• Title/Summary/Keyword: Oxygen content

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Effect Oxygen in Inflation Gas for Warm Ischemia-reperfusion Injury in the Lung of a Mongrel Dog (황견에서 폐장의 산소가 온열 허혈후 재관류 시폐손상에 미치는 영향)

  • 성숙환;김현조;김영태
    • Journal of Chest Surgery
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    • v.33 no.2
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    • pp.125-131
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    • 2000
  • Background: Hyperinflation during lung ischemia has been known to improve pulmonary functions after reperfusion which may be exerted through a pulmonary vasodilation and avoidance of atelectasis by an increased surfactant release and been known whether the improvement of pulmonary function was the effect of hyperinflation itself or the oxygen content in inflation gas. Therefore we attempted to clarify the effect of hyperinflation with oxygen in pulmonary inflation gas during warm ischemia on pulmonary function after reperfusion to solve the problem of ischemia-reperfusion injury after lung transplantation. Material and Method: sixteen mongrel dogs were randomly divided into two groups: the left lung was inflated to 30-35 cm H2O with 100% oxygen in oxygen group and 100% nitrogen in nitrogen group. The inflated left lung was maintained with warm ischemia for 100 minutes. Arterial and mixed venous blood gas analysis and hemodynamics were measured before ischemia and 30, 60, 120, 180 and 240 minutes afer reperfusion. Lung biopsy was taken for the measurement of lung water content after the end of reperfusion. Result: In oxygen group arterial oxygen tension the difference of arterial and mixed venous oxygen tension and the difference of alveolar-arterial oxygen tension at 30-minute after reperfusion were not significantly different from those before ischemia and were stable during the 40hour reperfusion. However in nitrogen group these values were significantly deteriorated at 30-minute after reperfusion. there was no significant difference between two groups in hemodynamic data peak airway pressure and lung water content. Conclusion : The results indicated that the oxygenation one of the most important pulmonary functions was improved by pulmonary inflation with 100% oxygen during warm ischemia but the hemodynamics were not. Oxygen as a metabolic substrate during warm ischenia was believed to make the pulmonary tissues to maintain aerobic metabolism and to prevent ischemic damage of alveoli and pulmonary capillary.

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Cesium Ions Adsorption of Activated Carbon Treated by Oxygen Plasma (산소 플라즈마 처리된 활성탄소의 세슘 이온 흡착)

  • Ha, Seongmin;Kwak, Cheol Hwan;Lim, Chaehun;Kim, Seokjin;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.38-43
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    • 2022
  • The effect of introducing oxygen functional groups by oxygen plasma treatment of activated carbon on adsorption properties of cesium ions was investigated. During the oxygen plasma treatment, the frequency, power, and oxygen gas flow rates were fixed at 100 kHz, 80 W, and 60 sccm, respectively, while the reaction time was varied. Under the experimental conditions, the amount of cesium ion adsorption increased as the content of oxygen groups on C-O-C and O=C-O bonds increased when the reaction time with oxygen gas was 10 minutes. However, when the reaction time increased to 15 minutes, the oxygen functional group content decreased resulting in the decrease of the adsorbed cesium ion amount. On the other hand, unlike the oxygen content of the surface-treated activated carbon, the specific surface area and pore properties were hardly affected by the oxygen plasma reaction time. As a result, the oxygen plasma-treated activated carbon improved the cesium ion removal rate by up to 97.3% compared to that of the untreated activated carbon. This is considered to be due to the content of oxygen groups on C-O-C and O=C-O bonds introduced on the surface of the activated carbon through oxygen plasma treatment.

Membranes of Polyurethanes Containing Crystalline Soft Segments: Oxygen Permeability and Morphology

  • O, Hyo Jin;Kim, Wan Yeong;Jeong, Yong Seop;Lee, Yun Sik
    • Bulletin of the Korean Chemical Society
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    • v.22 no.2
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    • pp.194-198
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    • 2001
  • In order to look for polymeric materials applicable to the oxygen electrode membranes of biosensors, polyurethanes (PUs) were synthesized from poly(butylene succinate) diol (Mn 1150), poly(ethylene glycol) (Mn 200), and 4,4'-methylenebis(cyclohexyl isocyanate). The PUs (Mn 15000-100000) underwent the crystallization and melting transitions in the temperature range of 20-30 $^{\circ}C$ and 90-110 $^{\circ}C$, respectively. The oxygen permeability for the PU membranes prepared by the solution casting method could not be measured since oxygen simply leaked through the membranes with an audible noise. However, when the PUs were blended with carboxylated poly(vinyl chloride) (CPVC), the permeability could be measured. The oxygen permeability coefficient (Po2) of the PU/CPVC $(96}4)$ membranes (6.4 Barrer) was high enough for the application as the electrode membranes. The Po2 decreased dramatically when the CPVC content increased from 4 to 5 wt%, but decreased very slowly and approached to that of CPVC (~0.26 Barrer) when the CPVC content increased further. The scanning electron micrographs of the membranes revealed that the PU membranes were composed of large crystal grains with many pores, but the size of the PU crystal grains and pores decreased progressively with increasing the CPVC content.

