• Journal of Korean Society of Environmental Engineers
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• v.35 no.2
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• pp.124-130
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• 2013

Of all the brominated flame retardants (BFRs), TBBPA has the largest production volume (50% of the BFRs in current use). It is interest to investigate how they may degrade, because of it can pose an environmental hazard. By using UV-A (${\lambda}=352nm$ ), we have found that the UV-A irradiation increased the photodecomposition reaction rate of TBBPA in an intensity-dependent manner. We also observed 2,6-dibromo-p-benzosemiquinone radical ($a_{2H}=2.36G$, g = 2.0056) generated from TBBPA by reaction with singlet oxygen ($^1O_2$). On the other hand, when an aqueous preparation of HA was irradiated in the presence of TBBPA, the typical spectrum of semiquinone radical was detected by electron spin resonance (ESR). And then, we have found that the photodecomposition rate of TBBPA is decreased in depend on HA concentration. Radical formation and the reactive rate of TBBPA were inhibited by sodium azide used as a singlet oxygen quencher. Therefore we report that a similar $^1O_2$-induced oxidation can be initiate in aqueous solutions of TBBPA dissolved in humic acid (HA) by the UV-A irradiation (${\lambda}=352nm$). From these results, we suggest that the reaction rate of HA with $^1O_2$ is faster than that of TBBPA with $^1O_2$.

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.1
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• pp.1-7
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• 2014

This paper aims to explain the safety assessment and remediation mechanism of Granulated Coal Ash (GCA) as a material for the remediation of coastal sediments and to evaluate the improvement of the sediment in Kaita Bay, where GCA was applied. The concentrations of heavy metal contained in GCA and the dissolved amounts of heavy metal from GCA satisfied the criteria for soil and water pollution in Japan. The mechanisms on the remediation of coastal sediments using GCA is summarized as follows; (1) removal of phosphate and hydrogen sulfide (2) neutralization of acidic sediment (3) oxidation of reductive sediment (4) increase of water permeability (5) increase of soil strength (6) material for a base of seagrass. From the results obtained from the field experiment carried out in Kaita Bay, it was clarified that GCA is a promizing material for remediation of coastal sediment. This remediation technology can contribute to promote waste reduction in society and to decrease cost of coastal sediment remediation by applying GCA in other polluted coastal areas.

• Economic and Environmental Geology
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• v.42 no.5
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• pp.395-401
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• 2009

The smectite-illite (SI) reaction is a ubiquitous process in siliciclastic sedimentary environments. For the last 4 decades the importance of smectite to illite (S-I) reaction was described in research papers and reports, as the degree of the (S-I) reaction, termed "smectite illitization", is linked to the exploration of hydrocarbons, and geochemical/petrophysical indicators. The S-I transformation has been thought that the reaction, explained either by layer-by-layer mechanism in the solid state or dissolution/reprecipitation process, was entirely abiotic and to require burial, heat, and time to proceed, however few studies have taken into account the bacterial activity. Recent laboratory studies showed evidence suggesting that the structural ferric iron (Fe(III)) in clay minerals can be reduced by microbial activity and the role of microorganisms is to link organic matter oxidation to metal reduction, resulting in the S-I transformation. In abiotic systems, elevated temperatures are typically used in laboratory experiments to accelerate the smectite to illite reaction in order to compensate for a long geological time in nature. However, in biotic systems, bacteria may catalyze the reaction and elevated temperature or prolonged time may not be necessary. Despite the important role of microbe in S-I reaction, factors that control the reaction mechanism are not clearly addressed yet. This paper, therefore, overviews the current status of microbially mediated smectite-to-illite reaction studies and characterization techniques.

• Korean Journal of Environmental Agriculture
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• v.27 no.1
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• pp.86-91
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• 2008

