• Title/Summary/Keyword: Oxidation efficiency

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The Evaluation of Catalytic Trap Oxidizer on a City Bus (市內버스 煤煙防止를 위한 觸媒酸化濾過裝置의 實用化 硏究)

  • Cho, Kang-Rae;Kim, Yang-Kyun;Eom, Myung-Do;Kim, Chong-Chun
    • Journal of Korean Society for Atmospheric Environment
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    • v.5 no.1
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    • pp.79-87
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    • 1989
  • In order to reduce the smoke emission from the in-service city bus, this study was evaluated the particulate reduction efficiency and regeneration ability of the catalitic trap oxidizer (CTO) on the city bus (D0846HM engine) equipped with it. Before the on-road CTO test, the laboratory test of CTO on engine test-bench was performed. Reduction efficiencies of smokes and particulates were 54 and 45%, and those of gaseous pollutants such as carbon monoxide (CO) and hydrocarbons (HC) were 90 and 60%. In order to evaluate the regeneration ability of the CTO by the catalytic oxidation of trapped particulate, field test was performed on the in-service road. The regeneration temperature was 350$^\circ$ which was same with the exhaust temperature of city bus.

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Removing Malodor Using Photocatalyst and Infrared (광촉매와 적외선을 이용한 악취저감)

  • Jeon, Tae-Yeong;Kim, Jae-Yong
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.8
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    • pp.528-533
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    • 2014
  • Recently, people interest in environmental pollution and attempt to improve the indoor air quality contaminated with various pollutants since it is very important to construct healthy and comfortable living environment. In the current study, we used the technology that has first received the certification of green technology for improving the removal efficiency of malodor causing substances. This green technology is a new technology to increase the reactivity of the odorous substances with OH radicals for oxidation reaction by using an infrared lamp in the existing air purification system. Comparing the efficiency of the green technology with the infrared lamp to that of the existing technology of air cleaner, there was a difference in the decomposition efficiency depending on the initial concentrations and speciation of the odorous substances. The removal efficiencies of contaminants were enhanced by 16.9 and 13.2% at low and high concentrations, respectively.

Optimized ultra-thin tunnel oxide layer characteristics by PECVD using N2O plasma growth for high efficiency n-type Si solar cell

  • Jeon, Minhan;Kang, Jiyoon;Oh, Donghyun;Shim, Gyeongbae;Kim, Shangho;Balaji, Nagarajan;Park, Cheolmin;Song, Jinsoo;Yi, Junsin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.308-309
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    • 2016
  • Reducing surface recombination is a critical factor for high efficiency silicon solar cells. The passivation process is for reducing dangling bonds which are carrier. Tunnel oxide layer is one of main issues to achieve a good passivation between silicon wafer and emitter layer. Many research use wet-chemical oxidation or thermally grown which the highest conversion efficiencies have been reported so far. In this study, we deposit ultra-thin tunnel oxide layer by PECVD (Plasma Enhanced Chemical Vapor Deposition) using $N_2O$ plasma. Both side deposit tunnel oxide layer in different RF-power and phosphorus doped a-Si:H layer. After deposit, samples are annealed at $850^{\circ}C$ for 1 hour in $N_2$ gas atmosphere. After annealing, samples are measured lifetime and implied Voc (iVoc) by QSSPC (Quasi-Steady-State Photo Conductance). After measure, samples are annealed at $400^{\circ}C$ for 30 minute in $Ar/H_2$ gas atmosphere and then measure again lifetime and implied VOC. The lifetime is increase after all process also implied VOC. The highest results are lifetime $762{\mu}s$, implied Voc 733 mV at RF-power 200 W. The results of C-V measurement shows that Dit is increase when RF-power increase. Using this optimized tunnel oxide layer is attributed to increase iVoc. As a consequence, the cell efficiency is increased such as tunnel mechanism based solar cell application.

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Fabrication of Semiconductor-Insulator-Semiconductor Solar Cells and their Characteristics (SIS 태양전지의 제조 및 그 특성)

  • Kim, Jin-Seop;Lee, Deok-Dong;Lee, U-Il
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.18 no.4
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    • pp.21-26
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    • 1981
  • SnO2/n-Si and ITO/n-Si SIS solar cells have been fabricated ty mears of electron-beam deposition. The optimum oxidation and heat-treatment condition for SnO2/n-Si cells and ITO/n-Si cells are 50$0^{\circ}C$-5min., 30$0^{\circ}C$-10min., and 50$0^{\circ}C$-5min., 30$0^{\circ}C$-20min. respectively. The open-circuit Voltage(Voc), short-circuit current density(Jsc), fill factor(FF), and efficiency (η) under AMI(100mW/$\textrm{cm}^2$) illumination were 0.4V, 34mA/$\textrm{cm}^2$, 0.44, and 6.0%(active area efficiency, 6.9%) for SnO2/n-Si solar cells, and 0.44V, 36mA/$\textrm{cm}^2$, 0.53, and 8.45%(active area efficiency, 9.71%) for ITO/n-Si solar calls.

