• Title/Summary/Keyword: Oxygen-Concentration

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Fabrication of Oxygen Sensitive Particles and Characteristic Analysis (산소감응성 입자 제조 및 특성 분석 연구)

  • Jeong, Won-Taek;Yi, Seung-Jae;Kim, Hyun-Dong;Kim, Kyung-Chun
    • Journal of the Korean Society of Visualization
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    • v.9 no.4
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    • pp.41-46
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    • 2011
  • Oxygen sensitive functional particles(OSParticle) were fabricated by three different methods for using the particles as oxygen sensors and PIV tracers. The used methods were a physical coating method, an ion-exchange method and a dispersion polymerization method. The physical coating method is dipping $SiO_2$ hollow particles into dye solution then drying. This method is very simple, but particles are not uniform in diameter and luminescence. The particles fabricated by the ion-exchange method have very uniform diameter and well doped. However, it can not be used in water since the particles are hydrophobic. In case of the dispersion polymerization method, the diameter of OSParticles is quite uniform. The diameter of OSParticles can be changed by controlling the quantity of AIBN (2,2'-azobis isobutyronitrile). For the purpose of dissolved oxygen concentration measurement in micro scale water flows, the dispersion polymerized OSParticles turn out to be the most superior functional particles. The luminescent intensity of OSParticles was tested with the variation of dissolved oxygen concentration in water samples. As a result, the luminescent intensity of OSParticles is monotonically decreased with increasing DO (Dissolved oxygen) concentration of water.

Effect of Non-lattice Oxygen Concentration and Micro-structure on Resistance Switching Characteristics in Nb-doped HfO2 by DC Magnetron Co-Sputtering

  • Lee, Gyu-Min;Kim, Jong-Gi;Kim, Yeong-Jae;Kim, Jong-Il;Son, Hyeon-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.378.1-378.1
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    • 2014
  • In this study, we investigated that the resistance switching characteristics of Nb-doped HfO2 films with increasing Nb doping concentration. The Nb-doped HfO2 based ReRAM devices with a TiN/Nb-doped HfO2/Pt/Ti/SiO2 were fabricated on Si substrates. The Nb-doped HfO2 films were deposited by reactive dc magnetron co-sputtering at $300^{\circ}C$ and oxygen partial ratio of 60% (Ar: 16sccm, O2: 24sccm). Microstructure of Nb-doped HfO2 films and atomic concentration were investigated by XRD, TEM, and XPS, respectively. The Nb-doped HfO2 films showed set/reset resistance switching behavior at various Nb doping concentrations. The process voltage of forming/set is decreased and whereas the initial current level is increased in doped HfO2 films. However, the switching properties of Nb-doped HfO2 were changed above the specific doping concentration of Nb. The change of resistance switching behavior depending on doping concentration was discussed in terms of concentration of non-lattice oxygen and micro-structure of Nb-doped HfO2.

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Effect of Ambient Conditions on the Soot Generation of Decane Fuel Droplet (분위기 조건이 Decane 액적의 Soot 생성에 미치는 영향)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of ILASS-Korea
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    • v.19 no.4
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    • pp.211-215
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    • 2014
  • The main purpose of this study is to provide basic information of droplet soot generation of decane fuel. To achieve this, this paper presents the experimental results on the decane droplet combustion conducted under various ambient pressure($P_{amb}$), and oxygen concentration($O_2$) conditions. At the same time, the experimental study was conducted in terms of soot volume fraction($f_v$) and its maximum value. Also, visualization of single fuel droplet was conducted by high resolution CCD camera and ambient pressure($P_{amb}$) and oxygen concentration($O_2$) was changed by control system. It was revealed that higher ambient pressure($P_{amb}$), and oxygen concentration($O_2$) enhanced the soot generation and improved the maximum soot volume fraction( $f_v$).

Approximated Solution of Model for Three-Phase Fluidized Bed Biofilm Reactor in Wastewater Treatment

  • Choi Jeong-Woo;Min Junhong;Lee Won-Hong;Lee Sang Baek
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.5 no.1
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    • pp.65-70
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    • 2000
  • An approximated analytical solution of mathematical model for the three phase fluidized bed bioreactor (TFBBR) was proposed using the linearization technique to describe oxygen utilization rate in wastewater treatment. The validation of the model was done in comparison with the experimental results. Satisfactory agreement was obtained in the comparison of approximated analytical solution and numerical solution in the oxygen concentration profile of a TFBBR. The approximated solutions for three modes of the liquid phase flow were compared. The proposed model was able to predict the biomass concentration, dissolved oxygen concentration the height of efficient column, and the removal efficiency.

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NO Reduction and Oxidation over PAN based-ACF

  • Kim, Je-Young;Lee, Jong-Gyu;Hong, Ik-Pyo
    • Carbon letters
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    • v.1 no.1
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    • pp.17-21
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    • 2000
  • Catalytic reduction and oxidation of NO over polyacrylonitrile based activated carbon fibers (PAN-ACF) under various conditions were carried out to develop removal process of NO from the flue gas. The effect of temperature, oxygen concentration and the moisture content for the reduction of NO with ammonia as a reducing agent was investigated. The reduction of NO increased with the oxygen concentration, but decreased with the increased temperature. The moisture content in the flue gas affects the reduction of NO as the inhibition of the adsorption of the other components and the reaction on the surface of ACE For the oxidation of NO to $NO_2$ over PAN-ACF without using a reducing gas, it showed the temperature and the oxygen concentration of the flue gas are the important factors for the NO conversion in which the conversion increased with oxygen concentration and decreased with the temperature increase and might be the alternative option for the selective catalytic reduction process.

