• Title/Summary/Keyword: Oxidized material

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Hydroxyapatite+TiO2 Composite Sol Coating on Cp-Ti (Cp-Ti 표면의 Hydroxyapatite+TiO2 복합 Sol 코팅에 관한 연구)

  • Kim, Yun-Jong;Kim, Taik-Nam;Lee, Sung-Ho
    • Korean Journal of Materials Research
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    • v.15 no.7
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    • pp.444-447
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    • 2005
  • In this study, $Hydroxyapatite+TiO_2(HAp+TiO_2)$ composite sol coatings on Cp-Ti substrates were deposited by using a sol-gel derived precursor. Prior to hydroxyapatite coating, the samples were micropolished and divided into three sets. The first set was coated with hydroxyapatite (HAp) directly on Cp-Ti. The second set was first coated with intermediate titania layer and then coated with HAp. The third set samples were coated with $HAp+TiO_2$ (50:50) composite sol. Each samples were predried at $200^{\circ}C$, and heat treated at $600^{\circ}C$. The formation of hydroxyapatite has been confirmed by XRD analyses and the substrate material was found to be oxidized with negligible amount of CaO in the coating. The NaOH treated samples showed the presence of rutile crystal. The SEM studies revealed surface morphologies of each samples. $HAp+TiO_2$ composite sol coating layer was found to be smooth. The bonding strength of each samples were calculated using pull out tests. The bonding strength of the $HAp+TiO_2$ composite sol coating on substrate was 29.35MPa.

Odor Removal by Using Compost and Granular Scrap Tires (퇴비 및 폐타이어 Granule을 이용한 악취 제거)

  • Chung, Yoon-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.1
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    • pp.43-50
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    • 1999
  • In spite of low energy requirement, and operation and construction cost, biofilters with soil beds have not been operated efficiently. Because of excess moisture in winter and rainy periods, saturated pores in the bed prevent passage and sorption of odorous compounds. Sometimes this results in septic conditions that release previously sorbed and oxidized sulfur. Therefore, an economical and effective alternative needs to be developed. The objectives of this study were to confirm applicability of the granular scrap tires with compost for treating odorous gas as well as to obtain optimum design parameters for proposed system. In lab-scaled test, multiple stage reactors had lower headloss than a single stage reactor and less headloss was occurred for the gas with higher moisture content. For practical purpose, pilot-scaled reactor was operated to remove odor from septic tank, manure and animal wastewater treatment plant and composting machine. According to the results of pilot scaled test, $H_2S$ can be always removed completely and ammonia/amine can be removed excellently when proper moisture content is provided. The results from lab and pilot test showed that granular scrap tire could be replaced with soil as supporting material for biofilter showed excellent drainage because of its ability to reject moisture.

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A Study on Laser Assisted Machining for Silicon Nitride Ceramics (II) - Surface Characteristics of LAM Machined SSN and HIPSN - (질화규소 세라믹의 레이저 예열선삭에 관한 연구 (II) - 예열선삭된 SSN 및 HIPSN 질화규소 세라믹의 표면특성 -)

  • Kim, Jong-Do;Lee, Su-Jin;Kang, Tae-Young;Suh, Jeong;Lee, Jae-Hoon
    • Journal of Welding and Joining
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    • v.28 no.5
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    • pp.80-85
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    • 2010
  • This study focused on laser assisted machining (LAM) of silicon nitride ceramic that efficiently removes the material through machining of the softened zone by local heating. The effects of laser-assisted machining parameters were studied for cost reduction, and active application in processing of silicon nitride ceramics in this study. Laser assisted machining of silicon nitride allows effective cutting using CBN tool by local heating of the cutting part to the softening temperature of YSiAlON using by the laser beam. When silicon nitride is sufficiently preheated, the surface is oxidized and decomposed and then forms bloating, micro crack and silicate layer, thereby making the cutting process more advantageous. HIPSN and SSN specimens were used to study the machining characteristics. Higher laser power makes severer oxidation and decomposition of both materials. Therefore, HIPSN and SSN specimens were machined more effectively at higher power.

