착성 (Surface Modification of Steel Tire Cords via Plasma Etching and Plasma Polymer Coating : Part I. Adhesive properties)

  • 강현민;정경호;강신영;윤태호
    • Elastomers and Composites
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    • 제35권1호
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    • pp.53-62
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    • 2000
  • 아연 도금된 강철 타이어 코드를 아세틸렌 또는 부타디엔 가스를 이용한 플라즈마 고분자 중합으로 고무와의 접착성 향상을 위하여 코팅하였다. 플라즈마의 세기, 중합 시간 및 가스의 압력을 변화시키면서 플라즈마 고분자 중합을 실시하였으며, 아르곤 가스를 이용한 에칭도 실시하였다. 또한 플라즈마 중합시에 아르곤, 질소 또는 산소를 담체 가스로 사용하여 접착성 향상으로 도모하였으며, 접착성은 TACT 방법으로 측정하였다. 아르곤 에칭 (90W, 10min, 30mTorr) 후에 아르곤 가스를 (25/5 : 아세틸렌/아르곤) 담체로 사용하여 아세틸렌 플라즈마 중합 (10W, 30sec, 30mTorr)으로 코팅된 타이어 코드가 285N의 접착력으로 가장 좋은 결과를 보였으며, 이는 황동으로 코팅된 타이어 코드의 290N과 같은 수준의 접착력이다.

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대기압 유전체장벽방전 플라즈마에 의한 식품유해 미생물 살균 (Sterilization of Food-Borne Pathogenic Bacteria by Atmospheric Pressure Dielectric Barrier Discharge Plasma)

  • 이승제;송윤석;박유리;유승민;전형원;엄상흠
    • 한국식품위생안전성학회지
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    • 제32권3호
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    • pp.222-227
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    • 2017
  • 연구는 대기압 유전체장벽방전 플라즈마 처리에 따른 식품유해 미생물 사멸효과를 조사하기 위해 수행되었다. 플라즈마 처리 시, 활성종 생성 및 농도에 영향을 미치는 노출시간, 노출거리, 산소비율, 전력 변화에 따른 E. coli의 사멸효과를 조사한 결과, E. coli의 사멸율은 플라즈마 처리를 위한 노출시간, 산소비율, 전력의 증가에 따라 증가한 반면, 노출거리의 증가에 따라서는 사멸율이 감소하였다. 이 결과는 미생물 시료가 플라즈마에 노출되는 시간이 증가됨으로서 시료 내 NO 농도가 증가되고, E. coli의 사멸율 역시 증가되는 결과로 뒷받침할 수 있고, 미생물 사멸효과를 높이기 위해서는 활성종의 농도가 증가되어야 함을 의미한다. E. coli와 함께 B. cereus, B. subtilis, B. thuringiensis, B. atrophaeus를 대상으로 대기압 유전체 장벽방전 플라즈마에 의한 살균효과를 조사한 결과, 72.3~91.3%의 높은 사멸율을 나타내었다. 이러한 결과로 미루어, 대기압 유전체장벽방전 플라즈마기술은 다양한 미생물에 적용될 수 있는 유용한 살균기술임을 확인하였다.

