• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.25.2-25.2
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• 2011

The tungsten oxide wire-like nanostructure is fabricated by deposition and thermal oxidation of tungsten metal on porous single wall carbon nanotubes (SWNTs). The morphology and crystalline quality of materials are investigated by SEM, TEM, XRD and Raman analysis. The results prove that $WO_3$ wire-like nanostructure fabricated on SWNTs show highly porous structures. Exposure of the sensors to NH3 gas in the temperature range of 150~300$^{\circ}C$ resulted in the highest sensitivity at $250^{\circ}C$ with quite rapid response and recovery time. Response time as a function of test concentrations and NH3 gas sensing mechanism is reported and discussed.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 1999.10a
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• pp.332-338
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• 1999

Surface hardening of plain carbon steel (SM$%C) by Laser are usually much finer and stronger than those of the base metals. The present study was undertaken to investigate the wear resistance and a processing parameters such as, power density, pulse width, defocusing distance, and molten depth for surface modification of plain carbon steel. The wear test was carried out under experimental condition using the wear test device, and in which the annular surfaces of wear test specimens as well as mating specimen of alumina ceramics(Al2O3) was rubbed in dry sliding condition. It is shown that molten depth and width depend on defocusing distance. The wear loss on variation of sliding speed was much in lower speed range below 0.2m/sec and in higher speed range above 0.7m/sec, but wear loss was little in intermediate speed range. It depends on oxidation speed and wear speed.

• Journal of Bio-Environment Control
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• v.3 no.2
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• pp.136-144
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• 1994

A long- time aeration method was developed for purification of animal wastewater. Under repeated aereations of 4 hours on and 4 hours off, the higher removal rates were obtained which were in average of 99%, 96%, 92% and 50% for BOD, SS, total nitrogen and phosporous, respectively. In detail, the measured BOD concentrations of the influent and effluent were 2,700ppm and 40ppm while the SS concentrations in the primary chamber and of the effluent were about 3,000 and 110 ppm, respectively. Zeolite and activated carbon, applied for removing the nitrogen and phosphorous, showed a good absorption, especially zeolite for NH$_4$-N and activated carbon for NO$_3$-N and PO$_4$-P. The treatment cost per head by this method amounts to 1,923 won and it comes to 1.6% in the whole production cost. Therefore, this method is economically available with the half cost of the conventional activated sludge process.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.6
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• pp.621-630
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• 1998

The concentrations of organic carbon (OC) and elemental carbon (EC) in fine aerosols were determined from the samples collected at the two background sites of Kosan in Cheju Island and Kangwha. Samplings were carried out during the spring and winter of 1996 and the fall and winter of 1997. PM25 particles were collected on the prefired quartz filters for 24 hours and analyzed by the selective thermal oxidation method. The concentrations of OC at the sites were higher than those commonly observed from clean areas around the world, but those of EC at both sites were lower than, or comparable to, other clean areas in the world. Both the OC and EC levels at Kangwha were higher than those at Kosan. According to backward trajectory analysis, most air pollutants collected at the two sites were from China. It was found that the OC and EC concentrations in air masses from southern China were higher than those from northern China.

• Journal of environmental and Sanitary engineering
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• v.19 no.3 s.53
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• pp.31-39
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• 2004

In order to reduce the pollution load from the livestock farms and to improve the water quality of the effluent in livestock wastewater, the electrolysis system is introduced. For the selection of optimal electrode, various combination of electrodes such as carbon, Al and Fe were examined. In this study, electrode material, electrolyte concentration, electrode distance, current density, and pH value were found to have significant effect on both pollutant removal efficiency and current efficiency in electrochemical oxidation process. After electrolysis for 90 min with carbon/Al, it was observed that COD, T-N, T-P and $NH_4^+-N$ of livestock waste-water were removed with $80\%,\;61\%,\;81\%\;and\;87\%$, respectively.

• Journal of Environmental Health Sciences
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• v.21 no.2
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• pp.68-74
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• 1995

The optimum conditions was synthesized for the formation of Magnetite ($Fe_3O_4$) by air bubbling with the suspensions obtained by mixing Ferrous sulfate ($FeSO_4\cdot 7H_2O$) and Sodium Hydroxide (NaOH) solution in various values equivalent ratio($R=2NaOH/FeSO_4$) were studied. The changes of the structure were measured with XRD, $EM and BET. Equivalent ratio R: 0.65 was synthesized Goethite ($\alpha$-FeOOH), which becomes Maghemite ($\gamma=Fe_2O_3$) by dehydration, reduction and oxidation process. At the equivalent ratio over 1 (R>1), Magnetite ($Fe_3O_4$) was synthesized directly. The oxygen-deficient Magnetite ($Fe_3O_{4-\delta}$), which is obtained by flowing $H_2$ gas(100 ml/min) through the synthesis Magnetite at 350$\circ$C for 4 hr. By using it, was researched the decomposition reaction of $CO_2$. $CO_2$ was decomposed nearly 100% in 45 minutes by the oxygen-deficient Magnetite.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.487-490
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• 2008

