• Bulletin of the Korean Chemical Society
• /
• v.31 no.6
• /
• pp.1704-1710
• /
• 2010

The structure of a 2D grid-like copper(II) complex [Cu$(NCO)_2$(pyz)](pyz=pyrazine) (1) consists of 1D chains of Cu-pyz units connected by double end-on (EO) cyanato bridges. Each Cu(II) ion has a distorted octahedral coordination, completed by the four EO cyanato and two pyrazine ligands. Magnetic interactions through EO cyanato and pyrazine bridges in 1 are discussed on the basis of DFT broken-symmetry calculations at the B3LYP level. For model dicopper(II) complexes I (bridged by cyanato) and II (bridged by pyrazine), electronic structure calculations reproduce very well the experimental couplings for the S = 1/2 ferromagnetic and antiferromagnetic exchange-coupled 2D system: the calculated exchange parameters J are +1.25 $cm^{-1}$ and -3.07 $cm^{-1}$ for I and II, respectively. The $\sigma$ orbital interactions between the Cu $x^2-y^2$ magnetic orbitals and the nitrogen lone-pair orbitals of pyrazine are analyzed from the viewpoint of through-bond interaction. The energy splitting of 0.106 eV between two SOMOs indicates that the superexchange interaction should be antiferromagnetic in II. On the other hand, there are no bridging orbitals that efficiently connect the two copper(II) magnetic orbitals in I because the HOMOs of the basal-apical NCO bridge do not play a role in the formation of overlap interaction pathway. The energy separation in the pair of SOMOs of I is calculated to be very small (0.054 eV). This result is consistent with the occurrence of weakly ferromagnetic properties in I.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.53 no.3
• /
• pp.286-292
• /
• 2017

The Coastal VTS will be continuously constructed to prevent marine traffic accidents in the coastal waters of the Republic of Korea. In order to provide the best traffic information service to the ship operator, it is important to understand the navigation risk factor. In this study, we analyzed the navigational hazards of Gunsan coastal area where the coastal VTS will be constructed until 2020. For this purpose, major traffic flows of merchant ships and density of vessels engaged in fishing were analyzed. This study was conducted by Automatic Identification System (AIS) and Vessel Pass (V-PASS) data. The grid intervals are 10 minute ${\times}$ 10 minute (latitude ${\times}$ longitude) based on the section of the sea. A total of 30 sections were analyzed by constructing a grid. As a result of the analysis, the major traffic flows of the merchant vessels in the coastal area of Gunsan were surveyed from north to south toward Incheon, Pyeongtaek, Daesan, Yeosu, Pusan and Ulsan, and from east to west in the port of Gunsan Port, 173-3, 173-6, 173-8, 183-2, 183-5, 183-8, 183-3, 184-1 and 184-2. As a result of the study, the fishing boats in Gunsan coastal area mainly operated in spring and autumn. On the other hand, the main traffic flow of merchant ships and the distribution of fishing vessels continue to overlap from March to June, so special attention should be paid to the control during this period.

• Journal of the Optical Society of Korea
• /
• v.18 no.6
• /
• pp.706-713
• /
• 2014

An enhanced 360-degree integral-floating three-dimensional display system using a hexagonal lens array and a hidden point removal operator is proposed. Only the visible points of the chosen three-dimensional point cloud model are detected by the hidden point removal operator for each rotating step of the anamorphic optics system, and elemental image arrays are generated for the detected visible points from the corresponding viewpoint. Each elemental image of the elemental image array is generated by a hexagonal grid, due to being captured through a hexagonal lens array. The hidden point removal operator eliminates the overlap problem of points in front and behind, and the hexagonal lens array captures the elemental image arrays with more accurate approximation, so in the end the quality of the displayed image is improved. In an experiment, an anamorphic-optics-system-based 360-degree integral-floating display with improved image quality is demonstrated.