Effect of Oxygen Injection on Microstructure and Mechanical Properties of Ni-based Superalloy Recycled by AOD Process (AOD공정으로 재활용된 니켈합금의 산소주입량에 따른 조직과 기계적 성질 변화)

  • Lee, Duk-Hee;Woo, Kee-Do;Kang, Whang-Jin;Yoon, Jin-Ho
    • Resources Recycling
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    • v.25 no.2
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    • pp.10-16
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    • 2016
  • In this study, the Ni base superalloy was recycled by Argon oxygen decarburization(AOD) process using an inconel 713C scrap. During AOD process, argon gas was continuously injected 1,000 sccm and oxygen gas was injected into 10, 20 and 30 minutes of 100, 250 and 500 sccm.. In early stage of oxygen injection, the oxygen dose increased with increasing Al, Cr, and Mo content and decreasing C content. And Al content was decreased by carburization with added elements in late stage Because of oxidation was occurred with Al, Cr etc. after the reaction of carbon has been finished. From the results, the ratio of ${\gamma}^{\prime}$ phase reduced due to decreasing of Al content for that reason Al is the main element to form the ${\gamma}^{\prime}$ phase. Also carbide reduced owing to decreasing of C content so the mechanical properties of the specimens excessively injected by excess $O_2$ gas were decreased.

Effect of Oxygen Content on Shape Memory Characteristics of Ti-18Nb-6Zr-XO (X = 0~1.5at%) Alloys (생체용 Ti-18Nb-6Zr-XO (X = 0~1.5at%) 합금의 형상기억특성에 미치는 산소 농도의 영향)

  • Park, Young-Chul;Ock, Ji-Myeon;Oh, Jeong-Hwa;Park, Su-Ho;Lee, Jun-Hee;Kim, Jae-Il
    • Korean Journal of Materials Research
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    • v.21 no.11
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    • pp.617-622
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    • 2011
  • The effect of oxygen on the shape memory characteristics in Ti-18Nb-6Zr-XO (X = 0-1.5 at%) biomedical alloys was investigated by tensile tests. The alloys were fabricated by an arc melting method at Ar atmosphere. The ingots were cold-rolled to 0.45 mm with a reduction up to 95% in thickness. After severe cold-rolling, the plate was solution-treated at 1173 K for 1.8 ks. The fracture stress of the solution-treated specimens increased from 450 Mpa to 880 MPa with an increasing oxygen content up to 1.5%. The fracture stress increased by 287MPa with 1 at% increase of oxygen content. The critical stress for slip increased from 430 MPa to 695 MPa with an increasing oxygen content up to 1.5 at%. The maximum recovery strain of 4.1% was obtained in the Ti-18Nb-6Zr-0.5O (at%) alloy. The martensitic transformation temperature decreased by 140 K with a 1.0 at% increase in O content, which is lower than that of Ti-22Nb-(0-2.0)O (at%) by 20 K. This may have been caused by the effect of the addition of Zr. This study confirmed that addition of oxygen to the Ti-Nb-Zr alloy increases the critical stress for slip due to solid solution hardening without being detrimental to the maximum recovery strain.

Strain Ageing Behavior of Cold Worked Zircaloy-4 with Varying Oxygen Content

  • Rheem, K.S.;Park, W.K.
    • Nuclear Engineering and Technology
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    • v.8 no.3
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    • pp.151-157
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    • 1976
  • The strain ageing behavior of cold-worked Zircaloy-4 in vacuum was studied as a function of deformation temperature and oxygen content from 1143 ppm to 3500 ppm 0. Strain ageing occured in the temperature range between 200 and 45$0^{\circ}C$ for the 0 to 10% cold-worked Zircaloy-4, decreasing with increasing amount of cold work. This suppression of strain ageing by cold work is considered to be due to the trapping of oxygen atoms by cold work-produced defects. It has been found that the maximum strain ageing stress in cold-worked Zircaloy-4 is proportional to the square root of oxygen content.

