• Title/Summary/Keyword: Oxide pool

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ESTIMATION OF ALUMINUM AND ARGON ACTIVATION SOURCES IN THE HANARO COOLANT

  • Jun, Byung-Jin;Lee, Byung-Chul;Kim, Myung-Seop
    • Nuclear Engineering and Technology
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    • v.42 no.4
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    • pp.434-441
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    • 2010
  • The activation products of aluminum and argon are key radionuclides for operational and environmental radiological safety during the normal operation of open-tank-in-pool type research reactors using aluminum-clad fuels. Their activities measured in the primary coolant and pool surface water of HANARO have been consistent. We estimated their sources from the measured activities and then compared these values with their production rates obtained by a core calculation. For each aluminum activation product, an equivalent aluminum thickness (EAT) in which its production rate is identical to its release rate into the coolant is determined. For the argon activation calculation, the saturated argon concentration in the water at the temperature of the pool surface is assumed. The EATs are 5680, 266 and 1.2 nm, respectively, for Na-24, Mg-27 and Al-28, which are much larger than the flight lengths of the respective recoil nuclides. These values coincide with the water solubility levels and with the half-lives. The EAT for Na-24 is similar to the average oxide layer thickness (OLT) of fuel cladding as well; hence, the majority of them in the oxide layer may be released to the coolant. However, while the average OLT clearly increases with the fuel burn-up during an operation cycle, its effect on the pool-top radiation is not distinguishable. The source of Ar-41 is in good agreement with the calculated reaction rate of Ar-40 dissolved in the coolant.

Experimental Investigations on Pool Boiling CHE of Nano-Fluids (나노유체의 풀비등 임계열유속에 대한 실험적 연구)

  • Kim, Hyung-Dae;Kim, Moo-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.11
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    • pp.949-956
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    • 2007
  • Pool boiling critical heat flux (CHF) of nanofluids with oxide nanoparticles of $TiO_2$ or $Al_2O_3$ was experimentally investigated under atmospheric pressure. The results showed that a dispersion of oxide nanoparticles significantly enhances the CHF over that of pure water. Moreover it was found that nanoparticles were seriously deposited on the heater surface during pool boiling of nanofluids. CHF of pure water on a nanoparticle-deposited surface, which is produced during the boiling of nanofluids, was not less than that of nanofluids. The result reveals that the CHF enhancement of nanofluids is absolutely attributed to modification of the heater surface by the nanoparticle deposition. Then, the nanoparticle-deposited surface was characterized with parameters closely related to pool boiling CHF, such as surface roughness, contact angle, and capillary wicking. Finally, reason of the CHF enhancement of nanofluids is discussed based on the changes of the parameters.

Dynamic Behavior of Oxide and Nitride LMR Cores during Unprotected Transients

  • Na, Byung-Chan;Dohee Hahn
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05a
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    • pp.489-494
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    • 1997
  • A comparative transient analyses were performed for oxide and nitride cores or a large (3000 MWt), pool-type, liquid-metal-cooled reactor (LMR). The study was focused on three representative accident initiators with failure to scram : the unprotected loss-of-flow (ULOF), the unprotected transient overpower (UTOP), and the unprotected fast transient overpower (UFTOP). The margins to fuel melting and sodium boiling have been evaluated for these representative transients. The results show that there is an increase in safety margin with nitride core which maintains the physical dimensions of the oxide core.

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Two- and three-dimensional experiments for oxide pool in in-vessel retention of core melts

  • Kim, Su-Hyeon;Park, Hae-Kyun;Chung, Bum-Jin
    • Nuclear Engineering and Technology
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    • v.49 no.7
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    • pp.1405-1413
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    • 2017
  • To investigate the heat loads imposed on a reactor vessel through the natural convection of core melts in severe accidents, mass transfer experiments were performed based on the heat transfer/mass transfer analogy, using two- (2-D) and three-dimensional (3-D) facilities of various heights. The modified Rayleigh numbers ranged from $10^{12}$ to $10^{15}$, with a fixed Prandtl number of 2,014. The measured Nusselt numbers showed a trend similar to those of existing studies, but the absolute values showed discrepancies owing to the high Prandtl number of this system. The measured angle-dependent Nusselt numbers were analyzed for 2-D and 3-D geometries, and a multiplier was developed that enables the extrapolation of 2-D data into 3-D data. The definition of $Ra^{\prime}_H$ was specified for 2-D geometries, so that results could be extrapolated for 3-D geometries; also, heat transfer correlations were developed.

