• 센서학회지
• /
• 제15권2호
• /
• pp.97-101
• /
• 2006

Silver electrode having a high Electrocatalytic activity is oxygen-permeable electrode, in which oxygen ad-atoms are adsorbed and moved toward YSZ electrolyte by bulk diffusion. It is the different point in comparison to usual porous electrodes, especially platinum, which react with oxygen only in TPBs(Three Phase Boundaries). Also ad-atoms at TPBs of Pt are diffused to YSZ electrolyte by interfacial diffusion mechanism. These properties were used for turning down the operating temperature of YSZ from over $600^{\circ}C$ to below $450^{\circ}C$. The different heat-treatment temperature between a working electrode and a reference electrode suppresses the formation of silver oxides and reduces a volatility of Ag as well. Above all, these own characteristics and special processes of Ag improved a long-term stability of a oxygen sensor.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 1993년도 추계 학술발표 강연 및 논문 개요집
• /
• pp.69-71
• /
• 1993

Fluoride compound potentiometric cell oxygen sensors were fabricated for the measurement of oxygen pressure in the low temperature range (300。K-500。K). The disk type sensors consist of a reference Air(0$_2$):Ag, a solid electrolyte SrF$_2$, and a sensing metel Ag electrode. And the buried reference electrode type sensor have a NiO/Ni reference electrode. The open circuit emf of the cell showed high sensivity to oxygen gas (60mv) at the measuring temperature 20$0^{\circ}C$. Also, The buried reference electrode type sensor showed 30mv from 1% to 10% oxygen pressure range.

• 한국해양학회지:바다
• /
• 제28권1호
• /
• pp.41-50
• /
• 2023

용존산소 센서는 그 특성상 시간이 지남에 따라 자료의 변형(drift)이 일어난다. 따라서 용존산소 센서를 이용하여 해수 중의 정확한 용존산소 농도를 측정하기 위해서는 반드시 용존산소 센서의 현장 교정이 필요하다. 현장 교정 방법과 교정을 위한 적절한 시료의 개수 및 용존산소 센서의 실험실 교정주기를 제시하고자 약 1년에 걸쳐 인도양, 태평양, 동해에서 수행된 세 번의 서로 다른 항차에서 총 133개의 용존산소 분석을 위한 시료를 획득하였다. 화학 분석을 통해 얻은 용존산소 분석값과 센서값을 비교 분석하였다. 그 결과 제조사에서 제시하는 센서의 출력전압과 용존산소 분석값을 비교하기보다는 센서에서 주는 최종 농도값과 분석값을 직접 비교하여 얻은 직선의 관계식을 이용하여 센서의 측정값을 교정하는 것이 바람직하고, 박막형 용존산소 센서의 경우 정확한 보정을 위해서는 최소한 30개 이상의 시료에 대한 분석값을 이용해야 약 1% 이내의 정확도 범위 내에서 현장 교정이 가능하다. 또한 CTD용 박막형 용존산소 센서가 70% 이상의 성능을 내기 위해서는 1년 이내의 주기로 실험실 또는 제조사에서 이루어지는 실험실 교정을 수행할 것을 권장한다.

• Journal of Electrochemical Science and Technology
• /
• 제14권3호
• /
• pp.215-221
• /
• 2023

A rapid and environment-friendly electrochemical sensor to determine the chemical oxygen demand (COD) has been developed. The boron-doped diamond (BDD) thin-film electrode is employed as the anode, which fully oxidizes organic pollutants and provides a current response in proportion to the COD values of the sample solution. The BDD-based amperometric COD sensor is optimized in terms of the applied potential and the solution pH. At the optimized conditions, the COD sensor exhibits a linear range of 0 to 80 mg/L and the detection limit of 1.1 mg/L. Using a set of model organic compounds, the electrochemical COD sensor is compared with the conventional dichromate COD method. The result shows an excellent correlation between the two methods.

• KSBB Journal
• /
• 제19권1호
• /
• pp.62-66
• /
• 2004

의료용 갈바닉형 산소센서를 이용하여 BOPP, OPP 및 CPP 막의 두께와 온도 변화에 따른 산소 투과 특성을 연구한 결과, 전류와 산소농도의 탁월한 선형관계 (R＞0.999)로부터 구한 산소 투과도는 BOPP ＞ OPP ＞ CPP의 순으로 막의 두께에 의존하는 것으로 나타났다. 본 전기화학적 산소투과도 측정방법은 기존의 압력법에 비하여 간편한 실험방법임을 확인하였다 한편, 산소 투과도에 대한 활성화에너지는 13.1 kJ/mol에서 28.5 kJ/mol 사이의 값으로, 각 막에 따라 다른 값을 나타냈지만 같은 종류의 막에서 두께에 의존하지는 않았다. 이는 고분자의 활성화 에너지는 고분자가 갖고 있는 고유의 물성에 의존하기 때문인 것으로 추정된다.