Dicamba(3,6-dichloro-2-methoxybenzoic acid) is used to control for pre and post-emergence of annual and perennial broad-leaf weeds. It is very soluble in water and highly mobile, acidic herbicide. So it is easily moved and detected in groundwater. Zerovalent iron(ZVI) has been used for the reductive degradation of certain compounds through amination of nitro-substituted compounds and dechlorination of chloro-substituted compounds. In this study, we investigated the potential of ZVI for the oxidative degradation of dicamba in water. The degradation rate of dicamba by ZVI was more rapidly increased in pH 3.0 than pH 5.0 solution. The degradation percentage of dicamba was increased with increasing amount of ZVI from 0.05% to 1.0%(w/v) and reached above 90% within 3 hours of reaction. As a result of identification by GC-MS after derivatization with diazomethane, we obtained three degradation products of dicamba by ZVI. They were identified 4-hydroxy dicamba or 5-hydroxy dicamba, 4,5-dihydroxy dicamba and 3,6-dichloro-2-methoxyphenol. 4-Hydroxy dicamba or 5-hydroxy dicamba and 4,5-dihydroxy dicamba are hydroxylation products of dicamba. 3,6-dichloro-2-methoxyphenol is hydroxyl group substituted compound instead of carboxyl group in dicamba. We also confirmed the same degradation products of dicamba in the Fenton reaction which is one of oxidation processes using ferric sulfate and hydrogen peroxide. But we could not find out the dechlorinated degradation products of dicamba by ZVI.

• Korean Journal of Environmental Agriculture
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• v.27 no.1
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• pp.44-49
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• 2008

The purpose of this study is to investigate the current status, including the maintenance problems and removal efficiency, of small sewage treatment facilities in Chung-nam province(Asan, Buyeo, and Gongju city). Our results showed that inflow water quality of Asan city was 19.1 mg/L of BOD, 29.0 mg/L of COD, 13.4 mg/L of T-N and 1.5 mg/L of T-P, respectively, which was much higher than any other site. Among the factors known to be an important index of water quality, the SS and BOD removal efficiency was about 70% and 50% respectively. However, the nitrogen removal efficiency was less than 10%. The total removal efficiency of pollutant was 71.1% of SS, 52.6% of BOD, 46.2% of COD, 9.2% of T-P and 4.6% of T-N respectively. Therefore nitrogen removal processes are required to prevent serious eutrophication of small river. Removal efficiency for BOD and SS of high-efficient sewage treatment facilities (STFs) and contact oxidation process was much higher than another process. Performance of these sewage treatment facilities(STFs) is not optimal due to ineffective planning for the inflow water quality. To improve these facilities, it is proposed that a technical expert analysis of water quality at these facilities is periodically required.

• Journal of Animal Science and Technology
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• v.54 no.4
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• pp.307-313
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• 2012

This study was conducted to investigate the effects of glucomannan (GMN), carrageenan (CAR), carboxymethyl cellulose (CMC), and transglutaminase-B (TGB) on the quality and storage properties of pork patties manufactured with pork skin connective tissue during 21 d of storage at $4^{\circ}C$. Results showed that CIE color values like lightness, redness and yellowness did not differ significantly among the pork patties. Sensory attributes also did not differ between the treatments (P>0.05). However, cooking loss was significantly lower in the group with added GMN, CAR, CMC, and TGB compared to the control at 21 d of storage. The shear force value of GMN and TGB were lower than the control at 21 d of storage (P<0.05). The pork patties added with GMN and TGB had lower thiobarbituric acid reactive substances (TBARS) values than the control at 1 or 21 d of storage (P<0.05). Volatile basic nitrogen (VBN) values of all treatment samples was lower than the control at 21 d of storage (P<0.05). Therefore, result of cooking loss suggested that the decrease in shear force in GMN and TGB were due to higher moisture retention. Also, the pork skin connective tissue with added GMN and TGB decreased lipid oxidation of pork patties.

• Journal of Animal Science and Technology
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• v.49 no.4
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• pp.539-548
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• 2007

The study was carried out to examine combined effects of packaging and electron-beam irradiation on lipid oxidation and meat color of fermented sausages during storage. Fermented and aged sausages were exposed to electron-beam at 2 kGy. The samples were vacuum or aerobic-packaged with the non-irradiated samples at 4±1℃. Regardless of irradiation, the pH values of vacuum-packaged samples was lower than those of aerobic-packaged ones at 14 day (p<0.05). Total microbes and lactic acid bacteria counts significantly decreased during the storage period (p<0.05). And counts of non-irradiated samples were significantly higher than those of irradiated (2 kGy) samples with aerobic packaging. The TBARS values of 2 kGy-irradiated samples were significantly higher than those of non-irradiated samples. The TBARS values of vacuum packaged samples had lower than those of aerobic-packaged ones (p<0.05). Colors (parameters L*, a* and b* values) tended to decrease as the storage period increased. Redness(a*) and yellowness (b*) of 2 kGy irradiated samples were higher than those of non-irradiated ones (p<0.05). In sensory analysis, irradiated (2 kGy) samples with aerobic packaging had higher off-flavor than non-irradiated ones (p<0.05). Therefore, results indicated that irradiation coupled with vacuum packaging may minimize TBARS values of irradiated sausages during storage.

