• Title/Summary/Keyword: Oxidized powder

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An Experimental Evaluation of Mechanical Behavior in Ultra-High Strength Concrete Utilizing Graphene and Hollow Glass Powder (그래핀과 유공유리분말을 사용한 초고강도 콘크리트의 역학적 성능에 관한 실험적 연구)

  • Seo, Tae-Seok;Byon, Chan;Kim, Kang-Min;Lee, Hyun-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.4
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    • pp.381-392
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    • 2023
  • This research scrutinizes the mechanical characteristics of ultra-high strength concrete using oxide graphene nanoplatelet(GO) and hollow glass powder(HGP). The investigation covered various mechanical attributes, including workability, compression strength, tensile strength, water resistance, and the internal microstructure of standard concrete. Our findings reveal that workability experiences a significant improvement with the incorporation of a minimal amount of HGP, and an increase was also observed in tensile strength and water resistance. It was confirmed that cGO(C company GO) and HGP demonstrated commendable dispersion and the pore volume exhibited a reduction of more than 20%. The potential of cGO and HGP to substitute silica fume(SF) was also explored. Consequently, it was found that both workability and mechanical properties were enhanced in the absence of SF when cGO and HGP were used. This finding implies that the utilization of these novel materials could potentially modify conventional methods of concrete manufacturing.

High-temperature Oxidation of Turbocharger Steels Manufactured by Powder Metallurgy and Casting (분말야금법과 주조법으로 제조한 자동차 터보차져강의 고온산화)

  • Park, Soon Yong;Lee, Dong Bok
    • Corrosion Science and Technology
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    • v.14 no.3
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    • pp.132-139
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    • 2015
  • Turbocharger steels were manufactured by the powder metallurgical and casting method. They consisted primarily of a large amount of ${\gamma}$-Fe, a small amount of ${\alpha}$-Fe, and fine $Nb_6C_5$ precipitates. The casting method was better than the powder metallurgical method, because a sound matrix with little oxides were obtained. When turbocharger steels were oxidized at $900^{\circ}C$ for 50 h, $Mn_2VO_4$ and (Mn,Si)-oxides were formed along grain boundaries, while $Mn_2O_3$ and $CrMn_2O_4$ were formed intragranularly. Fe, Nb, and Ni were depleted in the oxide scale.

Synthesis and Compaction of Al-based Nanopowders by Pulsed Discharge Method

  • Rhee, Chang-Kyu;Lee, Geun-Hee;Kim, Whung-Whoe
    • Journal of Powder Materials
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    • v.9 no.6
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    • pp.433-440
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    • 2002
  • Synthesis and compaction of Al-base nano powders by pulsed discharge method were investigated. The aluminum based powders with 50 to 200 nm of diameter were produced by pulsed wire evaporation method. The powders were covered with very thin oxide layer. The perspective process for the compaction and sintering of nanostructured metal-based materials stable in a wide temperature range can be seen in the densification of nano-sized metal powders with uniformly distributed hard ceramic particles. The promising approach lies in utilization of natural uniform mixtures of metal and ceramic phases, e.g. partially oxidized metal powders as fabricated in our synthesis method. Their particles consist of metal grains coated with oxide films. To construct a metal-matrix material from such powder, it is necessary to destroy the hard oxide coatings of particles during the compaction process. This goal was realized in our experiments with intensive magnetic pulsed compaction of aluminum nanopowders passivated in air.

Characteristics of Cladding Process with High Viscosity Mixing Powder Using $CO_2$ Laser ($CO_2$ 레이저를 이용한 고점성 혼합분말의 클래딩 가공 특성)

  • 이영곤;전병철;오동수;서병권;김재도
    • Proceedings of the KWS Conference
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    • 2000.10a
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    • pp.256-259
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    • 2000
  • High viscosity mixing powder is a very useful material for laser cladding. This material has a high viscosity so that it can be sticked to substrate. Therefore, Laser cladding can be performed on a curved or slope surface. Laser cladding can be easily performed with the material instead of wire that is difficult to be manufactured in some case. In this experiment, it was used a high viscosity mixing powder which consists of a high temperature flux and a bronze powder. And AC2B alloy material was used as a substrate. Flux prevents the clad layer from being oxidized and increases bonding property between substrate and cladding material. It makes possible to laser cladding at low level energy.

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Charge/Discharge Characteristics of Lithium ion Secondary Battery Using Ag-deposited Graphite as Anode Active Material (은 담지한 흑연을 부극 활물질로 이용한 Lithium ion 2차전지의 충방전 특성)

  • 김상필;조정수;박정후;윤문수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.9
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    • pp.727-732
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    • 1998
  • Ag-deposited graphite powder was prepared by a chemical reduction method of metal particles onto graphite powder. X-ray diffraction observation of Ag-deposited graphite powder revealed that silver existed in a metallic state, but not in an oxidized one. From SEM measurement, ultrafine silver particles were highly dispersed on the surface of graphite particles. Cylindrical lithium ion secondary battery was manufactured using Ag-deposited graphite anodes and $LiCoO_2$ cathodes. The cycleability of lithium ion secondary battery using Ag-deposited graphite anodes was superior to that of original graphite powder. The improved cycleability may be due to both the reduction of electric resistance between electrodes and the highly durable Ag-graphite anode.

