• Title/Summary/Keyword: Oxidation of carbon

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Removal of carbon monoxide using a solid electrolyte cell reactor (고체전해질 전지 반응기를 이용한 일산화탄소의 제거)

  • 신석재;오인환
    • Journal of the Korean Society of Safety
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    • v.11 no.3
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    • pp.112-118
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    • 1996
  • When fossil fuels are burned they produce CO gas because of incomplete combustion. If the CO gas reacts with the hemoglobin in the red blood cells, it may result in death or sequelae. Generally, the CO gas is eliminated in the form of the $$$CO_2$ gas by the oxidation reaction over the platinum catalyst. In this study, the electrochemical CO removal was investgated by using the solid electrolyte cell reactor, the type of which was represented as reactants$/Pt/Y_2O_3-ZrO_2/Pt/Air$. If the overpotential was applied to the platinum working electrode, the conversion could be changed with the overpotential applied. It was found that the oxidation rate could be increased 2.8 times higher than that of the normal condition, i. e. under open circuit conditions when $P_{co}/P_{O_2}$ was 0.5 and overpotential was 0.9V. From these results, it is concluded that the reactor used in this study is more efficient than conventional catalytic reactors.

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Technologies for Volatile Organic Compounds(VOCs) Treatment (휘발성 유기 화합물(VOCs) 처리 기술)

  • 서봉국;나영수;송승구
    • Journal of Environmental Science International
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    • v.12 no.7
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    • pp.825-833
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    • 2003
  • The emission of volatile organic compounds (VOCs) generated from painting and coating processes is a worldwide problem as contributing factors to the development of photochemical smog and other environmental problems. Common methods of reducing VOC emissions are adsorption on activated carbon, membrane separation, absorption, incineration, or catalytic oxidation. In this article, the environmental issues caused by VOC emissions and the trend of legislation against such emissions will be surveyed first. Several conventional control technologies will then be summarized and the characteristics of each process will be introduced. Lastly, some examples will be described to show the hybrid processes which have been industrially applied for the recovery of VOC.

A Study on the removal of B.T.X by UV Photooxidation-Activated Carbon (광산화-활성탄 복합공정에 의한 B.T.X. 분해에 관한 연구)

  • Jeong, Chang Hun;Bae, Hae Ryong
    • Journal of Environmental Science International
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    • v.13 no.1
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    • pp.41-45
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    • 2004
  • In this study, The decomposition of gas-phase Benzene and Toluene, Xylene in air streams by direct UV Photolysis, UV/TiO$_2$ and UV/TiO$_2$/A.C process was studied. The experiments were carried out under various UV light intensities and initial concentrations of B.T.X to investigate and compare the removal efficiency of the pollutant. B.T.X was determined by GC-FID of gas samples taken from the a glass sampling bulb which was located at reactor inlet and outlet by gas-tight syringe. From this study, the results indicate that UV/TiO$_2$/A.C system (photooxidation-photocatalytic oxidation-adsorption process) is ideal for treatment of B.T.X from the small workplace. Although the results needs more verifications, the methodology seems to be reasonable and can be applied for various workplace (laundry, gas station et al.).

Methane Reforming Using Atmospheric Plasma Source (대기압 플라즈마를 이용한 메탄 개질 반응)

  • Lee, Dae-Hoon;Kim, Kwan-Tae;Cha, Min-Suk;Song, Young-Hoon;Kim, Dong-Hyeon
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.64-68
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    • 2005
  • Methane reforming processes to obtain hydrogen were investigated experimentally by using atmospheric plasma source. Among possible reforming processes, such as a $CO_2$ reforming(dry reforming), a partial oxidation (POx), a steam reforming(SR), and a steam reforming with oxygen(SRO or auto-thermal reforming), partial oxidation and the steam reforming with oxygen were considered. We choose a rotating arc plasma as an atmospheric plasma source, since it shows the best performances in our preliminary tests in terms of a methane conversion, a hydrogen production, and a power consumption. Then, the effects of a feeding flow-rate, an electrical power input to a plasma reaction, an $O_2/C$ ratio and a steam to carbon ratio in the case of SRO on the reforming characteristics were observed systematically. As results, at a certain condition almost 100% of methane conversion was obtained and we could achieve the same hydrogen production rate by consuming a half of electrical power which was used by the best results for other researchers.

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Microbial synthesis of sex hormones

  • Lee, Sang-Sup;Kang, Young-Ui;Kim, Young-Bae;Han, Jung-Rip
    • YAKHAK HOEJI
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    • v.16 no.3
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    • pp.137-147
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    • 1972
  • Estrone, which is obtainable from 19-hydroxycholesterol acetate through microbial oxidation, was chemically transformed to orally active estrogens, ethynylestradiol and methylestradiol. For progestin synthesis, $5{\alpha}$-bromo-619-oxidoisoandrosterone, was harvested from the culture broth(ATCC:19170), in which $5{\alpha}$-bromo-619-oxidocholestanol, acetate was added as a carbon source. Methylestrenolone, a potent orally active progestin, was synthesized from the harvested product via several reactions. Norethindrone, a popular progestin, was also prepared from 19-norandrostenedione. 19-Norandrostenedione is also available through microbial oxidation and chemical modification of $5{\alpha}$-chlor-619-oxidocholestanol, acetate.

