• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2000년도 추계학술대회논문집
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• pp.116-119
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• 2000

The advantage of plasma-sprayed coating is their good resistance against thermal shock due to the porous state of the coated layer with a consequently low Youngs modulus. However, the existence of many pores with a bimodal distribution and a laminar structure in the coating reduces coating strength and oxidation protection of the base metals. In order to counteract these problems, there have been many efforts to obtain dense coatings by spraying under low pressure or vacuum and by controlling particle size and morphology of the spraying materials. The aim of the present study is to survey the effects of the HIP treatment between 1100 and 130$0^{\circ}C$ on plasma-sprayed oxide coating of A1$_2$O$_3$, A1$_2$O$_3$-SiO$_2$on the metal substrate (type C18N10T stainless steel). These effects were characterized by phase identification, Vickers hardness measurement, and tensile test before and after HIPing. These results show that high-pressure treatment has an advantage for improving adhesive strength and Vickers hardness of plasma-sprayed coatings.

• 상하수도학회지
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• 제24권6호
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• pp.735-741
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• 2010

A pilot test was carried out to investigate the long term operation characteristics of Microfiltration (MF) system as a pretreatment for seawater reverse osmosis (SWRO) processes for two years. A commercialized MF module with pressurized operation type was used to filter seawater to remove particles which can foul reverse osmosis (RO) membrane. Silt Density Index (SDI) values of filtered seawater by the MF system were ranged from 0.14 to 1.79, which meet the SDI standard for RO feed water as depicted in previous literatures. Although the tested seawater is quite clean (i.e., dissolved organic cabon (DOC) concentration and turbidity were about 1 mg/l and less than 1 NTU, respectively) enough not to foul the MF membrane, steep increase in trans-membrane pressure (TMP) with a constant flux were observed over a whole operation period. A set of operation and water analysis data implies that the steep increase in TMP was resulted from iron and maganese fouling by the combination of metal corrosion by seawater and oxidation state by aeration and residual chlorine.

• 센서학회지
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• 제15권5호
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• pp.371-377
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• 2006

Nano porous, transparent silica aerogels monoliths were prepared under ambient drying (1 atm, $270^{\circ}C$) condition by the combination of sol-gel process and surface modification with subsequent heat treatment. Three kinds of solvent, n-hexane, n-heptane and xylene, were selected in the point view of low surface tension and vapor pressure in order to restrain a formation of cracks during drying. Crack-free silica aerogels with over 93 % of porosity and below $0.14g/cm^3$ of density were obtained by solvent exchange and surface modification under atmosphere condition. Optimum solvent was confirmed n-heptane among these solvents through estimation of FT-IR, TGA, BET and SEM. Modified silica aerogel exhibited a higher porosity and pore size compare to unmodified aerogels. Hydrophobicity was also controled by C-H and H-OH bonding state in the gel structure and heat treatment over $400^{\circ}C$ effects to the hydrophobicity due to oxidation of C-H radicals.

• Structural Engineering and Mechanics
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• 제61권6호
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• pp.693-700
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• 2017

Concrete cover cracking due to the corrosion of steel reinforcing bars is one of the main causes of deterioration in Reinforced Concrete (RC) structures. The oxidation level of the bars causes varying levels of expansion. The rebar expansions could lead to through-thickness cracking of the concrete cover, where depending on the cracking characteristics, the service life of the structures would be affected. In this paper, the effect of geometrical and material parameters, i.e., concrete cover thickness, reinforcing bar diameter, and concrete tensile strength, on the required pressure for concrete cover cracking due to corrosion has been investigated through detailed numerical simulations. ABAQUS finite element software is employed as a modeling platform where the concrete cracking is simulated by means of eXtended Finite Element Method (XFEM). The accuracy of the numerical simulations is verified by comparing the numerical results with experimental data obtained from the literature. Using a previously proposed empirical equation and the numerical model, the time from corrosion initiation to the cover cracking is predicted and then compared to the respective experimental data. Finally, a parametric study is undertaken to determine the optimum ratio of the rebar diameter to the reinforcing bars spacing in order to avoid concrete cover delamination.

• 한국응용과학기술학회지
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• 제30권3호
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• pp.528-539
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• 2013

Biodiesel is one of the most important renewable energy, since it is one of the most important alternative and eco-friendly energy source compared to fossil energy, especially for diesel engineequipped vehicles. It is now coming up for preparation of biodiesel as the alternative that applies the hetrogeneous catalyst, super critical state and various methods used in order to reduce the stages of the processes be converted and separation stages started from oil and fat which are originated from animals and wastes, and those new methods bring eco-friendly as well, though some of those are stand on research step so far. It is necessary that nation provides the tax exemption program for the supplier and strengthen the research system for the farming crops relate to fat and oil. It can improve the development of biodiesel which sustains stability against oxidation and keeps good mobility over the low temperatures in the winter season by new additives and develops new processes to show good harmony with diesel engine.