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A comparative study on efficiency in the sulfate -added anaerobic landfill site and the semi-aerobic landfill site for the inhibition of methane genration from a landfill site (매립지의 메탄 발생억제를 위한 황산염 첨가형매립지 및 준호기성 매립지의 효율 비교에 대한 연구)

  • 김정권;김부길
    • Journal of Environmental Science International
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    • v.8 no.3
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    • pp.325-330
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    • 1999
  • This study aims to observe the inhibition of methane generation, the decomposition of organic matter, and the trend of outflowing leachate, using the simulated column of the anaerobic sanitary landfill structure of sulfate addition type which is made by adding sulfate to a current anaerobic landfill structure, and the simulated column of semi-aerobic landfill structure in the laboratory which is used in the country like Japan in order to inhibit methane from a landfill site among the gases caused by a global warming these days, and at the same time to promote the decomposition of organic matter, the index of stabilization of landfill site. As a result of this study, it is thought that the ORP(Oxidation Reduction Potential) of the column of semi-aerobic landfill structure gradually represents a weak aerobic condition as time goes by, and that the inside of landfill site is likely to by in progress into anaerobic condition, unless air effectively comes into a semi-aerobic landfill structure in reality as time goes by. In addition, it can be seen that the decomposition of organic matter is promoted according to sulfate reduction in case of $R_1$, a sulfate-added anaerobic sanitary landfill structure, and that the stable decomposition of organic matter in $R_1$ makes a faster progess than $R_2$. Moreover it can be estimated that $R_1$, a sulfate-added anaerobic sanitary landfill structure has an inhibition efficiency of 55% or so, compared with $R_2$, a semi-aerobic landfill structure, in the efficiency of inhibiting methane.

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Effects of electric current on electrocoagulation for optimal harvesting of microalgae for advanced wastewater treatment (하수고도처리용 미세조류의 최적회수를 위한 전기응집기술 적용에 있어 전류의 영향)

  • Lee, SeokMin;Joo, Sung Jin;Choi, Kyoung Jin;Zhang, Shan;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.4
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    • pp.473-478
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    • 2014
  • Microalgae is known as one alternative energy source of the fossil fuel with the small size of $5{\sim}50{\mu}m$ and negative charge. Currently, the cost of microalgae recovery process take a large part, about 20 - 30% of total operating cost. Thus, the microalgae recovery method with low cost is needed. In this study, the optimum current for Scenedesmus dimorphus recovery process using electrocoagulation techniques was investigated. Under the electrical current, Al metal in anode electrode is oxidized to oxidation state of $Al^{3+}$. In the cathode electrode, the water electrolysis generated $OH^-$ which combine with $Al^{3+}$ to produce $Al(OH)_3$. This hydroxide acts as a coagulant to harvest microalgae. Before applying in 1.5 L capacity electrocoagulation reactor, Scenedesmus dimorphus was cultured in 20 L cylindrical reactor to concentration of 1 OD. The microalgae recovery efficiency of electrocoagulation reactor was evaluated under different current conditions from 0.1 ~ 0.3 A. The results show that, the fastest and highest recovery efficiency were achieved at the current or 0.3 A, which the highest energy efficiency was achieved at 0.15 A.

Optimization of Air-plasma and Oxygen-plasma Process for Water Treatment Using Central Composite Design and Response Surface Methodology (중심합성설계와 반응표면분석법을 이용한 수처리용 산소-플라즈마와 공기-플라즈마 공정의 최적화)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.20 no.7
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    • pp.907-917
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    • 2011
  • This study investigated the application of experimental design methodology to optimization of conditions of air-plasma and oxygen-plasma oxidation of N, N-Dimethyl-4-nitrosoaniline (RNO). The reactions of RNO degradation were described as a function of the parameters of voltage ($X_1$), gas flow rate ($X_2$) and initial RNO concentration ($X_3$) and modeled by the use of the central composite design. In pre-test, RNO degradation of the oxygen-plasma was higher than that of the air-plasma though low voltage and gas flow rate. The application of response surface methodology (RSM) yielded the following regression equation, which is an empirical relationship between the RNO removal efficiency and test variables in a coded unit: RNO removal efficiency (%) = $86.06\;+\;5.00X_1\;+\;14.19X_2\;-\;8.08X_3\;+\;3.63X_1X_2\;-\;7.66X_2^2$ (air-plasma); RNO removal efficiency (%) = $88.06\;+\;4.18X_1\;+\;2.25X_2\;-\;4.91X_3\;+\;2.35X_1X_3\;+\;2.66X_1^2\;+\;1.72X_3^2$ (oxygen-plasma). In analysis of the main effect, air flow rate and initial RNO concentration were most important factor on RNO degradation in air-plasma and oxygen-plasma, respectively. Optimized conditions under specified range were obtained for the highest desirability at voltage 152.37 V, 135.49 V voltage and 5.79 L/min, 2.82 L/min gas flow rate and 25.65 mg/L, 34.94 mg/L initial RNO concentration for air-plasma and oxygen-plasma, respectively.

