• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 하계학술대회 논문집
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• pp.486-486
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• 2009

In this paper, the current-voltage (I-V) curves, such as linear sweep voltammetry (LSV) and cyclic voltammetry (CV), were employed to evaluate the effect of electrolyte concentration on the electrochemical reaction trend. From the I-V curve, the electrochemical states of active, passive, transient and trans-passive could be characterized. And then, we investigated that how this chemical affect the process of voltage-induced material removal in electrochemical mechanical polishing (ECMP) of Copper. The scanning electron microscopy (SEM) and energy dispersive spectroscopy EDS) analyses were used to observe the surface profile. Finally, we monitored the oxidation and reduction process of the Cu surface by the repetition of anodic and cathodic potential from cyclic voltammetry (CV) method in acid- and alkali-based electrolyte. From these analyses, it was important to understand the electrochemical mechanisms of the ECMP technology.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2004년도 학술논문집
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• pp.337-337
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• 2004

As one of researches for the P ＆ T purposes, a basic experiment on the recovery of actinide elements from the mixture with rare earth elements by means of electrorefining using a liquid cadmium cathode in the LiCl-KC1 eutectic melt was carried out. In order to examine the behaviors of electrodeposition of metal ions on a liquid electrode, recovery experiments of rare earth metals resulting from forming electrodeposits were performed by a galvanostatic electrolysis method at various current densities. A cyclic voltammetric technique was applied to determine reduction-oxidation potential of each metal element in the melt and to detect the changes of the multi component melt composition for on-line monitoring. Also, a collaboration study with RIAR was completed to test the preliminary feasibility on a recovery of actinide elements from the mixture with rare earth elements using a liquid cadmium cathode and actinide metals. Experimental results showed that the ratio of actinides to rare earths, 9: 0.5∼1 led to the rare earth content of about 5∼10 wt% in the deposit.

• 한국환경과학회지
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• 제6권6호
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• pp.697-709
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• 1997

Sequencing Batch Reactor(SBR) experiments for organics and nutrients removal have been conducted to find an optimum anaerobic/anoxic/aerobic cycling time and evaluate the applicability of oxidation-reduction potential(ORP) as a process control parameter. In this study, a 61 bench-scale plant was used and fed with night-soil wastewater in K city which contained TCODcr : 10, 680 mg/l, TBm : 6, 893 mg/l, $NH_4^+-N$ : 1, 609 mg/l, $PO_4^{3-}-P$ : 602 mg/l on average. The cycling time In SBRs was adjusted at 12 hours and 24 hours, and then certainly included anaerobic, aerobic and inoxic conditions. Also, for each cycling time, we performed 3 series of experiment simultaneously which was set up 10 days, 20 days and 30 days as SRT From the experimental results, the optimum cycling time for biological nutrient removal with nlght-soil wastewater was respctively 3hrs, 5hrs, 3hrs(anaerobic-aerobic-anoxic), Nitrogen removal efficiency was 77.9%, 77.9%, 81.7% for each SRT, respectively. When external carbon source was fed in the anoxic phase, ORP-bending point indicating nitrate break point appeared clearly and nitrogen removal efficiency increased as 96.5%, 97.1%, 98.9%. Phosphate removal efficiency was 59.8%, 64.571, 68.6% for each SRT. Also, we finded the applicability of ORP as a process control parameter in SBRs.

• Food Science and Biotechnology
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• 제17권5호
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• pp.1010-1015
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• 2008

The effects of heat treatment on the physicochemical properties and mineral composition of sun-dried salt were investigated. The salts parched at high temperature were appeared the higher alkalinity and the lower oxidation-reduction potential (ORP) than the samples without heat treatment. The commercial salts (bamboo salt and yellow loess salt) and the sun-dried salt parched at high temperature had relatively higher sodium ion content (418-450 ppm) compared to that (418.0 ppm) of refined salt. The increase of calcium ion occurred in the salts parched at high temperature compared to the sun-dried salt without heat treatment, but the magnesium ion was vice versa. The commercial salt, yellow loess salt had highest turbidity (0.973) whereas sun-dried salt showed lowest level (0.097) among the tested samples. Turbidity of heat treatment samples decreased as solubility increased. The maximum concentration of dialyzed salt was reached after 4 hr regardless of various processed salts, but those had no difference significantly among the tested samples. The X-ray diffraction patterns of the parched sun-dried salts showed different peak intensity with common salts, and they were similar to the patterns of oxide salts, especially MgO. The maximum value (2.56%) of MgO appeared in the sun-dried salt parched at $1,400^{\circ}C$.

• 공업화학
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• 제17권4호
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• pp.335-342
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• 2006

금속 알루미늄의 낮은 환원전위는 전기화학적 산화반응을 통하여 알루미늄과 그 표면에 존재하는 산화막의 구조 및 성질의 변화를 일으킨다. 산성용액에서 알루미늄을 전기화학적으로 에칭하여 표면적을 확대시키고 중성의 용액에서 알루미늄 표면에 치밀한 유전체 산화막을 형성시켜 커패시터의 전극으로 이용하고 있다. 저온의 산성용액에서는 양극산화시 나노크기의 다공층 산화막이 형성되며, 나노구조체의 템플레이트로 사용되고 있다. 이와같은 알루미늄의 전기화학적 특성은 알루미늄을 새로운 기능성을 가진 재료로 변화시킴으로서 다양한 분야에서 응용될 것으로 기대된다.