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A Study on Effect of Intake Charging Conditions upon NO Emissions in a DI Diesel Engine Using Engine Cycle Simulation (엔진 사이클 시뮬레이션에 의한 직분식 디젤기관의 NO 배출물에 미치는 흡기충전 조건의 영향에 관한 연구)

  • 함윤영
    • Journal of Advanced Marine Engineering and Technology
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    • v.26 no.6
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    • pp.679-687
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    • 2002
  • In this study, a cycle simulation using a two-zone model is carried out to investigate the effect of intake charging conditions such as oxygen concentration, temperature and pressure on NO emissions in a DI diesel engine. The model is validated against measurements in terms of cylinder pressure, torque, BSFC and NOx emissions with 2902 cc DI diesel engine. Calculated results can be summarized as follows. The oxygen concentration in the intake charge is decreased with increasing of EGR rate and equivalence ratio. As the intake oxygen concentration is reduced, the combustion pressure and the burned gas temperature decrease and, as a result, NO formation decreases. Also, the results show that as the intake pressure increases and the intake temperature decreases, NO emissions are effectively reduced.

Oxygen Permeability Measurement of $ZrO_2-TiO_2-YB_2O_3$ Mixed Conductor

  • Hitoshi Naito;Kim, Hitoshi ishima;Toru Takahashi;Hiroo Yugami
    • The Korean Journal of Ceramics
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    • v.6 no.2
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    • pp.124-128
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    • 2000
  • Electrical properties of $ZrO_2-TiO_2Yb_2O_3$mixed conductor (Ti-YbSZ) were investigated. This mixed conductor can be applied as a membrane for gas separation at high temperatures. The total conductivity decreased with increasing the $TiO_2$concentration. At high temperatures, the rate of the conductivity degradation became smaller than that at low temperatures. From the oxygen partial pressure dependence of the total conductivity of Ti-YbSZ, the electronic conductivity increased with increasing $TiO_2$concentration at low oxygen partial pressures and at high temperatures. Both 15 and 20 mol% $TiO_2$doped YbSZ showed high oxygen permeability. Mixed conductors, which has high $TiO_2$concentration in YbSZ, are promising materials for using as a membrane for gas separation at high temperatures.

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Fabrication and characteristics of limit-current type oxygen sensor with monolith aperture structure (일체화된 Aperture 구조의 한계전류형 산소센서의 제작 및 특성)

  • Oh, Young-Jei;Lee, Deuk Yong
    • Journal of Sensor Science and Technology
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    • v.17 no.4
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    • pp.273-280
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    • 2008
  • Monolith aperture-type oxygen sensors with simple structure of YSZ(pin-hole)/Pt/ YSZ(solid electrolyte)/Pt were fabricated by co-firing technique. To enhance the yield of productivity, a couple of YSZ green sheets for diffused barrier and solid electrolyte were prepared by tape-casting and co-firing method. The limit current characteristics of the oxygen sensors were measured between 500 and $650^{\circ}C$ The heating temperature of $600^{\circ}C$ was optimum as a portable oxygen sensor in the range of oxygen concentration from 0 to 75 vol%. Linear proficiency of limit current behavior as a function of oxygen concentration was controlled by the variation of aperture dimension. The fabricated oxygen sensors showed the stable sensing output for 30 days. Gas leakage in bonding area due to warping, cracking and thermal cycling was not found in the period.

Hydrogen photoproduction by the synchronously grown marine unicellular cyanobacterium Synechococcus sp. Miami BG 043511 under extremely high oxygen concentration

  • Yih, Won-Ho;Takeyama, Haruko;Mitsui, Akira
    • Journal of the korean society of oceanography
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    • v.31 no.1
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    • pp.18-22
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    • 1996
  • The effect of exogenous oxygen on hydrogen photoproduction was examined in the synchronously grown cells of marine Synechococcus sp. Miami BG 043511 under conditions of high cell density (0.6-0.8 mg chl-${\alpha}$ $ml^{-1}$) and high light intensity (1000 ${\mu}$E $m^{-2}$ $s^{-1}$). Hydrogen evolution after 20-h incubation did not decline under the initial oxygen concentrations up to 20%, but declined by half under 34% oxygen. 50% and 100% oxygen gas phase did not completely inhibit the hydrogen photoproduction during 40-h incubations. After 2-day pretreatment under 100% exogenous oxygen the hydrogen photoproduction capabilities were not irreversibly inhibited, which was demonstrated in the subsequent 9-day incubation under initial 0, 50 and even under 100% oxygen gas phase. This strain could be useful for developing a hydrogen photoproduction system under atmospheric oxygen concentration.

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A Study on the Regeneration of Ni Catalyst for Hydrogenation(II) (수소첨가반응용 니켈 폐촉매의 활성재생에 관한 연구 (II))

  • Kim, Jung-Hun;Lee, Gun-Dae;Lee, Ho-In
    • Applied Chemistry for Engineering
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    • v.2 no.1
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    • pp.47-55
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    • 1991
  • Regeneration of carbon-deposited Ni catalyst used for hydrogenation reaction was studied. Deposited carbon was removed by oxidation with various concentrations of oxygen. Activity of the catalysts was tested on aniline hydrogenation as a model reaction. When a carbon-deposited catalyst was treated under oxygen atmosphere, the specific surface area of the catalyst increased and then decreased with the increase of treatment temperature. The treatment temperature which gives maximum specific surface area increased with the decrease of oxygen concentration. Pore size of the support was decreased and sintering of nickel particles was more significant with the increase of oxygen concentration. The catalyst treated under 5 % oxygen concentration recovered its catalytic activity up to 90 % of the initial value, but the treatment under 20 % oxygen concentration gave no significant increase of the catalytic activity. Catalytic activity increased with treatment time when the catalyst was treated under 5 % oxygen concentration, but nearly constant after 1 hour.

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