Mass Transfer Experiments for the Heat Load During In-Vessel Retention of Core Melt

  • Park, Hae-Kyun;Chung, Bum-Jin
    • Nuclear Engineering and Technology
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    • v.48 no.4
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    • pp.906-914
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    • 2016
  • We investigated the heat load imposed on the lower head of a reactor vessel by the natural convection of the oxide pool in a severe accident. Mass transfer experiments using a $CuSO_4-H_2SO_4$ electroplating system were performed based on the analogy between heat and mass transfer. The $Ra^{\prime}_H$ of $10^{14}$ order was achieved with a facility height of only 0.1 m. Three different volumetric heat sources were compared; two had identical configurations to those previously reported, and the other was designed by the authors. The measured Nu's of the lower head were about 30% lower than those previously reported. The measured angular heat flux ratios were similar to those reported in existing studies except for the peaks appearing near the top. The volumetric heat sources did not affect the Nu of the lower head but affected the Nu of the top plate by obstructing the rising flow from the bottom.

Comparisons of 2-D and 3-D IVR experiments for oxide layer in the three-layer configuration

  • Bae, Ji-Won;Chung, Bum-Jin
    • Nuclear Engineering and Technology
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    • v.52 no.11
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    • pp.2499-2510
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    • 2020
  • We performed 3-D (3-dimensional) IVR (In-Vessel Retention) natural convection experiments simulating the oxide layer in the three-layer configuration, varying the aspect ratio (H/R). Mass transfer experiment was conducted based on the analogy to achieve high RaH's of 1.99 × 1012-6.90 × 1013 with compact facilities. Comparisons with 2-D (2-dimensional) experiments revealed different local heat transfer characteristics on upper and lower boundaries of the oxide layer depending on the H/R. For the 3-D shallow oxide layer, the multi-cell flow patterns appeared and the number of cells was considerably increased with the H/R decreases, which differs with the 2-D experiments that the number of cells was independent on H/R. Thus, the enhancement of the downward heat transfer and the mitigation of the focusing effect were more noticeable in the 3-D experiments.

Antioxidant properties of tidal pool microalgae, Halochlorococcum porphyrae and Oltamannsiellopsis unicellularis from Jeju Island, Korea

  • Lee, Seung-Hong;Lee, Joon-Baek;Lee, Ki-Wan;Jeon, You-Jin
    • ALGAE
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    • v.25 no.1
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    • pp.45-56
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    • 2010
  • In this study, we assessed the antioxidant properties of tidal pool microalgae, Halochlorococcum porphyrae and Oltamannsiellopsis unicellularis, from Jeju Island, Korea. Specifically, the antioxidant activity of fractions isolated from 80% methanol extract, and digests produced from five proteases and carbohydrases, were investigated. Almost all the fractions and the 80% methanol extract exhibited higher effects on 1,1-Diphenyl-2-picrylhydrazyl (DPPH) free radical scavenging. The ethyl acetate fraction showed the highest superoxide anion scavenging activity, while both n-hexane and chloroform fractions exhibited higher $H_2O_2$ scavenging activity. Among the enzymatic digests from H. porphyrae and O. unicellularis, all the digests exhibited remarkable DPPH scavenging activities. In nitric oxide inhibition, all the digests recorded significantly higher effects than those of the commercial antioxidants (p < 0.05). Flavozyme and Neutrase digests from H. porphyrae, and Termamyl and Alcalase digests from O. unicellularis, showed significant effects in metal chelating. Lipid peroxidation was significantly inhibited in the ethyl acetate fraction, in the Celluclast and Protamex digests from H. porphyrae, and in the chloroform fraction from O. unicellularis. These findings suggest that the two tidal pool microalgae tested in this study are rich in potential antioxidative compounds, the specific properties of which can be considered for use in the food and pharmaceutical industries.