• 전기학회논문지
• /
• 제67권12호
• /
• pp.1641-1647
• /
• 2018

In this paper, we describe a portable potentiostat which is capable of cyclic voltammetry(CV) and amperometry for electrochemical dissolved oxygen sensor. In addition, this portable potentiostat can also transmit the measured data wirelessly to android devices such as smart phone, tablet, etc. through Bluetooth. The potentiostat system consists of three parts; a voltage generator circuit which is controlled by Arduino nano and 12-bit DAC(digital to analog converter) to generate necessary electric potential for operating the electrochemical sensor, an oxidation/reduction current measurement circuit, and a Bluetooth module to transmit data wirelessly to an android device. Once measurements are carried out with the android application, the measured data is transmitted to the android device via Bluetooth and displayed using the android app. in real time. In this paper, we report the measured reduction current with a fabricated dissolved oxygen sensor in both saturated-oxygen state and zero-oxygen states. The results of the developed portable potentiostat system are in good agreement with those of the commercial portable potentiostat (${\mu}stat200$, Dropsens inc.). The measured peak reduction currents using the developed potentiostat and the commercial ${\mu}stat200$ potentiostat were $-0.755{\mu}A$ and $-0.724{\mu}A$, respectively. The reduction currents measured at zero-oxygen state were $-0.005{\mu}A$ and $-0.004{\mu}A$. The discrepancy between those two systems seems very small, which implies successful development of a portable and wireless potentionstat.

• 한국분말재료학회지
• /
• 제18권3호
• /
• pp.250-255
• /
• 2011

The potential application of ultrafine cerium oxide (ceria, $CeO_2$) as an oxygen gas sensor has been investigated. Ceria was synthesized by a thermochemical process: first, a precursor powder was prepared by spray drying cerium-nitrate solution. Heat treatment in air was then performed to evaporate the volatile components in the precursor, thereby forming nanostructured $CeO_2$ having a size of approximately 20 nm and specific surface area of 100 $m^2/g$. After sintering with loosely compacted samples, hydrogen-reduction heat treatment was performed at 773K to increase the degree of non-stoichiometry, x, in $CeO_{2-x}$. In this manner, the electrical conductivity and oxygen-response ability could be enhanced by increasing the number of oxygen vacancies. After the hydrogen reduction at 773K, $CeO_{1.5}$ was obtained with nearly the same initial crystalline size and surface. The response time $t_{90}$ measured at room temperature was extremely short at 4 s as compared to 14 s for normally sintered $CeO_2$. We believe that this hydrogen-reduced ceria can perform capably as a high-performance oxygen sensor with good response abilities even at room temperature.

• 분석과학
• /
• 제20권1호
• /
• pp.1-9
• /
• 2007

용존산소(dissolved oxygen; DO) 전극에 미생물 막과 보호막을 장착하여 BOD(biochemical oxygen demand) 센서를 제작하였다. 토양과 물 그리고 활성슬러지에서 분리한 다양한 미생물들을 BOD 센서에 적용하여 그 감응특성을 조사하여 빠른 산소 호흡력과 회복력을 나타내는 미생물로 Bacillus 종인 HN24와 HN93을 선별하였다. 최종적으로 최적화한 BOD 센서는 Bacillus subtilis, Bacillus sp. HN24 그리고 Bacillus sp. HN93을 혼합한 미생물 막과 DO 전극의 기체투과막을 silicon rubber(SR) 막으로 사용한 것이며, 측정조건으로 완충용액에 50% 산소(질소와의 비율)를 주입하여 감응특성을 향상시켰다. 본 실험에서 제작된 BOD 센서는 100 mg/L BOD 농도 이상까지 우수한 직선감응성($r^2=0.9986$)을 나타냈다.

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2007년도 춘계학술대회 논문집
• /
• pp.503-504
• /
• 2007

• 한국생물공학회:학술대회논문집
• /
• 한국생물공학회 2001년도 추계학술발표대회
• /
• pp.819-822
• /
• 2001

In this study a fiber optic biosensor has been developed to on-line monitor the concentrations of oxygen and glucose. The oxygen concentrations in solution and gas phase monitored by the fiber optic sensor has been compared with those by a dissolved oxygen electrode and an IR-type $O_2$ analyzer. The fiber optic glucose sensor has been made by immobilizing glucose oxidase on the tip of the optic fiber and used to on-line monitor the concentration of glucose in a fermentation process.