• 제목/요약/키워드: Out-diffusion

검색결과 1,232건 처리시간 0.024초

전개확산제트화염과 정체점 확산화염과의 유사성 (Similarity between a stagnant point diffusion flame and an evolving jet diffusion flame)

  • 박정;신현동
    • 대한기계학회논문집B
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    • 제21권4호
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    • pp.494-502
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    • 1997
  • Experiments on corresponding jet flames with stagnant point diffusion flames have been carried out in initial injection periods. A compensated measurement of maximum flame temperature, which is based on the ion signal, has been employed to inspect flame responses to time-varying strain rates. The flame responses are obtained at two conditions for the slowly time-varying strain rate and the case of flame extinction, and analyzed to confirm similarity between a stagnant point diffusion flame and an evolving jet diffusion flame. Nonsteady effects are addressed via the comparison between several time scales. The time variation with low strain rates, in which illustrates the flame behavior of the upper branch far from extinction in the well-known S-curve, is confirmed to produce a quasi-steady flame response through the nonsteady experiments. The time variation with strain rates in the case of flame extinction indicates an unsteady effect of flame response. It is therefore found that the flame responses near jet tip depend on time histories of characterized strain rates in the developing process.

Effect of Lateral Diffusion on Hydrogen Permeation Measurement in Thick Steel Specimens

  • Traidia, A.;El-Sherik, A.M.;Attar, H.;Enezi, A.
    • Corrosion Science and Technology
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    • 제16권4호
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    • pp.201-208
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    • 2017
  • A finite element analysis is proposed to study the effect of specimen dimensions on lateral diffusion of hydrogen during hydrogen permeation flux measurements. The error of measurement on thick specimens because of 1D diffusion approximation may be as much as 70%. A critical condition for accurate measurements is to designate the area of hydrogen monitoring/exit surface smaller than the area of hydrogen charging/entry surface. For thin to medium thickness specimens (ratio of thickness to specimen radius of 5:10 and below), the charging surface should be maximized and the monitoring surface should be minimized. In case of relatively thick specimens (ratio of thickness to specimen radius above of 5:10), use of a hydrogen-diffusion barrier on the specimen boundaries is recommended. It would completely eliminate lateral losses of hydrogen, but cannot eliminate the deviation towards 2D diffusion near the side edges. In such a case, the charging surface should be maximized and the monitoring surface should be as closer in dimension as the charging surface. A regression analysis was carried out and an analytical relationship between the maximum measurement error and the specimen dimensions is proposed.

Chloride diffusion study in different types of concrete using finite element method (FEM)

  • Paul, Sajal K.;Chaudhuri, Subrata;Barai, Sudhirkumar V.
    • Advances in concrete construction
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    • 제2권1호
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    • pp.39-56
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    • 2014
  • Corrosion in RCC structures is one of the most important factors that affects the structure's durability and subsequently causes reduction of serviceability. The most severe cause of this corrosion is chloride attack. Hence, to prevent this to happen proper understanding of the chloride penetration into concrete structures is necessary. In this study, first the mechanism of this chloride attack is understood and various parameters affecting the process are identified. Then an FEM modelling is carried out for the chloride diffusion process. The effects of fly ash and slag on the diffusion coefficient and chloride penetration depth in various mixes of concretes are also analyzed through integrating Virtual RCPT Lab and FEM.

역확산화염에서 부상 상태의 진동현상에 관한 연구 (The Periodic Motion of Lifted Flames in Inverse Coflow Jets)

  • 원장혁;서정일;배수호;신현동
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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    • pp.73-78
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    • 2006
  • The lifted oscillating flame has been studied using experiments of inverse diffusion flames that the air jet injected into a methane background. To find out the characteristics of inverse diffusion flames, fundamentally flame stabilized diagram is investigated with various air and fuel jet velocities. It has five regions - flame extinction, stable attached flame, anchored flame, liftoff flame and blow off region. In inverse diffusion flame, lifted flames were observed near the blow off region. As long as flames lift off, flames oscillate by periods. In this oscillating lifted flame region, the frequency of 1 and under were observed in various air and methane jet velocities. Characteristics of lifted flames are also examined by using the ICCD direct image. And intensity of flame chemiluminescence is very different in rising and falling period from photographs. For the present, it is predicted that the changes of flame structure are related with flame oscillation, but more experiments will be needed to make clear the phenomenon.

