• Title/Summary/Keyword: Oxidation resistance

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A Study on Lubrication Characteristics of Automotive Engine Oil Merchandised in Domestic (국내 판매되는 자동차용 엔진오일의 윤활특성 연구)

  • Kim, Shin;Kang, Hyung-Kyu;Lim, Tae-Yoon;Kwon, Jong-Soo;Kim, Jai-Gueon;Choi, Dae-Sung;Kim, Dong-Kil;Jung, Choong-Sub
    • Tribology and Lubricants
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    • v.25 no.6
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    • pp.432-437
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    • 2009
  • The effect of oxidation in SAE 5W30 engine oils on friction and wear characteristics was investigated using reciprocating bench tester and shell 4-ball tester. Commercial engine oils were collected and oxidized using the KS M 2021 method modifying the oxidation time. Kinematic viscosity, total acid number(TAN), FT-IR spectrum and total base number(TBN) also measured to examine the chemical change of oils with oxidation. The results showed that TAN was slightly changed and Kinematic viscosity was suddenly increased during the oxidation stage. however, TBN results keep a constant slope after TBN linearly decreased with oxidation time. Spectroscopy results showed that spectrums were orderly increased at $1710cm^{-1}$ during the oxidation time. Friction test results showed that oxidation of oils formed unstable friction layers causing higher fluctuating friction. however, the wear resistance was independent of oxidized time due to the different friction characteristics by oxidation. We found several factors in relation to lubrication properties with oxidation time. This factors were Viscosity, TBN, change of FT-IR spectrum, friction coefficient using reciprocating bench tester and wear scar.

Effect of Al and Cr contents on the High Temperature Oxidation- and Sulfidation-resistance of Fe Alloys (Fe합금의 내 산화성과 황화성에 미치는 Al과 Cr 함량의 영향)

  • Kim, Seul-Ki;Lee, Dong-Bok
    • Journal of the Korean institute of surface engineering
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    • v.45 no.2
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    • pp.61-69
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    • 2012
  • Alloys of Fe-(5, 10, 15)Al and Fe-(10, 20, 30, 40)Cr were corroded at 700 and $800^{\circ}C$ for 70 hr in either atmospheric air or 1 atm of Ar+$1%SO_2$ gases. In these atmospheres, Fe-5Al and Fe-10Cr alloys displayed poor corrosion resistance. In atmospheric air, Fe-5Al alloys formed oxide nodules, while Fe-10Cr alloys formed thick scales and internal oxides. In Ar+$1%SO_2$ gases, Fe-5Al and Fe-10Cr alloys formed thick, nonadherent bi-layered scales, which grew primarily by the outward diffusion of Fe ions and inward diffusion of oxygen and sulfur ions. By contrast, in atmospheric air and Ar+$1%SO_2$ gases, Fe-(10, 15)Al and Fe-(20, 30, 40)Cr alloys displayed good corrosion resistance by forming $Al_2O_3$ and $Cr_2O_3$ layers on the surface, respectively.

Effect of Potassium Permanganate on Corrosion Behavior of Magnesium Alloy Prepared by Micro-Arc Oxidation (마이크로 아크 산화처리된 마그네슘 합금의 부식특성에 미치는 과망간산칼륨의 영향)

  • Ko, Young Gun;Lee, Kang Min;Shin, Ki Ryong;Shin, Dong Hyuk
    • Korean Journal of Metals and Materials
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    • v.48 no.8
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    • pp.724-729
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    • 2010
  • The effect of potassium permanganate ($KMnO_4$) in an electrolyte on the corrosion performance of magnesium alloy coated by micro-arc oxidation (MAO) has been investigated in this study. For this purpose, MAO coating was carried out on the present sample under AC condition in an alkaline silicate electrolyte with and without $KMnO_4$. Irrespective of the addition of $KMnO_4$, it was found from structural observation that the ceramic coating layers consisted of inner and outer layers. In the sample processed in the electrolyte with $KMnO_4$, the outer layer became dense and even contained a number of $Mn_2O_3$ atoms, resulting in high corrosion resistance. Based on the results of a potentiodynamic polarization test, it was confirmed that the coating layer formed in the electrolyte with $KMnO_4$exhibited better corrosion resistance than that without $KMnO_4$. The high corrosion resistance of the MAO-treated magnesium alloy was explained in relation to the equivalent circuit model.