• 제목/요약/키워드: Oxidation efficiency

검색결과 954건 처리시간 0.028초

축열식 저 NOx 연소기의 배가스 재순환이 연소특성에 미치는 영향 (The effect of flue-gas recirculation on combustion characteristics of regenerative low NOx burner)

  • 강민욱;윤영빈;동상근
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2002년도 제25회 KOSCI SYMPOSIUM 논문집
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    • pp.97-104
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    • 2002
  • The conventional regenerative system has a high thermal efficiency as well as energy saving using the high preheated combustion air. in spite of these advantages, it can not avoid high nitric oxide emissions. Recently, flameless combustion has received much attention to solve these problems. In this research, numerical analysis is performed for flow-combustion phenomena in the self regenerative burner. In this analysis we used Fluent 6.0 code. the that is developed for commercial use, Methane gas is used as a fuel and two-step reaction model for methane and Zeldovich mechanism for NO generation are used. the velocity of the preheated combustion air is used as a parameter and we analyze the characteristics of flow-field, temperature distributions and NO emissions. Due to the increased recirculation rate, the maximum temperature of flame is significantly increased and NOx emissions is reduced

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촉매연소 시스템 안정화 : 고온용 열교환기를 이용한 능동제어 (Catalytic Combustion System Stability:Active Control with High Temperature Heat Exchanger)

  • 유상필;송광섭
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2002년도 제25회 KOSCI SYMPOSIUM 논문집
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    • pp.65-69
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    • 2002
  • Catalytic combustion known as one of the traditional oxidation methods of VOC gas is restricted to its applicable fields because of its reaction characteristics. But recently innovative improvement of catalytic endurance makes its applicable range broader from MEMs to industrial power generation. Therefore, control technologies based on the catalytic combustion characteristics are researched and developed dynamically. Especially, the stable control of catalytic combustion is an essential factor in a view of maximizing its efficiency. In this research, the fuel equivalence ratio and the preheating temperature of mixture gas is controlled by catalytic combustion system enhanced in heat transfer with high temperature heat exchanger. As a result, the combustion characteristics of system was investigated, and both passive and active control type were compared and analyzed.

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해수담수화에서 용존유기물을 제거하기 위한 전처리 공정의 평가 (Evaluation of Pretreatment Processes for Dissolved Organic Carbon Removal in a Desalination Process)

  • 김우항
    • 한국물환경학회지
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    • 제20권5호
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    • pp.447-451
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    • 2004
  • The various pretreatment processes were evaluated to remove organic pollutants of weathered oil contaminated seawater(WOCS) for reverse osmosis desalination process, Biodegradation, coagulation, ultrafiltration, advanced oxidation processes and granular activated carbon filtration were used to evaluate the potential of organic pollutants removal in WOCS. Dissolved Organic Carbon(DOC) was almost not removed by biodegradation in WOCS. DOC was removed by 25% and 10% with the addition of $FeCl_3$ and PAC in WOCS, respectively. The removal efficiency using ultrafiltration(WOCS 500) was about 20% of DOC and 40% of $E_{260}$, respectively. In AOP application of WOCS, the removal of organic materials was improved up to 60% by the combination of $UV/O_3$ compared to UV process. However, 98% of DOC in woes could be removed by granular activated carbon filtration. It is revealed that activated carbon filtration is the best process for the pretratment of DOC removal.

광펜톤반응과 펜톤반응에 의한 수중 클로로페놀 분해비교연구 (Degradation Of 4-chlorophenol By Photo-Fenton Process and Fenton Process in Aqueous Solutions)

  • 김현승;김일규
    • 상하수도학회지
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    • 제25권4호
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    • pp.463-469
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    • 2011
  • The degradation of 4-chlorophenol by various AOPs(Advanced Oxidation Processes) including the Fenton and the photo-Fenton process has been examined. In sole Fe, UV or $H_2O_2$ process without combination, low removal efficiencies have been achieved. But the photo-Fenton process showed higher removal efficiency for degradation of 4-chlorophenol than those of other AOPs including the Fenton process. Generally more hydrogen peroxide was required to achieve higher removal efficiencies of 4-CP at constant dosage of $FeSO_4$ in both of the Fenton and the photo-Fenton processes. Based on the results, The photo-Fenton process is proposed to be the most efficient alternative for degradation of 4-chlorophenol among the processes studied in this research.

비단열 화염편 모델을 이용한 Mild Combustor의 연소특성 해석 (A Study on Characteristics of Mild Combustion using the Radiative Flamelet Model)

  • 김군홍;김용모;안국영
    • 한국자동차공학회논문집
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    • 제13권1호
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    • pp.60-67
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    • 2005
  • Mild combustion or Flameless oxidation(FLOX) have been considered as one of the most prospective clean-combustion technologies to meet both the targets of high process efficiency and low pollutant emissions. A mild combustor with high air preheating and strong internal exhaust gas recirculation is characterized by relatively low flame temperature, low NOx emissions, no visible flame and no sound. In this study, the Steady Flamelet Approach has been applied to numerically analyze the combustion processes and NOx formation in the mild combustor. The detailed discussion has been made f3r the basic characteristics of mild combustor, numerical results and limitation of the present combustion modeling.

