• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.417-423
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• 2007

Oxy-gasification or oxygen-blown gasification, enables a clean and efficient use of coal and opens a promising way to CO2 capture. The coal gasification process of a slurry feed type, entrained-flow coal gasifier was numerically predicted in this paper. The purposes of this study are to develop an evaluation technique for design and performance optimization of coal gasifiers using a numerical simulation technique, and to confirm the validity of the model. By dividing the complicated coal gasification process into several simplified stages such as slurry evaporation, coal devolatilization, mixture fraction model and two-phase reactions coupled with turbulent flow and two-phase heat transfer, a comprehensive numerical model was constructed to simulate the coal gasification process. The influence of turbulence on the gas properties was taken into account by the PDF (Probability Density Function) model. A numerical simulation with the coal gasification model is performed on the Conoco-Philips type gasifier for IGCC plant. Gas temperature distribution and product gas composition are also presented. Numerical computations were performed to assess the effect of variation in oxygen to coal ratio and steam to coal ratio on reactive flow field. The concentration of major products, CO and H2 were calculated with varying oxygen to coal ratio (0.2-1.5) and steam to coal ratio(0.3-0.7). To verify the validity of predictions, predicted values of CO and H2 concentrations at the exit of the gasifier were compared with previous work of the same geometry and operating points. Predictions showed that the CO and H2 concentration increased gradually to its maximum value with increasing oxygen-coal and hydrogen-coal ratio and decreased. When the oxygen-coal ratio was between 0.8 and 1.2, and the steam-coal ratio was between 0.4 and 0.5, high values of CO and H2 were obtained. This study also deals with the comparison of CFD (Computational Flow Dynamics) and STATNJAN results which consider the objective gasifier as chemical equilibrium to know the effect of flow on objective gasifier compared to equilibrium. This study makes objective gasifier divided into a few ranges to study the evolution of the gasification locally. By this method, we can find that there are characteristics in the each scope divided.

• Journal of Korea Water Resources Association
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• v.36 no.6
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• pp.971-984
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• 2003

This paper presents the hydraulic analysis of the air entrainment by the weir types. For the weir types, the stepped weir, the labyrinth weir and the gate underflow weir were selected, and the oxygen transfer efficiency was estimated by the site investigation and the hydraulic model tests. The most effective type for the oxygen transfer was stepped weir The more steps the stepped weir had, the higher efficiency it revealed. Oxygen transfer was proportional to the flow velocity, the Froude number, and the flow discharge in order. Hydraulic model tests showed that a nappe flow occurred at small flow rates. The concurrent condition of a nappe flow and a skimming flow occurred as flow rate increases, nappe flow at the upper part and skimming flow at the lower part. In the region of nappe flow, air inception occurred from the step edges due to flow separation, and air entrainment was made through a free-falling nappe, an air pocket, a nappe impact and a subsequent hydraulic jump. In the region of skimming flow, air entrainment occurred by the variation of water surface over the steps, but it was relatively small compared with nappe flow.

• Journal of The Korean Astronomical Society
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• v.42 no.4
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• pp.81-91
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• 2009

We make a new catalog of AGB stars in our Galaxy from the sources listed in the Infrared Astronomical Satellite (IRAS) point source catalog (PSC) compiling the lists of previous works with verifying processes. We verify the class identification of AGB stars into oxygen-rich and carbon-rich stars using the information from recent investigations. For the large sample of AGB stars, we present infrared two-color diagrams from the observations at near infrared bands and IRAS PSC. On the two-color diagrams, we plot the tracks of theoretical radiative transfer model results with increasing dust shell optical depths. Comparing the observations with the theoretical tracks, we discuss the meaning of the infrared two-color diagrams.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.10
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• pp.2418-2425
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• 1993

A two-dimensional transient heat transfer model for reactive gas assisted laser cutting process with a moving Gaussian heat source is developed using a numerical finite difference technique. The kerf width, melting front shape and temperature distribution were calculated by using the boundary-fitted coordinate system to handle the ejection of workpiece material and heat input from reaction and evaporation. An analytical solution for cutting front movement was adopted and numerical simulation was performed to calculate the temperature distribution and melting front thickness. To calculate the moving velocity of cutting front, the normal distribution of the cutting gas velocity was used. The kerf width was revealed to be dependent on the cutting velocity, laser power and cutting gas velocity.

• Nuclear Engineering and Technology
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• v.41 no.1
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• pp.39-52
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• 2009

Theory-based models and high performance simulations are briefly reviewed starting with atomistic methods, such as Electronic Structure calculations, Molecular Dynamics, and Monte Carlo, continuing with meso-scale methods, such as Dislocation Dynamics and Phase Field, and ending with continuum methods that include Finite Element and Finite Volume. Special attention is paid to relating thermo-mechanical and chemical properties of the fuel to reactor parameters. By inserting atomistic models of point defects into continuum thermo-chemical calculations, a model of oxygen diffusivity in $UO_{2+x}$ is developed and used to predict point defect concentrations, oxygen diffusivity, and fuel stoichiometry at various temperatures and oxygen pressures. The simulations of coupled heat transfer and species diffusion demonstrate that including the dependence of thermal conductivity and density on composition can lead to changes in the calculated centerline temperature and thermal expansion displacements that exceed 5%. A review of advanced nuclear fuel performance codes reveals that the many codes are too dedicated to specific fuel forms and make excessive use of empirical correlations in describing properties of materials. The paper ends with a review of international collaborations and a list of lessons learned that includes the importance of education in creating a large pool of experts to cover all necessary theoretical, experimental, and computational tasks.