A Study on the Oxidation Resistance of Aluminum Cast Iron by Aluminum Content (알루미늄 함량에 따른 알루미늄 주철의 내산화성에 관한 연구)

  • Kim, Dong-Hyuk
    • Journal of Korea Foundry Society
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    • v.40 no.6
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    • pp.135-145
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    • 2020
  • Aluminum cast iron has excellent oxidation resistance, sulfurization resistance, and corrosion resistance. However, the ductility at room temperature is insufficient, and at temperatures above 600?, the strength drops sharply and practicality is limited. In the case of heat-resistant cast iron, high-temperature materials containing Cr and Ni account for 30 to 50% or more. However, these high-temperature materials are expensive. Aluminum heat-resistant cast iron is considered as a substitute for expensive heat-resistant materials. Oxidation due to the aging temperature and holding time conditions increases more in 0 wt.% Al-cast iron than in 2 and 4 wt.% Al-cast iron according to oxidized weight and gravimetric oxide layer thickness measurements. As a result of observing the cross-section of the oxide layer, it was found to contain 0 wt.% of Al-cast iron silicon oxide-containing SiO2 or Fe2SiO4 oxide film. In cast iron containing aluminum, the thickness of the internal oxide layer due to aluminum increases as the aging temperature and retention time increase, and the amount of the iron oxide layer generated on the surface decreases.

Effect of Na2P2O7 Electrolyte and Al Alloy Composition on Physical and Crystallographical Properties of PEO Coating Layer : II. Crystallographic Analysis of PEO Layer (플라즈마 전해 산화 코팅에 있어서 인산염 전해액과 모재 성분 변화가 Al 산화피막 물성에 미치는 영향 II. PEO 층의 결정상 분석)

  • Kim, Bae-Yeon;Kim, Jeong-Gon;Lee, Deuk-Yong;Kim, Yong-Nam;Jeon, Min-Seok;Kim, Sung-Youp;Kim, Kwang-Youp
    • Journal of the Korean Ceramic Society
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    • v.49 no.3
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    • pp.247-252
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    • 2012
  • Crystal structure and chemical compositions of Plasma electrolytic oxidized layer of A-1100, A-2024, A-5052, A-6061, A-6063, A-7075, ACD-7B and ACD-12 were investigated. The electrolyte for plasma electrolytic oxidation was mixture of distilled water, $Na_2P_2O_7$, Cu, Cr metal salts and KOH. ${\eta}$-Alumina, as well as ${\alpha}$-alumina, was main crystal phase. Another crystals such as $(Al_{0.948}Cr_{0.052})_2O_3$ and $(Al_{0.9}Cr_{0.1})_2O_3$ were also formed in the oxide layer. It was thought that the effect of electrolyte compositions on the physical properties and crystal system of PEO layers was greater than the effect of Al alloy composition variation.

GaN Nanowire Growth on Si Substrate by Utilizing MOCVD Methods (MOCVD 방법에 의한 Si 기판위 GaN 나노선의 성장)

  • Woo, Shi-Gwan;Shin, Dae-Keun;O, Byung-Sung;Lee, Hyung-Gyoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.11
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    • pp.848-853
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    • 2010
  • We have grown GaN nanowires by the low pressure MOCVD method on Ni deposited oxidized Si surface and have established optimum conditions by observing surface microstructure and its photoluminescence. Optimum growth temperature of $880^{\circ}C$, growth time of 30 min, TMG source flow rate of 10 sccm have resulted in dense nanowires on the surface, however further increase of growth time or TMG flow rate has not increased the length of nanowire but has formed nanocrystals. On the contrary, the increase of ammonia flow has increased the length of nanowires and the coverage of nanowire over the surface. The shape of nanowire is needle-like with a Ni droplet at its tip; the length is tens of micron with more than 40 nm in diameter. Low temperature photoluminescence obtained from the sample at optimum growth condition has revealed several peaks related to exciton decay near band-edge, but does not show any characteristic originated from one dimensional quantum confinement. Strong and broad luminescence at 2.2 eV is observed from dense nanowire samples and this suggests that the broad band is related to e-h recombination at the surface state in a nanowire. The current result is implemented to the nanowire device fabrication by nanowire bridging between micro-patterned neighboring Ni catalysis islands.

