• Journal of the Korean Society of Combustion
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• v.15 no.2
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• pp.1-11
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• 2010

Power generation systems based on the oxy-coal combustion with carbon dioxide capture and storage (CCS) capability are being proposed and discussed lately. Although a large number of lab scale studies for oxy-coal power plant have been made, studies of pilot scale or commercial scale power plant are not enough. Only a few demonstration projects for oxy-coal power plant are publicized recently. The proposed systems are evolving and various alternatives are to be comparatively evaluated. This paper presents a proposed approach for performance evaluation of a commercial 100 MWe class power plant, which is currently being considered for 'retrofitting' for the demonstration of the concept. The system is configurated based on design and operating conditions with proper assumptions. System components to be included in the discussion are listed. Evaluation criteria in terms of performance are summarized based on the system heat and mass balance and simple performance parameters, such as the fuel to power efficiency and brief introduction of the second law analysis. Also, gas composition is identified for additional analysis to impurities in the system including the purity of oxygen and unwanted gaseous components of nitrogen, argon and oxygen in air separation unit and $CO_2$ processing unit.

• Journal of the Korean Society of Combustion
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• v.16 no.2
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• pp.1-8
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• 2011

As one of the main technologies for carbon capture and storage in power generation, oxy-coal combustion is being developed for field demonstration in Korea. This study presents the results of numerical simulation for combustion in a single-wall-fired 100 $MW_e$-scale boiler proposed for the initial design of the demonstration plant. Using a commercial CFD code, the detailed combustion, flow and heat transfer characteristics were assessed both for air-mode and oxy-mode combustion. The results show that stable combustion can be achieved in the dual mode operation with the current boiler configuration. However, the differences in the flow pattern and heat transfer between the two combustion modes need to be considered in the design and operation which is mainly due to the larger density and specific heat of $CO_2$ compared to $N_2$. Further development of the boiler design is required using improved numerical modeling for radiative heat transfer and combustion.

• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.51-54
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• 2008

This study aims to devise and analyze a power generation system combining the solid oxide fuel cell and oxy-fuel combustion technology. The fuel cell operates at an elevated pressure, a constituting a SOFC/gas turbine hybrid system. Oxygen is extracted from the high pressure cathode exit gas using ion transport membrane technology and supplied to the oxy-fuel power system. The entire system generates much more power than the fuel cell only system due to increased fuel cell voltage and power addition from oxy-fuel system. More than one third of the power comes out of the oxy-fuel system. The system efficiency is also higher than that of the fuel cell only system. Recovering most of the generated carbon dioxide is major advantage of the system.

• 한국연소학회:학술대회논문집
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• 2006.04a
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• pp.63-68
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• 2006

Effects of oxidizer inlet velocity on NO emission characteristics of 0.2MW oxy-fuel combustor have been experimentally investigated. The NO formation process in the oxy-fuel combustion is extremely sensitive even for the small fraction of nitrogen in oxidizer. By increasing the oxidizer velocity, flame length is reduced due to the enhanced turbulent mixing. The increased oxidizer velocity also results in the decreased flame temperature through the elevated entrainment rate of the recirculated product and the corresponding NO emission is drastically decreased. Experimental results clearly indicate that the entrained product gases play a crucial role to decrease the temperature at the flame zone and the post flame zone where the thermal NO is mainly formed.

• Journal of the Korean Society of Combustion
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• v.21 no.4
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• pp.39-47
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• 2016

The aims of this research were to investigate combustion characteristics of lab-scale pressurized oxy-fuel combustion(POFC) system. In this study, the reactor, 800 mm long, was equipped with co-axial burner. Low calorific value syngas that is composed of mainly CO and $H_2$ was used as fuel whereas pure oxygen was used as an oxidant. Thermal heat input to the reactor varied from 2.6 kW to 6.1 kW. The reactor pressure also increases from atmospheric up to 15 bar. The results show that as the pressure increase, the temperature of reactor decreases on the whole in all cases. A significant temperature drop was observed especially at the bottom section of the reactor that exist flame. In addition, the flame instability increases as the pressure increases. Furthermore $NO_x$ emissions increases from atmospheric up to 2 bar. However beyond 2 bar, $NO_x$ emission reduces as pressure increases. Lastly $NO_2$ ratio in $NO_x$ also increases as pressure increases.