A Study on the Oxygen Consumption Rate and Explosion Energy of Combustible Wood Dust in Confined System - Part I: Quantification of Explosion Energy and Explosive Efficiency (밀폐계 가연성 목재분진의 폭발에너지와 산소소모율에 관한 연구 - Part I: 폭발에너지의 정량화 및 폭발효율)

  • Kim, Yun Seok;Lee, Min Chul;Lee, Keun Won;Rie, Dong Ho
    • Journal of the Korean Society of Safety
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    • v.31 no.4
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    • pp.55-63
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    • 2016
  • A dust explosion is a phenomenon of strong blast wave propagation involving destruction which results from dust pyrolysis and rapid oxidation in a confined space. There has been some research done to find individual explosion characteristics and common physical laws for various dust types. However, there has been insufficient number of studies related to the heat of combustion of materials and the oxygen consumption energy about materials in respect of dust explosion characteristics. The present study focuses on the relationship between dust explosion characteristics of wood dust samples and oxygen consumption energy. Since it is difficult to estimate the weight of suspended dust participating in explosions in dust explosion and mixtures are in fuel-rich conditions concentrations with equivalent ratios exceeding 1, methods for estimating explosion overpressure by applying oxygen consumption energy based on unit volume air at standard atmospheric pressure and temperature are proposed. In this study an oxygen consumption energy model for dust explosion is developed, and by applying this model to TNT equivalent model, initial explosion efficiency was calculated by comparing the results of standardized dust explosion experiments.

Photocatalytic removal of NOx using TiO2-coated zeolite

  • Mendoza, Joseph Albert;Lee, Dong Hoon;Kang, Joo-Hyon
    • Environmental Engineering Research
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    • v.21 no.3
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    • pp.291-296
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    • 2016
  • Application of photocatalytic nanoparticles has been recently gaining an increased attention as air purifying material for sustainable urban development. The present work reports the photocatalytic removal of gaseous phase nitrogen oxides ($NO_x$) using $TiO_2$-coated zeolite to be applied as a filter media for the urban green infrastructure such as raingardens. The $TiO_2$-coated zeolite was synthesized by simple wet chemistry method and tested in a continuous-flow photo-reactor for its removal efficiency of $NO_x$ under different conditions of the weight percentage of $TiO_2$ coated on the zeolite, and gas retention time. The removal efficiency of $NO_x$ in general increased as the weight percentage of $TiO_2$ coated on the zeolite increased up to 15-20%. Greater than 90% of $NO_x$ was removed at a retention time of one minute using the $TiO_2$-coated zeolite ($TiO_2$ weight percentage = 20%). Overall, $TiO_2$-coated zeolite showed greater efficiency of $NO_x$ removal compared to $TiO_2$ powder probably by providing additional reaction sites from the porous structure of zeolite. It was presumed that the degradation of $NO_x$ is attributed to both the physical adsorption and photocatalytic oxidation that could simultaneously occur at the catalyst surface.

Transformation Characteristics of Chlorinated Aliphatic Hydrocarbon (CAH) Mixtures in a Two-Stage Column: 1st Chemical Column Packed with Zinc Natural Ore and 2nd Biological Column Stimulated with Propane-Oxidizing Microorganisms (아연 광석과 프로판산화 미생물을 이용한 이단 고정상 반응기에서의 염소계 지방족 탄화수소 혼합물 분해 특성)

  • Son, Bong-han;Kim, Nam-hee;Hong, Kwang-pyo;Yun, Jun-ki;Lee, Chae-young;Kwon, Soo-youl;Kim, Young
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.723-730
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    • 2007
  • This study was conducted to develop a combined method for remediating a Chlorinated Aliphatic Hydrocarbons (CAHs) mixtures-contaminated aquifer. The process is consist of two processes. A chemical process (1st) using natural zinc ores for reducing higher concentrations of CAH mixtures to the level at which biological process is feasible; and A biological process (2nd) using aerobic cometabolism for treating lower concentration of CAH mixtures (less than 1 mg/L). Natural zinc ore showed relatively high transformation capacity, average dehalogenation percentage, and the best economic efficiency in previously our study. To evaluate the feasibility of the process, we operated two columns in series (that is, chemical and biological columns). In the first column filled with natural zinc ore and sand, CAH mixtures were effectively transformed with more than 95% efficiency, the efficiency depends on the Empty Bed Contact Time (EBCT) and the mass of zinc ore packed. Scanning Electron Microscope (SEM), X-Ray Diffraction (XRD) analysis were performed to make sure whether natural zinc ore played an key role in the dechlorination of the CAH mixtures. The characteristics of zinc metal surface changed after exposure to CAHs due to oxidation of $Zn^0$ to $Zn^{2+}$. In the biological column injecting propane, DO and effluent of the chemical column, only 1,1,1-TCA was cometabolically transformed. Consequently, the combined process would be effective to remediate an aquifer contaminated with high concentrations of CAH mixtures.