• Journal of the Korea Safety Management & Science
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• v.20 no.4
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• pp.7-13
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• 2018

This study investigates the enhancement of the oxygen diffusion rate in the cathode channel of a proton exchange membrane fuel cell (PEMFC) by pure oscillating flow, which is the same as the mechanism of human breathe. Three-dimensional numerical simulation, which has the full model of the fuel cell including electrochemical reaction, ion and electronic conduction, mass transfer and thermal variation and so on, is performed to show the phenomena in the channel at the case of a steady state. This model could analysis the oscillating flow as a moving mesh calculation coupled with electrochemical reaction on the catalyst layer, however, it needs a lot of calculation time for each case. The two dimensional numerical simulation has carried on for the study of oscillating flow effect in the cathode channel of PEMFC in order to reduce the calculation time. This study shows the diffusion rate of the oxygen increased and the emission rate of the water vapor increased in the channel by oscillating flow without any forced flow.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.7 no.1
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• pp.27-40
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• 1997

The heat in Czochralski method is transfered by all transport mechanisms such as convection, conduction and radiation and convection is caused by the temperature difference in the molden pool, the rotations of crystal or crucible and the difference of surface tension. This study delvelops the simulation model of Czochralski growth by using the finite difference method with fixed grids combined with new latent heat treatment model. The radiative heat transfer occured in the surfce of the system is treated by calculating the view factors among surface elements. The model shows that the flow is turbulent, therefore, turbulent modeling must be used to simulate the transport phenomena in the real system applied to 8" Si single crystal growth process. The effects of a cusp magnetic field imposed on the Czochralski silicon melt are studied by numerical analysis. The cusp magnetic field reduces the natural and forced convection due to the rotation of crystal and crucible very effectively. It is shown that the oxygen concentration distribution on the melt/crystal interface is sensitively controlled by the change of the magnetic field intensity. This provides an interesting way to tune the desired O concentration in the crystal during the crystal growing.

• Nuclear Engineering and Technology
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• v.41 no.8
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• pp.1073-1078
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• 2009

A kinetic model for the oxidation of a $UO_2$ pellet to $U_3O_8$ powder has been suggested by considering the mass transfer and the diffusion of oxygen molecules. The kinetic parameters were estimated by a fitting of the experimental data. The activation energies for the chemical reaction and the product layer diffusion were calculated from the kinetic model. The oxidation conversion of a $UO_2$ pellet was simulated at various operating conditions. The suggested model explains the oxidation behavior of $UO_2$ well.

• Journal of the Mineralogical Society of Korea
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• v.20 no.4
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• pp.313-325
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• 2007

In order to have better insights into adsorption of organic molecules on kaolinite surfaces, we performed quantum chemical calculations of interaction between three different model clusters of kaolinite siloxane surfaces and benzyl alcohol, with emphasis on the effect of size and lattice topology of the cluster on the variation of electron density and magnetic shielding tensor. Model cluster 1 is an ideal silicate tetrahedral surface that consists of 7 hexagonal rings, and model cluster 2 is composed of 7 ditrigonal siloxane rings with crystallographically distinct basal oxygen atoms in the cluster, and finally model cluster 3 has both tetrahedral and octahedral layers. The Mulliken charge analysis shows that siloxane surface of model cluster 3 undergoes the largest electron density transfer after the benzyl alcohol adsorption and that of model cluster 1 is apparently larger than that of model cluster 2. The difference of Mulliken charges of basal oxygen atoms before and after the adsorption is positively correlated with hydrogen bond strength. NMR chemical shielding tensor calculation of clusters without benryl alcohol shows that three different basal oxygen atoms (O3, O4, and O5) in model cluster 2 have the isotropic magnetic shielding tensor as $228.2{\pm}3.9,\;228.9{\pm}3.4,\;and\;222.3{\pm}3.0ppm$, respectively. After the adsorption, the difference of isotropic chemical shift varies from 1 to 5.5 ppm fer model cluster 1 and 2 while model cluster 2 apparently shows larger changes in isotropic chemical shift. The chemical shift of oxygen atoms is also positively correlated with electron density transfer. The current results show that the adsorption of benzyl alcohol on the kaolinite siloxane surfaces can largely be dominated by a weak hydrogen bonding and electrostatic force (charge-charge interaction) and demonstrate the importance of the cluster site and the lattice topology of surfaces on the adsorption behavior of the organic molecules on clay surfaces.

• Journal of Hydrogen and New Energy
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• v.21 no.5
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• pp.460-469
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• 2010

To develop coal gasfication system, many studies have been actively conducted to describe the simulation of steady state. Now, it is necessary to study the gasification system not only in steady state but also in dynamic state to elucidate abnormal condition such as start-up, shut-down, disturbance, and develop control logic. In this study, a model was proposed with process simulation in dynamic state being conducted using a chemical process simulation tool, where a heat and mass transfer model in the gasifier is incorporated, The proposed model was verified by comparison of the results of the simulation with those available from NETL (National Energy Technology Laboratory) report under steady state condition. The simulation results were that the coal gas efficiency was 80.7%, gas thermal efficiency was 95.4%, which indicated the error was under 1 %. Also, the compositions of syngas were similar to those of the NETL report. Controlled variables of the proposed model was verified by increasing oxygen flow rate to gasifier in order to validate the dynamic state of the system. As a result, trends of major process variables were resonable when oxygen flow rate increased by 5% from the steady state value. Coal flow rate to gasifier and quench gas flow rate were increased, and flow rate of liquid slag was also increased. The proposed model in this study is able to be used for the prediction of gasification of various coals and dynamic analysis of coal gasification.