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.1019-1024
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• 2008

A 3 MW class oxy-fuel boiler has been developed to capture $CO_2$ from the exhaust gas. The system is a scale-up of the previous 0.5 MW class system in general. A heat exchanger and a mixer are additionally installed to stabilize the flame for the FGR mode. The system yields the exhaust gas with $CO_2$ concentration over 90% and reduced NO emission to 1/10 of conventional air combustion system.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.28 no.7
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• pp.275-282
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• 2016

MILD (Moderate and Intense Low-oxygen Dilution) combustion using oxygen as an oxidizer is considered as one of the most promising combustion technologies for high energy efficiency and for reducing nitrogen oxide and carbon dioxide emissions. In order to investigate the effects of nozzle angle and oxygen velocity conditions on the formation of oxygen-MILD combustion, numerical and experimental approaches were performed in this study. The numerical results showed that the recirculation ratio ($K_V$), which is an important parameter for performing MILD combustion, was increased in the main reaction zone when the nozzle angle was changed from 0 degrees to 15 degrees. Also, it was observed that a low and uniform temperature distribution was achieved at an oxygen velocity of 400 m/s. The perfectly invisible oxy-MILD flame was observed experimentally under the condition of a nozzle angle of $10^{\circ}$ and an oxygen velocity of 400 m/s. Moreover, the NOx emission limit was satisfied with NOx regulation of less than 80 ppm.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.857-864
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• 2011

Oxy-fuel combustion with many advantages such as high combustion efficiency, low flue gas flow rate and low NOx emission has emerged as a promising CCS technology for coal combustion facilities. In this study, the effects of the direct sulfation reaction on $SO_2$ removal efficiency were evaluated in a drop tube furnace under typical oxy-fuel combustion conditions represented by high concentrations of $CO_2$ and $SO_2$ formed by gas recirculation to control furnace combustion temperature. The effects of the operating parameters including the reaction temperature, $CO_2$ concentration, $SO_2$ concentration, Ca/S ratio and humidity on $SO_2$ removal efficiency were investigated experimentally. $SO_2$ removal efficiency increased with reaction temperature up to 1,200 due to promoted calcination of limestone reagent particles. And $SO_2$ removal efficiency increased with $SO_2$ concentrations and the humidity of the bulk gas. The increase of $SO_2$ removal efficiency with $CO_2$ concentrations showed that $SO_2$ removal by limestone was mainly done by the direct sulfation reaction under oxy-fuel combustion conditions. From the impact assessment of operation parameters, it was shown that these parameters have an effects on the desulfurization reaction by the order of the Ca/S ratio > residence time > $O_2$ concentration > reaction temperature > $SO_2$ concentration > $CO_2$ concentration > water vapor. The semi-empirical model equation for to evaluate the effect of the operating parameters on the performance of in-furnace desulfurization for oxy-fuel combustion was established.

• Journal of the Korean Society of Combustion
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• v.16 no.3
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• pp.12-20
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• 2011

Oxy-coal combustion for $CO_2$ capture in coal power plants entails a mode switching from air-firing to oxyfiring. In this study, procedure of the mode switching was investigated and discussed through experiments in pilot scale facilities: (1) a 0.3 $MW_{th}$ furnace with a vertical single burner and a FGR(Flue Gas Recirculation) system (2) a 1 $MW_{th}$ furnace with horizontal 4 burners and a FGR system. Principle of the mode switching was established and performed with control of FD fan, FGR fan, ID fan and oxygen flow rates. We have found that equivalence ratio in the oxy-firing mode should be increased more than that in the air-firing to achieve stable mode switching. Control of FD, ID and FGR fans should be performed carefully in the mode switching, in the sense of complete combustion and flame attachment. Moisture contents in the ash and the flue gas recycled to the primary oxidizer stream should be removed to prevent condensation, corrosion and duct clogging.

• 한국연소학회:학술대회논문집
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• 2006.04a
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• pp.69-74
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• 2006

An Experimental study was conducted on $CO_2$ recycle combustion heating system using pure oxygen instead of conventional air as an oxidant, which is thereby producing a flue gas of mostly $CO_2$ and water vapor($H_2O$) and resulting in higher $CO_2$ concentration. The advantages of the system are not only the ability to control high temperatures characteristic of oxygen combustion with recycling $CO_2$. but also the possibility to reduce NOx emission in the flue gas. A small scale industrial reheating furnace simulator and specially designed variable flame burner were used to characterize the $CO_2$ recycle oxy-fuel combustion, such as the variations of furnace pressure, temperature and composition in the flue gas during recycle. It was found that $CO_2$ concentration in the flue gas was about 80% without $CO_2$ recycle, but increased to $90{\sim}95%$ with $CO_2$ recycle. The furnace temperature and pressure was decreased due to recycle and the NOx emission was also reduced to maintain under 100ppm.