• Journal of the Architectural Institute of Korea Planning & Design
• /
• v.36 no.5
• /
• pp.59-70
• /
• 2020

The purpose of this study is to derive the environmental factors affecting child loss through correlation analysis between child loss and pedestrian density. The status of lost children was identified through the lost child records and interviews in large parks. In addition, the behavior survey was conducted by photographing the entire outdoor of each park, and visitors was marked on the behavioral maps. Also, the pedestrian density was analyzed by GIS as 100㎡ and 1㎡ grid. As a result, child loss was related to the pedestrian density rather than the number of visitors or the area. Especially, 'Dynamic pedestrian density' and 'Ratio of pedestrian in high density to area' was related to child loss. In other words, the more dynamic behaviors such as play and movement appear, and the more the local area of high density, the higher the probability of child loss. In addition, environmental factors that induce such high density include bottlenecks, overlap of circulation due to multi-functionality of space, concentration of rides, and concentration of guardians due to visual obstacles.

• Smart Structures and Systems
• /
• v.29 no.1
• /
• pp.1-16
• /
• 2022

Despite recent breakthroughs in deep learning and computer vision fields, the pixel-wise identification of tiny objects in high-resolution images with complex disturbances remains challenging. This study proposes a modified U-net for tiny crack segmentation in real-world steel-box-girder bridges. The modified U-net adopts the common U-net framework and a novel Self-Attention-Self-Adaption (SASA) neuron as the fundamental computing element. The Self-Attention module applies softmax and gate operations to obtain the attention vector. It enables the neuron to focus on the most significant receptive fields when processing large-scale feature maps. The Self-Adaption module consists of a multiplayer perceptron subnet and achieves deeper feature extraction inside a single neuron. For data augmentation, a grid-based crack random elastic deformation (CRED) algorithm is designed to enrich the diversities and irregular shapes of distributed cracks. Grid-based uniform control nodes are first set on both input images and binary labels, random offsets are then employed on these control nodes, and bilinear interpolation is performed for the rest pixels. The proposed SASA neuron and CRED algorithm are simultaneously deployed to train the modified U-net. 200 raw images with a high resolution of 4928 × 3264 are collected, 160 for training and the rest 40 for the test. 512 × 512 patches are generated from the original images by a sliding window with an overlap of 256 as inputs. Results show that the average IoU between the recognized and ground-truth cracks reaches 0.409, which is 29.8% higher than the regular U-net. A five-fold cross-validation study is performed to verify that the proposed method is robust to different training and test images. Ablation experiments further demonstrate the effectiveness of the proposed SASA neuron and CRED algorithm. Promotions of the average IoU individually utilizing the SASA and CRED module add up to the final promotion of the full model, indicating that the SASA and CRED modules contribute to the different stages of model and data in the training process.

• KSII Transactions on Internet and Information Systems (TIIS)
• /
• v.7 no.8
• /
• pp.1890-1910
• /
• 2013

Routing overlay offers an ideal methodology to improve the end-to-end communication performance by deriving a backup path for any node pair. This paper focuses on a challenging issue of selecting a proper backup path to bypass the failures on the default path with high probability for any node pair. For existing backup path selection approaches, our trace-driven evaluation results demonstrate that the backup and default paths for any node pair overlap with high probability and hence usually fail simultaneously. Consequently, such approaches fail to derive a robust backup path that can take over in the presence of failure on the default path. In this paper, we propose a three-phase RBPS approach to identify a proper and robust backup path. It utilizes the traceroute probing approach to obtain the fine-grained topology information, and systematically employs the grid quorum system and the Bloom filter to reduce the resulting communication overhead. Two criteria, delay and fault-tolerant ability on average, of the backup path are proposed to evaluate the performance of our RBPS approach. Extensive trace-driven evaluations show that the fault-tolerant ability of the backup path can be improved by about 60%, while the delay gain ratio concentrated at 14% after replacing existing approaches with ours. Consequently, our approach can derive a more robust and available backup path for any node pair than existing approaches. This is more important than finding a backup path with the lowest delay compared to the default path for any node pair.

• Journal of the Korea Computer Graphics Society
• /
• v.16 no.4
• /
• pp.35-40
• /
• 2010

Due to the distribution of digital camera, many work for photo management has been studied. However, most work use a sequential grid layout which arranges photos considering one criterion of digital photo. This interface makes users have lots of scrolling and concentrate ability when they manage their photos. In this paper, we propose a clustering method based on a temporal sequence considering their color similarity in detail. First we cluster photos using Cooper's event clustering method. Second, we makes more detailed clusters from each clustered photo set, which are clustered temporal clustering before, using maximal clique finding algorithm of interval graph. Finally, we arrange each detailed dusters on a user screen with their overlap keeping their temporal sequence. In order to evaluate our proposed system, we conducted on user studies based on a simple questionnaire.