Transparent Electrode Performance of TiO2/ZnS/Ag/ZnS/TiO2 Multi-Layer for PDP Filter (TiO2/ZnS/Ag/ZnS/TiO2 다층막의 PDP 필터용 전극 특성)

  • Oh, Won-Seok;Lee, Seo-Hee;Jang, Gun-Eik;Park, Seong-Wan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.9
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    • pp.681-684
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    • 2010
  • The $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ multilayered structure for the transparent electrodes in plasma display panel was designed by essential macleod program (EMP) and the multilayered film was deposited on a glass substrate by direct-current (DC)/radio-frequency (RF) magnetron sputtering system. During film deposition process, the Ag layer in $TiO_2$/Ag/$TiO_2$ structure became oxidized and the filter characteristic was degraded easily. In this study, ZnS layer was adopted as a diffusion blocking layer between $TiO_2$ and Ag to prevent the oxidation of Ag layer efficiently in $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ structure. Based on the AES depth profiling analysis, the Ag layer was effectively protected by the ZnS layer as compared with the $TiO_2$/Ag/$TiO_2$ multilayered films without ZnS as an antioxidant layer. The 3 times stacked $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ films have low sheet resistance of $1.22{\Omega}/{\square}$ and luminous transmittance was as high as 62% in the visible ranges.

A Study of Thin-Film Transistor with Mg0.1Zn0.9O/ZnO Active Structure (Mg0.1Zn0.9O/ZnO 활성층 구조의 박막트랜지스터 연구)

  • Lee, Jong Hoon;Kim, Hong Seung;Jang, Nak Won;Yun, Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.7
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    • pp.472-476
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    • 2014
  • We report the characteristics of thin-film transistor (TFT) to make the bi-channel structure with stacked $Mg_{0.1}Zn_{0.9}O$ (Mg= 10 at.%) and ZnO. The ZnO and $Mg_{0.1}ZnO_{0.9}O$ thin films were deposited by radio frequency (RF) co-sputter system onto the thermally oxidized silicon substrate. A total thickness of active layer was 50 nm. Firstly, the ZnO thin films were deposited to control the thickness from 5 nm to 30 nm. Sequentially, the $Mg_{0.1}ZnO_{0.9}O$ thin films were deposited to change from 45 nm to 20 nm. The bi-layer TFT shows more improved properties than the single layer TFT. The field effect mobility and subthreshold slope for $Mg_{0.1}ZnO_{0.9}O$/ZnO-TFT are $7.40cm^2V^{-1}s^{-1}$ and 0.24 V/decade at the ZnO thickness of 10 nm, respectively.

Correlation between crystalline phase and corrosion resistance of Mg alloy with different PEO conditions. I. Crystalline phase (Mg 합금의 PEO 공정 조건에 따른 산화피막 결정상과 내부식성에 대한 연구 I. 결정상)

  • Kim, Bae-Yeon;Kim, Yong-Nam;Jeon, Min-Seok;Ham, Jae-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.2
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    • pp.74-79
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    • 2018
  • To increase corrosion resistance of Mg alloy, AZ31 and AZ91 were PEO treated with different applied voltage and time conditions. We used Na-P and Na-Si system electrolyte. Crystalline phase and morphology were investigated. MgO was Most common crystal phase and vitreous phase could be found. Crystalline phase of $Na_{3.59}Mg_{2.71}(PO_4)_3$ and $Mg_2SiO_4$ also could be found. Porosity of oxidized surface tends to decrease with increasing PEO applied voltage, treat time and concentration of electrolyte, after then, size of pore increased and total number of pore decreased, distinctly.

Corelation between crystalline phase and corrosion resistance of Mg alloy with different PEO conditions. II. Corrosion resistance (Mg 합금의 PEO 공정 조건에 따른 산화피막 결정상과 내부식성에 대한 연구 II. 내부식성)

  • Kim, Bae-Yeon;Kim, Yong-Nam;Jeon, Min-Seok;Ham, Jae-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.2
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    • pp.80-84
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    • 2018
  • Mg alloys AZ31 and AZ91 were Plasma-Electrolytic-Oxidized in Na-P and Na-Si system electrolyte at various concentration, applied voltage and time. Thickness and surface roughness of PEO coating were examined. Salt spraying test were carried out to compare their corrosion resistances. Generally, corrosion resistances rate were increased as thickness and crystallinity increasing. Size of pore being larger, long term corrosion resistance decreased. It is turned out that $Mg_2SiO_4$ and other crystalline phase rather than MgO might be increase corrosion resistance dramatically.