Hydrodynamic effects of heater lengths on pool boiling critical heat flux (히터 길이가 수조비등 임계열유속에 미치는 수력학적 영향)

  • Su Cheong Park;Do Yeon Kim;Seon Ho Choi;Chang Hoon Lee;Younghun Lim;Chi Young Lee;Yeon Won Lee;Dong In Yu
    • Journal of the Korean Society of Visualization
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    • v.21 no.1
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    • pp.67-73
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    • 2023
  • In the study, pool boing critical heat flux (CHF) was experimentally investigated depending on the length of heaters. A smooth silicon oxide surfaces are used as the boiling surfaces. As the results of pool boiling experiments based on distilled water in ambient pressure condition, the CHF decreased as the length of the heater increased. By the high speed imaging, it was shown that the number of vapor columns increased as the length of the heater increased. Comparing the number of vapor columns and the CHF according to the heater length, the change in the CHF according to the heater length was analyzed based on the hydrodynamic instability.

Large-scale Synthesis of Uniform-sized Nanoparticles for Multifunctional Medical Applications

  • Hyeon, Taeg-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.1-1
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    • 2011
  • We developed a new generalized synthetic procedure, called as "heat-up process," to produce uniform-sized nanocrystals of many transition metals and oxides without a size selection process. We were able to synthesize uniform magnetite nanocrystals as much as 1 kilogram-scale from the thermolysis of Fe-oleate complex. Clever combination of different nanoscale materials will lead to the development of multifunctional nano-biomedical platforms for simultaneous targeted delivery, fast diagnosis, and efficient therapy. In this presentation, I would like to present some of our group's recent results on the designed fabrication of multifunctional nanostructured materials based on uniform-sized magnetite nanoparticles and their medical applications. Uniform ultrasmall iron oxide nanoparticles of <3 nm were synthesized by thermal decomposition of iron-oleate complex in the presence of oleyl alcohol. These ultrasmall iron oxide nanoparticles exhibited good T1 contrast effect. In in vivo T1 weighted blood pool magnetic resonance imaging (MRI), iron oxide nanoparticles showed longer circulation time than commercial gadolinium complex, enabling high resolution imaging. We used 80 nm-sized ferrimagnetic iron oxide nanocrystals for T2 MRI contrast agent for tracking transplanted pancreatic islet cells and single-cell MR imaging. We reported on the fabrication of monodisperse magnetite nanoparticles immobilized with uniform pore-sized mesoporous silica spheres for simultaneous MRI, fluorescence imaging, and drug delivery. We synthesized hollow magnetite nanocapsules and used them for both the MRI contrast agent and magnetic guided drug delivery vehicle.

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Refining of Steels by $Ar-CO_2$ Plasma (Ar-CO$_2$ Plasma에 의한 강(鋼)의 정련(精鍊))

  • Chang, Sek-Young;Kim, Dong-Ui
    • Journal of Korea Foundry Society
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    • v.6 no.4
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    • pp.284-289
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    • 1986
  • Decarburization phenomena have been studied by plasma in stainless steel, plain carbon steel and cast iron. It was also investigated the movement of impurity element P,S in the plasma jet metal pool. The plasma jet was obtained by $Ar\;-\;CO_2$ gas mixture with 5 kVA DC power source. It produced enough temperature to dissociate into activated oxygen atom by reaction of $CO_2{\leftrightarrows}CO+O^+$ and it reacted with ${\underline{C}}$ in metal pool. Decarburization rate was increased about 5 times in comparing with the conventional induction melted metal pool by $CO_2$ gas decarburization. Even under the Ar plasma jet, decarburization was obtained by agitation of metal bath by $Ar^+$ bombardment and dilution phenomena of carbon atom under the very high plasma temperature. But heavy element P and S are not much removed because they are too heavy in mass to be activated by $Ar^+$ion bombardment. Desulphurization was achieved by $Ar\;-\;CO_2$ plasma in plain carbon steel and cast iron by the reaction of $SO_2({\underline{S}}+O^+)$. But dephosphorization could not be obtained by $Ar\;-\;CO_2$ plasma, because gaseous reaction of phosphorous oxide (${\underline{P}}+O^+$) was not existed.

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