Encapsulation of Flavors by Molecular Inclusion Using $\beta$-Cyclodextrin: Comparison with Spray-drying Process Using Carbohydrate-based Wall Materials

  • Cho, Young-Hee;Park, Ji-Yong
    • Food Science and Biotechnology
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    • 제18권1호
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    • pp.185-189
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    • 2009
  • Microencapsulation of flavor was carried out by molecular inclusion process using $\beta$-cyclodextrin (${\beta}CD$). ${\beta}CD$-flavor complex was prepared at various flavor-to-${\beta}CD$ ratios (1:6-1:12) to determine the effect of ${\beta}CD$ concentration on the inclusion efficiency. Maximum total oil retention and minimal surface oil content were obtained at flavors to ${\beta}CD$ ratio of 1:10. The physical properties and controlled release pattern of flavors from ${\beta}CD$-flavor complex were measured and compared with spray-dried microcapsules prepared using carbohydrate wall system. ${\beta}CD$-flavor complex showed higher total oil retention and surface oil contents, smaller mean particle size, lower moisture uptake, and higher oxidation stability than spray-dried microcapsule. Oxidative stability of flavor was correlated with hygroscopicity of wall materials. The controlled release mechanism was highly affected by temperature and characteristics of wall materials.

고대 출토 철제 유물의 환경 변화에 따른 고찰 (The Study of Environment Change for Iron Antiquities after Excavation)

  • 문환석;김병근;위광철;황진주
    • 보존과학연구
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    • 통권14호
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    • pp.35-44
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    • 1993
  • The way of prevention for the continuous corrosion progress in iron antiquities after excavation and conservation treatment have been studied. The corrosion occuring have been found the oxidation of ferrous ions in the presence of chloride. The consideration to control the activity of chloride is important of controling relative humidity for the stable environment of the storage. One of the method that keeps archeological iron antiquities recommend the storage of special vinyl film(poly-vinyl alcohol film) with silica gel to control the relative humidity. Although this method is not permanent, it's very well efficiency of economy and convenience at present.

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하이브리드 로켓의 연소특성 해석 (Analysis for Combustion Characteristics of Hybrid Rocket Motor)

  • 김후중;김용모;윤명원
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2001년도 제17회 학술발표회 논문초록집
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    • pp.61-67
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    • 2001
  • Hybrid propulsion systems provide many advantages in terms of stable operation and safety. However, classical hybrid rocket motors have lower fuel regression rate and combustion efficiency compared to solid propellant rocket motor. The recent research efforts are focused on the improvement of volume limitation and regression rate in the hybrid rocket engine. The present study has numerically investigated the combustion processes in the hybrid rocket engine. The turbulent combustion is represented by the eddy breakup model and Hiroyasu and Nagle and Strickland-Constable model are used for soot formation and soot oxidation. Radiative heat transfer is modeled by finite volume method. To reduce the uncertainties for convective heat transfer near solid fuel surface having strong blowing effect, the Low Reynolds number k-$\varepsilon$ turbulent model is employed. Based on numerical results, the detailed discussion has been made for the turbulent combustion processes in the vortex hybrid rocket engine.

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CVD 방법(方法)에 의한 SnO_2/n-Si$ 태양전지(太陽電池)의 제작(製作) ([ $SnO_2/n-Si$ ] Solar Cell Fabricated by the CVD Method)

  • 노경석;손연규;이동헌
    • 태양에너지
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    • 제8권2호
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    • pp.19-25
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    • 1988
  • [ $SnO_2$ ] thin films have been deposited on the pyrex glasses and silicon wafers by CVD method. Tin oxide films had a good transmittance above 80% in the visible region and the lowest sheet resistance at $520^{\circ}C$. When the ratio of $SbCl_3$ was 2wt%. The optimum conditions were obtained at the oxidation time of 3 minutes in the case that Voc and Jsc were 0.40V and $33.5mA/cm^2$ respectively and the corresponding conversion efficiency was 6.07%.

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Kinetic Characterization and Molecular Modeling of $NAD(P)^+$-Dependent Succinic Semialdehyde Dehydrogenase from Bacillus subtilis as an Ortholog YneI

  • Park, Seong Ah;Park, Ye Song;Lee, Ki Seog
    • Journal of Microbiology and Biotechnology
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    • 제24권7호
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    • pp.954-958
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    • 2014
  • Succinic semialdehyde dehydrogenase (SSADH) catalyzes the oxidation of succinic semialdehyde (SSA) into succinic acid in the final step of ${\gamma}$-aminobutyric acid degradation. Here, we characterized Bacillus subtilis SSADH (BsSSADH) regarding its cofactor discrimination and substrate inhibition. BsSSADH showed similar values of the catalytic efficiency ($k_{ca}t/K_m$) in both $NAD^+$ and $NADP^+$ as cofactors, and exhibited complete uncompetitive substrate inhibition at higher SSA concentrations. Further analyses of the sequence alignment and homology modeling indicated that the residues of catalytic and cofactor-binding sites in other SSADHs were highly conserved in BsSSADH.