• The Korean Journal of Physiology and Pharmacology
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• v.16 no.3
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• pp.181-186
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• 2012

Fenofibrate is a selective peroxisome proliferator-activated receptor ${\alpha}$ ($PPAR{\alpha}$) activator and is prescribed to treat hyperlipidemia. The mechanism through which $PPAR{\alpha}$ agonists reduce food intake, body weight, and adiposity remains unclear. One explanation for the reduction of food intake is that fenofibrate promotes fatty acid oxidation and increases the production of ketone bodies upon a standard experimental dose of the drug (100~300 mg/kg/day). We observed that low-dose treatment of fenofibrate (30 mg/kg/day), which does not cause significant changes in ketone body synthesis, reduced food intake in Long-Evans Tokushima (LETO) rats. LETO rats are the physiologically normal controls for Otsuka Long-Evans Tokushima Fatty (OLETF) rats, which are obese and cholecystokinin (CCK)-A receptor deficient. We hypothesized that the reduced food intake by fenofibrate-treated LETO rats may be associated with CCK production. To investigate the anorexic effects of fenofibrate in vivo and to determine whether CCK production may be involved, we examined the amount of food intake and CCK production. Fenofibrate-treated OLETF rats did not significantly change their food intake while LETO rats decreased their food intake. Treatment of fenofibrate increased CCK synthesis in the duodenal epithelial cells of both LETO and OLETF rats. The absence of a change in the food intake of OLETF rats, despite the increase in CCK production, may be explained by the absence of CCK-A receptors. Contrary to the OLETF rats, LETO rats, which have normal CCK receptors, presented a decrease in food intake and an increase in CCK production. These results suggest that reduced food intake by fenofibrate treatment may be associated with CCK production.

• Resources Recycling
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• v.14 no.6 s.68
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• pp.3-9
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• 2005

In this study, the separation and recovery of cerium hydroxide was investigated from the wasted cerium polishing powders. Waste cerium polishing powder contains $64.5\;wt\%$ of rare earth oxide and the content of cerium oxide is $36.5\;wt\%$. Since cerium oxide, $56.3\%$ of rare earths, is the most stable state in rare earth, the dissolution of cerium oxide in acid solution is not easy. Therefore the process of rare earth oxide by sulfation and water leaching was examined in order to increase the recovery of rare earth. Rare earth elements were recovered in the form of $\Re{\cdot}Na(SO_{4})_{2}$ by the addition of sodium sulfate to leached solution. The slurry of rare earth hydroxide was prepared by the addition of $\Re{\cdot}Na(SO_{4})_{2}$ to sodium hydroxide solution. After the oxidation of cerous hydroxide($CE(OH)_{3}$) to ceric hydroxide($CE(OH)_{3}$) by aeration, ceric hydroxide was separated from other rare earth hydroxides by controlling the acidity of solution.

• Applied Biological Chemistry
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• v.26 no.2
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• pp.97-103
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• 1983

To get further information on the behavior of phorate(0,0-diethyl S-ethylthiomethyl phosphorodithioate) in soil under the subtropical conditions, a field experiment has been conducted. Phorate granule (10%) was applied to silt loam soil at the rate of 40kg a.i./ha and incorporated to 10cm soil depth. Residues of phorate and its metabolites in soil were determined with GLC and confirmed qualitatively with TLC. Phorate was rapidly oxidized to its sulfoxide and sulfone. Therefore, main metabolic pathway of phorate in soil was the oxidation of phorate to phorate sulfoxide and sulfone. Phorate sulfoxide and sulfone were relatively more persistent than phorate itself. Phoratoxon was detected at low level only up to 30 days after treatment and its sulfoxide and sulfone were not detected during the whole experimental period. Toluene-acetonitrile-nitromethane(40 : 30 : 30, v/v/v) solvent system separated satisfactorily phorate and its five metabolites. Most of the residues was found in the initial incorporation depth $(0{\sim}10cm)$. Consequently, insecticides showed a little downward movement.