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Germinability of Film-Coated Snap Bean Seed as Affected by Oxygen Diffusion Rate under Different Soil Moisture Contents

  • Kim, Seok-Hyeon;Alan G. Taylor
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.49 no.1
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    • pp.46-51
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    • 2004
  • The film coated snap bean (Phaseolus vulgaris) seeds with five different coating materials treated with 3% increase in seed weight were planted at sandy loam soil controlled moisture content of 18, 19, 20 and 21 %. The oxygen diffusion rate (ODR) was calculated from the different moisture content soil. The number of normal seedlings, seedling vigor, and seedling capability in field (seed vigor x dry matter weight) were observed at 9 days after planting and compared to the changes of ODR. The germination rate and ODR were sharply decreased simultaneously in the seeds planted at 21 % soil moisture content. Seedling emergence did not occur at all as the soil moisture content increased above 22 %. Hence this value should be considered as the threshold of soil moisture content for seedling emergence. An ODR value under 20% did not influence the percent emergence significantly. The certain difference observing in the emergence at the same ODR was not related clearly to the condition of soil. So it can be assumed that the limit of soil moisture content for the emergence of snap bean was approximately 20%. The value of 18% soil moisture content may be considered as the optimum for snap bean emergence. There was close relationship between the mean value of ODR in different soil moisture contents and the emergence. The germination rates of the seeds coated with the different materials were quite different when the seeds were planted at 21 % soil moisture. Dry weight of the seedlings from film coated seeds was decreased slightly, but the germination rates were not much different from the non-treated control under relatively higher soil moisture content (21 %). Major factor lowering emergence rate was oxygen stress while film coating act as a minor constraint for snap bean sown in excess soil moisture condition.

Development of New Soft Contact Lens Materials Using Ester-Monomers of Itaconic Acid from Aspergillus itaconicus (Aspergillus itaconicus 유래 itaconic acid의 ester-monomer를 이용한 새로운 soft contact lens 소재 개발)

  • You, Young-Hyun;Nam, Joo-Hyeung;Kim, Bieong-Kil;Kim, Soon-Bok;Moon, Ik-Jae;Kim, Jong-Pil;Seu, Young-Bae
    • Journal of Life Science
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    • v.19 no.4
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    • pp.538-542
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    • 2009
  • In this study, we confirmed water content and oxygen permeability of new polymeric materials synthesized from itaconic acid used for soft contact lenses. In this study, we polymerized materials for soft contact lenses using HEMA (2-hydroxyethyl methacrylate), the based-monomer of soft contact lenses, EGDMA (ethylene glycol dimethacrylate) as a cross linkage agent, and the new additives mono-ester or di-ester derived from itaconic acid commercially produced by the fermentation of A. itaconicus. New polymer materials for contact lenses were synthesized with the mixture of HEMA and mono- or di-ester at different ratios and water content and oxygen permeability (Dk) was analyzed. In polymerizing HEMA and mono-ester (15%), the water content and oxygen permeability of contact lenses were found to be of good value at 57.7% and 28.6 Dk respectively. The mixture of HEMA and mono-ester is more excellent than HEMA/di-ester in regards to water content and oxygen permeability. The water content and oxygen permeability of soft contact lenses made by new polymeric materials were highly represented.

Effect of Oxygen on the Microstructure and Mechanical Properties of Cr-O-N Coatings (Oxygen 함량에 따른 Cr-O-N 코팅막의 미세구조 및 기계적 특성에 관한 연구)

  • Yun, Jun-Seo;Kwon, Se-Hun;Park, In-Wook;Lee, Jeong-Du;Kim, Kwang-Ho
    • Journal of the Korean institute of surface engineering
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    • v.42 no.5
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    • pp.220-226
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    • 2009
  • Cr-O-N coatings having different oxygen contents were deposited on Si wafer and SUS 304 substrates by an arc ion plating technique using Cr target in $Ar/O_2/N_2$ gaseous atmosphere. As increasing oxygen content in the coating, the microstructure of Cr-O-N coating changed from polycrystalline having NaCl structure to amorphous structure. Further increase of oxygen content resulted in phase transformation from amorphous to rhombohedral structure. From the variations of d value and average grain size, it was revealed that the maximum solubility of oxygen in Cr-O-N coating was about 21 at.%. And the maximum micro-hardness of 2751HK was obtained in this composition. The lowest friction coefficient was measured in the coating having 34.8 at.% of oxygen. However, more narrow width of wear track was found in the coating having 30.1 at.% of oxygen.

Effect of argon flow on the quality of Czochralski silicon crystal (쵸크랄스키 실리콘 단결정의 특성에 미치는 아르곤 유동의 영향)

  • 김정민;이홍우;최준영;유학도
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.2
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    • pp.91-95
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    • 2000
  • The effects of argon gas flow on the axial temperature gradient near the interface, the oxygen concentration, and the radial oxygen uniformity was investigated for 8-inch CZ silicon growth. As argon flow rate was increased, the temperature gradient was increased in the crystal near the crystavmelt interface and the oxygen content in the crystal was decreased. But the radial oxygen uniformity was deteriorated. It was found that argon flow is one of the important growing parameters to affect the quality of crystals such as oxygen content and uniformity.

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