• 한국주조공학회지
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• 제10권6호
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• pp.528-537
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• 1990

7XXX aluminum alloy powders produced by the self-manufactured rotating disc atomizer were investigated to determine the influence of the atomization parameters on the particle size distributions in air atmosphere. The particle size distributions are almost always bimodal with the dominant mode on the large particle size. Average powder size of 7XXX aluminum alloy is $74/{\mu}m~125/{\mu}m$ when melt is poured with the rate of 9g /sec at 730$^{\circ}C$ on a rotating disc of 30㎜ diameter at 6300rad/sec. The mass of finer particle increased when disc diameter, angular velocity, pouring temperature increased and pouring rate decreased. The powder shapes of bimodal change from acicular to tear-drop and from tear-drop to ligament with increasing powder size. Powder shape was determined by the atomization mechanism and oxidation in liquid state. Microstructure of powders appeared to be cell and cellular dendrite. The SDAS of Al-7.9wt%Zn-2.4wt%Mg-1.5wt%Cu-0.9wt%Ni Powders is $0.8{\mu}m~1.0{\mu}m$ for the powders of $size＋44{\mu}m~53{\mu}m$ and $1.6{\mu}m∼1.8{\mu}m$ for the powders of $size＋105{\mu}m~125{\mu}m$, repectively.

• 한국자기공명학회논문지
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• 제14권2호
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• pp.117-126
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• 2010

Hsp33 is a molecular chaperone achieving a holdase activity upon response to a dual stress by heat and oxidation. Despite several crystal structures available, the activation process is not clearly understood, because the structure inactive Hsp33 as its reduced, zinc-bound, monomeric form has not been solved yet. Thus, we initiated structural investigation of the reduced Hsp33 monomer by NMR. In this study, to overcome the high molecular weight (33 kDa), the protein was triply isotope-[$^{13}C$, $^{15}N$, $^2H$]-labeled and its inactive, monomeric state was ensured. 2D-[$^1H$, $^{15}N$]-TROSY and a series of triple resonance spectra could be successfully obtained on a high-field (900 MHz) NMR machine with a cryoprobe. However, under all of the different conditions tested, the number of resonances observed was significantly less than that expected from the amino acid sequence. Thus, a possible contribution of dynamic conformational exchange leading to a line broadening is suggested that might be important for activation process of Hsp33.

• KIEE International Transactions on Electrophysics and Applications
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• 제3C권2호
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• pp.59-65
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• 2003

Electrical properties such as permittivity and tan$\delta$ of unaged (control) and aged (72 h at 18$0^{\circ}C$) mica/epoxy composites of 130 ${\mu}{\textrm}{m}$ thickness were measured and their surface conditions were characterized using scanning electron microscopy (SEM), Fourier transform infrared (FTIR), electron spectroscopy for chemical analysis (ESCA), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Both permittivity and tan6 of control specimens were higher than those of short-time aged specimens. FTIR results show a new peak at 1710 $cm^{-1}$ / for short-time aged specimens, originating from carbonyl group formed by the oxidation reaction during the aging process. ESCA results show that the binding energy at 532.9 eV representing the singlet state of oxygen ( $O_{1s}$) decreases by 13.7%, whereas that at 534.6 eV increases by 13.7%. Glass transition temperatures of control and short-time aged specimens are observed to be 95.4$^{\circ}C$ and 113.4$^{\circ}C$, which increase with the increase of aging time. TGA results indicate that the control specimens contain a smaller amount of volatile components than the short-time aged specimens.s.

• 암석학회지
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• 제13권1호
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• pp.16-33
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• 2004

자기암석학적인 연구를 화강암에 적용시키기 위해서는 먼저 화강암의 자성 함량, 즉, 대자율에 대한 전반적인 이해와 암석의 화학적인 연구 기반을 바탕으로 화강암의 자기적 특성을 규명해야 한다. 이를 위해서는 자기 암석학적인 연구가 선행되어야 한다. 자성광물특성, 전암의 자기성질, 암석학적 연구, 지화학적 연구와 자기이상 특성을 연구하여 암석에 기록되어 있는 자기특성을 이해함으로서 좀 더 명확한 지질학적인 해석과 자기탐사에서의 지질학적 응용을 증대시킬 수 있다. 그러므로 이 연구에서는 국내의 화강암체들 중 포천, 지포리, 금산, 남원, 속리산, 용담, 태백산 지역, 마산, 진동화강암체 등 시대별, 지구조적으로 서로 다른 화강암들에 대한 대자율을 측정하고 이를 암석화학적 자료들과 비교하였으며 그 결과 암석의 진화경로, 지구조적인 차이, 화강암이 생성되는 암석화학적인 환경, 화강암의 정치심도에 따라 대자율이 반드시 정비례적이지는 않지만 서로간에 상관관계를 보이고 있음을 알 수 있다.

• 한국환경과학회지
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• 제25권4호
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• pp.525-534
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• 2016

The biological wastewater treatment plant, which uses microbial community to remove organic matter and nutrients in wastewater, is known as its nonlinear behavior and uncertainty to operate. Therefore, operation of the biological wastewater treatment process much depends on observation and knowledge of operators. The manual inspection of human operators is essential to manage the process properly, however, it is impossible to detect a fault promptly so that the process can be exposed to improper condition not securing safe effluent quality. Among various process faults, equipment malfunction is critical to maintain normal operational state. To detect equipment faults automatically, the dynamic time warping was tested using on-line oxidation-reduction potential (ORP) and dissolved oxygen (DO) profiles in a sequencing batch reactor (SBR), which is a type of wastewater treatment process. After one cycle profiles of ORP and DO were measured and stored, they were warped to the template profiles which were prepared already and the distance result, accumulated distance (D) values were calculated. If the D values were increased significantly, some kinds of faults could be detected and an alarm could be sent to the operator. By this way, it seems to be possible to make an early detecting of process faults.