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Natural Organic Matter Removal and Fouling Control in Low-Pressure Membrane Filtration for Water Treatment

  • Cui, Xiaojun;Choo, Kwang-Ho
    • Environmental Engineering Research
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    • v.19 no.1
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    • pp.1-8
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    • 2014
  • Natural organic matter (NOM) is a primary component of fouling in low-pressure membrane filtration, either solely, or in concert with colloidal particles. Various preventive measures to interfere with NOM fouling have been developed and extensively tested, such as coagulation, oxidation, ion exchange, carbon adsorption, and mineral oxide adsorption. Therefore, this article aims to conduct a literature review covering the topics of low-pressure membrane processes, NOM characteristics and fouling behaviors, and diverse fouling control strategies. In-depth explanations and discussion are made regarding why some treatment options are able to remove NOM from source water, but do not reduce fouling. This review provides insight for hybridized membrane processes with respect to NOM removal and fouling mitigation in water treatment.

Cell Design for Mixed Gas Fuel Cell (혼합가스 주입형 연료전지를 위한 전지 디자인)

  • Park, Byung-Tak;Yoon, Sung Pil
    • Journal of the Korean Ceramic Society
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    • v.42 no.12 s.283
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    • pp.860-864
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    • 2005
  • In this study, we fabricated honeycomb type Mixed-Gas Fuel Cell (MGFC) which has advantages of stacking to the axial direction and increasing volume power density. Honeycomb-shaped anode with four channels was prepared by dry pressing method. Two alternative channels were coated with electrolyte and cathode slurry in order to make cathodic reaction sites and the others were filled with partial oxidation (POX) catalyst to increase fuel conversion. Furthermore we employed the sol-gel technique which can increase cell performance and decrease carbon coking.

Soil organic carbon variation in relation to land use changes: the case of Birr watershed, upper Blue Nile River Basin, Ethiopia

  • Amanuel, Wondimagegn;Yimer, Fantaw;Karltun, Erik
    • Journal of Ecology and Environment
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    • v.42 no.3
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    • pp.128-138
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    • 2018
  • Background: This study investigated the variation of soil organic carbon in four land cover types: natural and mixed forest, cultivated land, Eucalyptus plantation and open bush land. The study was conducted in the Birr watershed of the upper Blue Nile ('Abbay') river basin. Methods: The data was subjected to a two-way of ANOVA analysis using the general linear model (GLM) procedures of SAS. Pairwise comparison method was also used to assess the mean difference of the land uses and depth levels depending on soil properties. Total of 148 soil samples were collected from two depth layers: 0-10 and 10-20 cm. Results: The results showed that overall mean soil organic carbon stock was higher under natural and mixed forest land use compared with other land use types and at all depths ($29.62{\pm}1.95Mg\;C\;ha^{-1}$), which was 36.14, 28.36, and 27.63% more than in cultivated land, open bush land, and Eucalyptus plantation, respectively. This could be due to greater inputs of vegetation and reduced decomposition of organic matter. On the other hand, the lowest soil organic carbon stock under cultivated land could be due to reduced inputs of organic matter and frequent tillage which encouraged oxidation of organic matter. Conclusions: Hence, carbon concentrations and stocks under natural and mixed forest and Eucalyptus plantation were higher than other land use types suggesting that two management strategies for improving soil conditions in the watershed: to maintain and preserve the forest in order to maintain carbon storage in the future and to recover abandoned crop land and degraded lands by establishing tree plantations to avoid overharvesting in natural forests.

Sliding Wear Properties of Carbon Fiber Reinforced $Si_3N_4$ Ceramics (탄소섬유강화 질화규소 세라믹스의 마찰마모 특성)

  • Park Yi-Hyun;Yoon Han-Ki;Kim Bu-Ahn;Park Won-Jo
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.347-351
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    • 2004
  • [ $Si_3N_4$ ] composites have been extensively studied for engineering ceramics, because it has excellent room and high temperature strength, wear resistance properties, good resistance to oxidation, and good thermal and chemical stability. In the present work, carbon short fiber reinforced $Si_3N_4$ ceramics were fabricated by hot press method in $N_2$ atmosphere at $1800^{\circ}C$ using $Al_2O_3\;and\;Y_2O_3$ as sintering additives. Content of carbon short fiber was $0\%,\;0.1\%\;and\;0.3\%$. The composites were evaluated in terms of density, flexural strength and elastic modulus through the 3-point bending test at room temperature. Also, The wear behavior was determined by the pin on disk wear tester using silicon nitride ball. Experimental density and flexural strength decreased with increasing content of carbon fiber. But specific modulus increased with increasing content of carbon fiber. In addition, friction coefficient and specific wear loss decreased with increasing content of carbon short fiber by reason of interfacial defects between matrix and fiber.

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Oxidation-treated of Oxidized Carbons and its Electrochemical Performances for Electric Double Layer Capacitor (산화처리 탄소의 전기화학적 거동 및 이를 이용한 EDLC 특성)

  • Yang, Sun-Hye;Kim, Ick-Jun;Jeon, Min-Je;Moon, Seong-In;Kim, Hyun-Soo;An, Kye-Hyeok;Lee, Yun-Pyo;Lee, Young-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.481-481
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    • 2007
  • This work describes the effect of the number of roll pressing and the composition of carbon black on the electric and mechanical properties of carbon-PTFE electrode, in which composition is MSP 20 : carbon black: PTFE = 95-x : x : 5 wt.%. It was found that the best electric and mechanical properties were obtained in sheet electrode roll-pressed for about 15 times and in sheet electrode, in which composition is MSP 20 : carbon black: PTFE = 80 : 15 : 5 wt.%. These behaviors could be explained by the network structure of PTFE fibrils and conducting paths linked with carbon blacks, respectively. On the other hand, cell capacitor using the sheet electrode with 15 wt.% of carbon black attached on aluminum current collector with the electric conductive adhesive, in composition is carbon black : CMC = 70 : 30 wt.%, has exhibited the best rate capability in the current range of $0.5mA/cm^2$ $100mA/cm^2$ and the lowest equivalent series resistance.

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