• 한국토양비료학회지
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• 제47권6호
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• pp.473-479
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• 2014

In this study, chemical characteristics of groundwater around carcass burial areas and those in agricultural and livestock-farming complex areas in South Korea were monitored. Groundwater samples were collected from 166 wells around carcass burial sites and 466 wells around the agricultural areas where carcass burial sites are absent. The chemical parameters (pH, electrical conductivity, dissolved oxygen, oxidation reduction potential, $NO_3$-N, $NH_4$-N, and $Cl^-$) in carcass burial areas and agricultural areas were similar. The $NO_3$-N concentrations exhibited minimal seasonal fluctuations below $30mg\;L^{-1}$ in most of the wells, even in the wells located close to the carcass burial sites; and $Cl^-$ concentrations also showed similar patterns. The chemical characteristics of groundwater monitored in this study indicated that groundwater was widely contaminated by agricultural activities and livestock farming, but probably not by leachates derived from nearby carcass burial sites.

• 한국산학기술학회논문지
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• 제11권10호
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• pp.4047-4054
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• 2010

실험실 규모의 모사 실험을 통하여 해양 부영양화를 촉진하는 퇴적물의 용출 특성을 연구하였다. 즉 pH, ORP, 질소성분, 인성분 등 주요 환경인자를 분석하고 그에 따른 용출율을 계산하였다. 또한 산소발생제인 과산화칼슘을 이용하여 자연적 용출의 제어효과를 분석하였다. 산소발생제 처리에 따라 호기적 조건으로의 퇴적토 환경변화가 일어났으며 COD, $NH_3$-N의 용출율이 감소하고 질산화 촉진으로 NOx 성분은 증가하였다. 총인과 인산염인도 Ca 이온의 불용화 기작에 의거 감소하였다. 이에 따라 퇴적토의 용출로 인한 해양 부영양화 억제 방법론을 정립하고자한다.

• 상하수도학회지
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• 제32권1호
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• pp.19-25
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• 2018

The objectives of this study were to evaluate the removal characteristics of total nitrogen, the influence factor of denitrification and the optimum operating condition in the pigment wastewater treatment using PAC-A/O process. The operating conditions of PAC-A/O process were mean BOD volumetric loading $0.86kgBOD/m^3/day$, mean F/M ratio 0.072~0.13 kgBOD/kgMLVSS/day and mean C/N ratio 3.47, respectively. The conditions of anoxic process in the field plant test were mean pH 8.3~8.7 and mean temperature $34.1{\sim}44.0^{\circ}C$. The ORP bending point knee was eventually appeared in the ORP -107 mV and $NO_3{^-}-N$ removal efficiency was increased according to the ORP decrease. In the ORP -107 mV below condition, the removal efficiency of T-N and $NO_3{^-}-N$ was 92.3~95.0% and 98.5~99.7%. Denitrification rate was calculated to be 1.581~1.791 mg $NO_3{^-}-N/gMLSS/hr$. The experimental results showed that the ORP control in the PAC-A/O process could be an effective method for treatment of pigment wastewater.

• 한국환경과학회지
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• 제25권4호
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• pp.525-534
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• 2016

The biological wastewater treatment plant, which uses microbial community to remove organic matter and nutrients in wastewater, is known as its nonlinear behavior and uncertainty to operate. Therefore, operation of the biological wastewater treatment process much depends on observation and knowledge of operators. The manual inspection of human operators is essential to manage the process properly, however, it is impossible to detect a fault promptly so that the process can be exposed to improper condition not securing safe effluent quality. Among various process faults, equipment malfunction is critical to maintain normal operational state. To detect equipment faults automatically, the dynamic time warping was tested using on-line oxidation-reduction potential (ORP) and dissolved oxygen (DO) profiles in a sequencing batch reactor (SBR), which is a type of wastewater treatment process. After one cycle profiles of ORP and DO were measured and stored, they were warped to the template profiles which were prepared already and the distance result, accumulated distance (D) values were calculated. If the D values were increased significantly, some kinds of faults could be detected and an alarm could be sent to the operator. By this way, it seems to be possible to make an early detecting of process faults.

• 전기화학회지
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• 제10권3호
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• pp.159-168
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• 2007

An electrochemical study related to the redox characteristics of Ethyl-3-acetyl-6-methyl-1, 4-diphenyl-4, 3a-dihydro-1, 3, 4-triazolino[3, 4-a] pyrimidine-5-carboxylate ester and its derivatives (1a-f) and (2a-e) in nonaqueous solvents such as 1, 2-dichloroethane (DCE), dichloromethane (DCM), acetonitrile (AN), dimethylsulphoxide (DMSO) and tetrahydrofurane (THF) using $0.1\;mol\;dm^{-3}$ tetrabutylammonium perchlorate (TBAP) as a supporting electrolyte at platinum, glassy carbon and gold electrodes, has been performed using cyclic voltammetry (CV). Controlled potential electrolysis (CPE) is also carried out to elucidate the course of different electrochemical reactions through the separation and identification of the intermediates and final electrolysis products. The redox mechanism is suggested and proved. It was found that all the investigated compounds in all solvents are oxidized in a single irreversible one electron donating process following the well known pattern of the EC-mechanism to give a dimer. On the other hand, these compounds are reduced in a single irreversible one electron step to form the anion radical, which is basic enough to proton from the media forming the radical which undergoes tautomerization and then dimerization processes to give also another bis-compound through N-N linkage formation.