Oxygen Plasma Effect on AlGaN/GaN HEMTs Structure Grown on Si Substrate

  • Seo, Dong Hyeok;Kang, Sung Min;Lee, Dong Wha;Ahn, Du Jin;Park, Hee Bin;Ahn, Youn Jun;Kim, Min Soo;Kim, Yu Kyeong;Lee, Ho Jae;Song, Dong Hun;Kim, Jae Hee;Bae, Jin Su;Cho, Hoon Young
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.420-420
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    • 2013
  • We investigated oxygen plasma effect on defect states near the interface of AlGaN/GaN High Electron Mobility Transistor (HEMT) structure grown on a silicon substrate. After the plasma treatment, electrical properties were evaluated using a frequency dependant Capacitance-Voltage (C-V) and a temperature dependant C-V measurements, and a deep level transient spectroscopy (DLTS) method to study the change of defect densities. In the depth profile resulted from the temperature dependant C-V, a sudden decrease in the carrier concentration for two-dimensional electron gas (2DEG) nearby 250 K was observed. In C-V measurement, the interface states were improved in case of the oxygen-plasma treated samples, whereas the interface was degraded in case of the nitrogen-plasma treated sample. In the DLTS measurement, it was observed the two kinds of defects well known in AlGaN/GaN structure grown on sapphire substrate, which have the activation energies of 0.15 eV, 0.25 eV below the conduction band. We speculate that this defect state in AlGaN/GaN on the silicon substrate is caused from the decrease in 2DEG's carrier concentrations. We compared the various DLTS signals with filling pulse times to identify the characteristics of the newly found defect. In the filling pulse time range under the 80 us, the activation energies changed as the potential barrier model. On the other hand, in the filling pulse time range above the 80 us, the activation energies changed as the extended potential model. Therefore, we suggest that the found defect in the AlGaN/GaN/Si structure could be the extended defect related with AlGa/N/GaN interface states.

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Plasma bioscience for medicine, agriculture and hygiene applications

  • Eun Ha Choi;Nagendra Kumar Kaushik;Young June Hong;Jun Sup Lim;Jin Sung Choi;Ihn Han
    • Journal of the Korean Physical Society
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    • 제80권
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    • pp.817-851
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    • 2022
  • Nonthermal biocompatible plasma (NBP) sources operating in atmospheric pressure environments and their characteristics can be used for plasma bioscience, medicine, and hygiene applications, especially for COVID-19 and citizen. This review surveyed the various NBP sources, including a plasma jet, micro-DBD (dielectric barrier discharge) and nanosecond discharged plasma. The electron temperatures and the plasma densities, which are produced using dielectric barrier discharged electrode systems, can be characterized as 0.7 ~ 1.8 eV and (3-5) × 1014-15 cm-3, respectively. Herein, we introduce a general schematic view of the plasma ultraviolet photolysis of water molecules for reactive oxygen and nitrogen species (RONS) generation inside biological cells or living tissues, which would be synergistically important with RONS diffusive propagation into cells or tissues. Of the RONS, the hydroxyl radical [OH] and hydrogen peroxide H2O2 species would mainly result in apoptotic cell death with other RONS in plasma bioscience and medicines. The diseased biological protein, cancer, and mutated cells could be treated by using a NBP or plasma activated water (PAW) resulting in their apoptosis for a new paradigm of plasma medicine.

방전처리에 의한 Polypropylene섬유의 표면개질 (Surface Modification of Polypropylene Fiber by Plasma Discharge)

  • 허만우;이창재;강인규;한명호;김삼수;임학상
    • 한국염색가공학회지
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    • 제11권2호
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    • pp.27-37
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    • 1999
  • Polypropylene(PP) films were treated with plasma glow discharge to produce peroxy radicals on the surfaces. The peroxy radicals formed on the PP film surfaces were subsequently used for the graft polymerization of acrylic acid and acrylamide in an aqueous solution by heating, respectively. Introduction of acrylic acid and acrylamide on the PP film could be confirmed by the observation of carbonyl and primary amine absorptions based on carboxylic acid and amide, respectively. And introduction of functional group could be confirmed by weight analysis and ESCA. The water contact angle(90$^{\circ}$) of PP film was constant, irrespective of elapsed time, while plasma-treated and functional monomer-grafted PP films were slowly increased with elapsed time, showing the rearrangement of surface polar groups in air condition. The water contact angle$(90^\circ)$ of PP film was decreased by the plasma treatment$(56^\circ)$ and further decreased by the grafting of acrylic acid$(34^\circ)$ and acrylamide$(37^\circ)$, indicating increased hydrophilicity of the modified surfaces. The water contact angle of plasma-treated PP film increased a little as time elapsing. The half-life periods of surface voltage on acrylic acid-(31sec) and acrylamide-grafted PP(42sec) were significantly decreased when compared to those on PP(950sec) and plasma-treated PP film(241sec). In the experiments using acid, basic and disperse dyes, absorbance and $\Delta{E}$ values of functional monomer-grafted PP films were significantly increased than that of oxygen plasma-treated one.

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