Temperature programmed oxidation (TPO) is used to characterize coke species deposited on commercial nickel catalyst, C11-PR during propane pre-reforming. Propane pre-reforming performed under various condition, S/C from 1.5 to 2.5 and temperature from $350^{\circ}C$ to $450^{\circ}C$. There are three kinds of coke species detected by TPO: (i) reactive coke, (ii) coke deposited on metal site and (iii) coke deposited on acid support. Coke deposited on metal and support are minimized although reactive coke is generated at temperature of $400^{\circ}C$ and S/C of 2.0. Reactive coke is expected to remove easily below temperature of $200^{\circ}C$. Therefore, optimized pre-reforming condition for propane is $400^{\circ}C$ and S/C of 2.0.

• Journal of the Korean Ceramic Society
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• v.29 no.8
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• pp.601-608
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• 1992

We investigated the influence of several processes, including the preparation of slurry and preform and the heat-treatment of the preform, on the properties of composites to fabricate the carbon-fiber reinforced glass composites having good mechanical properties. Cerander was determined to be the best binder among Cerander, Rhoplex and Elvacite 2045 by the dipping test and the binder within a preform could be completely eliminatd by burning out the specimen under 10-6 Torr at 400$^{\circ}C$ for more than 1h. The fracture behavior of a composite was largely dependent on the uniformity of carbon-fiber distribution within the composite and the heat-treatment condition of the composite. The higher the glass content, the more difficult to obtain uniform distribution of carbon-fiber. As the hot-pressing temperature increased, the densification process of the composite and the formation of pore due to oxidation of carbon fiber occurred competitively. But, above 1000$^{\circ}C$ the latter played a predominant role. We could fabricated the densest 15 vol.% carbon-fiber-content glass composite having the highest toughness and flexural strength of 250 MPa by hot-pressing under 15 MPa at 900$^{\circ}C$ for 30 min.

• Proceedings of the Korean Environmental Health Society Conference
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• 2002.04a
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• pp.23-25
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• 2002

This study was conducted to understand characteristics of wastewater which is discharged from small-scale dyehouse located in Seoul downtown area and to Find the appliable treatment method on the spot. The results of this study were summarized as followings. 1. The method which is used at present is mostly flocculation by coagulant or fenton oxidation. But the treatment efficiency of them are not good. 2. The results of fenton oxidation experiment demonstrated that treatment efficiency of COD was limited, which showed the need of the additional process or the improvement of existing treatment method, while the color was reduced considerably in optimal condition. 3. The optimal condition of fenton oxidation are as followings. -Feasible pH was in the 3∼4 regardless of the kinds of iron ions, But the fluctuation of treatment efficiency with the change of pH was small - The mass ratio of H$_2$O/CODcr was used to evaluate the parameter of H$_2$O$_2$ The optimal range of this was in 0.7∼1,3 and it was observed that the ratio got higher as the quality got worse. -For iron ion, FeCl$_2$4H$_2$O turned out to be more effective for removal of color compared with was compared FeSO$_4$7H$_2$Oin. the mass ratio of Fe/H$_2$O$_2$ of 2.3∼2.8 for of FeSO$_4$7H$_2$O and 1.6∼1.8 for FeCl$_2$4H$_2$O resulted in good treatment efficiencies. 4. With adsorption process applied before fenton oxidation in order to treat the high concentration wastewater, the treatment efficiency increased by 61％ in CODcr, 55％ in color. and if the power activated carbon is injected in more than 2500mg/$\ell$, the wastewater can be treated within the effluent quality criteria.

• Composites Research
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• v.29 no.3
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• pp.104-110
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• 2016

This paper reports a novel method for simultaneous exfoliation of graphene and dispersion of carbon nanotube by using intercalation method. In common, graphene flake and carbon nanotubes can be produced through individual exfoliation or debundling process, but the process require significant amount of time. Here, potassium sodium tartrate was thermally intercalated into graphite and carbon nanotube bundle for simultaneous exfoliation and dispersion of graphene and carbon nanotubes. We confirmed expansion of interlayer distance via XRD, and also found that oxidation level of the exfoliated materials were significantly low (below 8.3 at%). The produced materials are fabricated in to conductive composite film via vacuum filtration and spray deposition to show enhancement of conductive properties.