• Computers and Concrete
• /
• v.23 no.3
• /
• pp.161-170
• /
• 2019

This paper aims at presenting a numerical method for estimating the elastic modulus of recycled concrete with crushed aggregates. In the method, polygonal aggregates following a given sieve curve are generated, and placed into a square simulation element with the aid of the periodic boundary condition and the overlap criterion of two polygonal aggregates. The mesostructure of recycled concrete is reconstructed by embedding an old interfacial transition zone (ITZ) layer inside each recycled aggregate and by coating all the aggregates with a new ITZ layer. The square simulation element is discretized into a regular grid and a representative point is selected from each sub-element. The iterative method is combined with the fast Fourier transform to evaluate the elastic modulus of recycled concrete. After the validity of the numerical method is verified with experimental results, a sensitivity analysis is conducted to evaluate the effects of key factors on the elastic modulus of recycled concrete. Numerical results show that the elastic modulus of recycled concrete increases with the increase of the total aggregate content and the elastic moduli of old and new ITZ but decreases with increasing the replacement ratio of recycled aggregate and the thicknesses of old and new ITZ. It is also shown that, for a replacement ratio of recycled aggregate smaller than 0.3, the elastic modulus of recycled concrete is reduced by no more than 10%.

• Journal of Life Science
• /
• v.28 no.3
• /
• pp.307-313
• /
• 2018

Alopecia cause psychological stress due to their effect on appearance. Thus, the global market size of the alopecia treatment products are growing quickly. Timosaponin A III is the well known active ingredient of Anemarrhenae Rhizoma. In this study, we investigated and compared the binding affinity of timosaponin A III with finasteride (5-beta reductase antagonist) and minoxidil (androgen receptor antagonist) on the target protein active site by in silico computational docking studies. The three dimensional crystallographic structure of 5-beta reductase (PDB ID : 3G1R) and androgen receptor (PDB ID: 4K7A) was obtained from PDB database. In silico computational autodocking analysis was performed using PyRx, Autodock Vina, Discovery Studio Version 4.5, and NX-QuickPharm option based on scoring functions. The timosaponin A III showed optimum binding affinity (docking energy) with 5-beta reductase as -12.20 kcal/mol as compared to the finasteride (-11.70 kcal/mol) and with androgen receptor as -9.00 kcal/mol as compared to the minoxidil (-7.40 kcal/mol). The centroid X, Y, Z grid position of the timosaponin A III on the 5-beta reductase was similar (overlap) to the finasteride, but the X, Y, Z centroid grid of the timosaponin A III on the androgen receptor was significantly far from the minoxidil centroid position. These results significantly indicated that timosaponin A III could be more potent antagonist to the 5-beta reductase and androgen receptor. Therefore, the extract of Anemarrhenae Rhizoma or timosaponin A III containing biomaterials can substitute the finasteride and minoxidil and can be applied to the alopecia protecting product and related industrial fields.

• Journal of the Institute of Electronics and Information Engineers
• /
• v.49 no.12
• /
• pp.56-63
• /
• 2012

The WBAN technology means a short distance wireless network which provides each device interactive communication by connecting devices inside and outside of body. Standardization on the physical layer, data link layer, network layer and application layer is in progress by IEEE 802.15.6 TG BAN. Wireless body area network is usually configured in energy efficient using sensor and zigbee device due to the power limitation and the characteristics of human body. Wireless sensor network consist of sensor field and sink node. Sensor field are composed a lot of sensor node and sink node collect sensing data. Wireless sensor network has capacity of the self constitution by protocol where placed in large area without fixed position. Mobile sink node distribute energy consumption therefore network life time was increased than fixed sink node. The energy efficient is important matter in wireless body area network because energy resource was limited on sensor node. In this paper we proposed cluster topology algorithm for efficient data transmission in wireless body area network based mobile sink. The proposed algorithm show good performance under the advantage of grid routing protocol and TDMA scheduling that minimized overlap area on cluster and reduced amount of data on cluster header in error prone wireless sensor network based on mobile sink.