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Preparation and Characteristics of the Ni-Ferrite Encapsulated Mo-Permalloy Powder

  • Park, Hyun-Kyu;Ji, In-Geol;Oh, Jae-Hee;Ko, Taeg-Yung
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.700-702
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    • 2006
  • We prepared a Ni-ferrite encapsulated Mo-permalloy powder through simple electroless plating and heat treatment. It was observed that Ni-ferrite particles formed in a spherical form on each Mo-permalloy grain. The microstructure and the magnetic characteristics of the encapsulated powders depended strongly on oxidation time in the heat-treatment. When the powder was oxidized for 60 min, a dense Ni-ferrite layer covered the Mo-permalloy grain, which in turn exhibited high saturation magnetization of 85.8 emu/g. The magnetic core prepared additionally with the encapsulated powder exhibited a resonant frequency of 12 kHz.

A Study on a Fabrication of simulated Fuels for a design of a High-Capacity Vol-oxidizer (대용량 사용후핵연료 공기산화로 설계를 위한 모의연료 제조연구)

  • Hwang, J.S.;Won, J.H.;Kim, Y.H.;Jung, J.H.;Yoon, K.H.;Park, B.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.488-490
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    • 2008
  • This study aims to design the high-capacity vol-oxidizer using simulated fuels instead of spent nuclear fuels. Simulated fuels are fabricated by blending tungsten powder with silicon carbide powder, and thereafter, paraffin coating covers simulated fuels to increase their strength. An oxidation experiment using simulated fuels have been carried out in order to analyze oxidation characteristics similar to spent fuels. After oxidation, simulated fuels were almost oxidized to be powders. Increased volume of simulated fuels approached to spent fuels. These results can be utilized as important informations for designing a high-capacity vol-oxidizer.

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Chemical Effects to Cement Concrete by Grease Oxidation (그리이스의 산화가 시멘트 콘크리트에 미치는 화학적 영향)

  • 정근우;조원오;김영운;임수진;이은아;김성욱
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2000.06a
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    • pp.99-105
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    • 2000
  • Greases composed of base oil and thickener are widely used in the purpose of lubrication and anti-corrosion of machinery. However, greases are sometimes oxidized and decomposed by heat of friction, and produced organic acid. And the greases leaked out ordinary spot make the concrete structures weaken. In this study, the chemical effects of the greases with the concrete structures were investigated through oxidation reaction under pressure and oxygen, and evaluated by the analysis of TAN, Ca content, FT-IR and XRD of grease and cement powder after the oxidation reaction. As the results, TAN value decreased with the increase of the content of cement because of neutralization of organic acid produced by the oxidation of grease with calcium contained in the cement. The content of calcium linearly increased with the increase of cement due to calcium salt by neutralization of acid. Also, according to XRD results of the cement powder oxidized at 99 $^{\circ}C$, the diffraction peak due to calcium hydroxide decreased in comparison with that at room temperature because of the reaction of calcium and organic acid.

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Development of New Powdered Additive and Its Application for Improving the Paperboard Bulk and Reducing Drying Energy (II) - Surface Modification of Brewers Grain(BG) and Oil Palm Frond(OPF) Powders with Cationic and Oxidized Starches - (산업용지의 벌크 향상 및 건조에너지 절감을 위한 분말상 첨가제 제조기술 개발(II) - 맥주박과 팜잎 분말상 첨가제의 표면개질에 대한 연구 -)

  • Lee, Ji-Young;Kim, Chul-Hwan;Kim, Sun-Young;Kim, Byeong-Ho;Lim, Gi-Baek;Kim, Jun-Sik
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.2
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    • pp.33-40
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    • 2013
  • Powdered additive or organic filler is used to improve paperboard thickness and to reduce drying energy consumption in the Korean paperboard industry. In a previous study, we identified alternative non-lignocellulosic resources to wood powder, specifically brewers grain and oil palm frond powders, and verified that these materials had the same functionality as wood powder. The main drawback of the use of such additives, including both lignocellulosic and non-lignocellulosic resources, is the deterioration in paperboard strengths. Therefore, we carried out a basic study on the surface modification of brewers grain and oil palm frond powders to improve the strengths of paperboard. Surface modification was performed using various types of cationic and oxidized starches. The streaming current and zeta-potential of the two non-lignocellulosic powders were measured and CLSM images were taken to assess the surface modification.

Study on Leaching Behavior for Recovery of Ga Metal from LED Scraps (LED 공정스크랩으로부터 Ga 회수를 위한 침출 거동 연구)

  • Park, Kyung-Soo;Swain, Basudev;Kang, Lee Seung;Lee, Chan Gi;Uhm, Sunghyun;Hong, Hyun Seon;Shim, Jong-Gil;Park, Jeung-Jin
    • Applied Chemistry for Engineering
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    • v.25 no.4
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    • pp.414-417
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    • 2014
  • LED scraps consisting of highly crystalline GaN and their leaching behavior are comprehensively investigated for hydro-metallurgical recovery of rare metals. Highly stable GaN renders the leaching of the LED scraps extremely difficult in ordinary acidic and basic media. More favorable state can be obtained by way of high temperature solid-gas reaction of GaN-$Na_2CO_3$ powder mixture, ball-milled thoroughly at room temperature and subsequently oxidized under ambient air environment at $1000-1200^{\circ}C$ in a horizontal tube furnace, where GaN was effectively oxidized into gallium oxides. Stoichiometry analysis reveals that GaN is completely transformed into gallium oxides with Ga contents of ~73 wt%. Accordingly, the oxidized powder can be suitably leached to ~96% efficiency in a boiling 4 M HCl solution, experimentally confirming the feasibility of Ga recycling system development.