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Mechanical and metallurgical properties of diffusion bonded AA2024 Al and AZ31B Mg

  • Mahendran, G.;Balasubramanian, V.;Senthilvelan, T.
    • Advances in materials Research
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    • 제1권2호
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    • pp.147-160
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    • 2012
  • In the present study, diffusion bonding was carried out between AZ31B magnesium and AA2024 aluminium in the temperature range of $405^{\circ}C$ to $475^{\circ}C$ for 15 min to 85 min and 5MPa to 20 MPa uniaxial loads was applied. Interface quality of the joints was assessed by microhardness and shear testing. Also, the bonding interfaces were analyzed by means of optical microscopy, scanning electron microscopy, energy dispersive spectrometer and XRD. The maximum bonding and shear strength was obtained at $440^{\circ}C$, 12 MPa and 70 min. The maximum hardness values were obtained from the area next to the interface in magnesium side of the joint. The hardness values were found to decrease with increasing distance from the interface in magnesium side while it remained constant in aluminium side. It was seen that the diffusion transition zone near the interface consists of various phases of $MgAl_2O_4$, $Mg_2SiO_4$ and $Al_2SiO_5$.

Synthesis of p-Type ZnO Thin Film Prepared by As Diffusion Method and Fabrication of ZnO p-n Homojunction

  • Kim, Deok Kyu
    • 한국전기전자재료학회논문지
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    • 제30권6호
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    • pp.372-375
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    • 2017
  • ZnO thin films were deposited by RF magnetron sputtering and then diffused by using an As source in the ampouletube. Also, the ZnO p-n homojunction was made by using As-doped ZnO thin films, and its properties were analyzed. After the As doping, the surface roughness increased, the crystal quality deteriorated, and the full width at half maximum was increased. The As-doped ZnO thin films showed typical p-type properties, and their resistivity was as low as $2.19{\times}10^{-3}{\Omega}cm$, probably because of the in-diffusion from an external As source and out-diffusion from the GaAs substrate. Also, the ZnO p-n junction displayed the typical rectification properties of a p-n junction. Therefore, the As diffusion method is effective for obtaining ZnO films with p-type properties.

Mechanisms of sulfate ionic diffusion in porous cement based composites

  • Gospodinov, P.;Mironova, M.;Kazandjiev, R.
    • Computers and Concrete
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    • 제4권4호
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    • pp.273-284
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    • 2007
  • The paper considers a theoretical model for the study of the process of transfer of sulfate ions in saturated porous media - mineral composites. In its turn, the model treats diffusion of sulfate ions into cement based composites, accounting for simultaneous effects such as filling of micro-capillaries with ions and chemical products and liquid push out of them. The proposed numerical algorithm enables one to account for those simultaneous effects, as well as to model the diffusive behavior of separate sections of the considered volume, such as inert fillers. The cases studied illustrate the capabilities of the proposed model and those of the algorithm developed to study diffusion, considering the specimen complex configuration. Computations show that the theoretical assumptions enable one to qualitatively estimate the experimental evidence and the capabilities of the studied composite. The results found can be used to both assess the sulfate corrosion in saturated systems and predict and estimate damage of structures built of cement-based mineral composites.

Temperature Dependence on Structure and Self-Diffusion of Water: A Molecular Dynamics Simulation Study using SPC/E Model

  • Lee, Song Hi
    • Bulletin of the Korean Chemical Society
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    • 제34권12호
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    • pp.3800-3804
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    • 2013
  • In this study, molecular dynamics simulations of SPC/E (extended simple point charge) model have been carried out in the canonical NVT ensemble over the range of temperatures 300 to 550 K with and without Ewald summation. The quaternion method was used for the rotational motion of the rigid water molecule. Radial distribution functions $g_{OO}(r)$, $g_{OH}(r)$, and $g_{HH}(r)$ and self-diffusion coefficients D for SPC/E water were determined at 300-550 K and compared to experimental data. The temperature dependence on the structural and diffusion properties of SPC/E water was discussed.

침적시험에 의한 콘크리트의 염소이온 확산계수 평가 (A Study on the Chloride Ion Diffusion Coefficient of Concrete by Submergence in Salt Water)

  • 김동석;양승규;정연식;유재상;이종열;본간건일
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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    • pp.297-300
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    • 2003
  • A chloride is an important deteriorating factor which governs the durability of the reinforced-concrete structures under marine environments. Also, the main penetration mechanism of chloride ion into concrete is a diffusion phenomenon. In this study, It is evaluated the diffusion coefficient of chloride ion in non-steady state by Fick's second law. Submergence method in salt water carried out in this experiment. Two types of cement which is different in mineral composition were used. In addition, the effect of mineral admixtures of blast-furnace slag and meta-kaolin was studied. In conclusion, the diffusion coefficient of chloride ion is much affected according to cement type and mineral admixtures, also, it is proved that meta-kaolin as well as blast-furnace slag is effective in preventing penetration of chloride ion.

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축대칭엔진 실린더 내의 유동장에 관한 수치해석적 연구 (Numerical Study on Flow Field in the Cylinder of an Axisymmetric Engine)

  • 김영환;유정열;강신형
    • 대한기계학회논문집
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    • 제17권2호
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    • pp.467-474
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    • 1993
  • Viscous flow and heat transfer phenomena in an axisymmetric cylinder which models a diesel engine have been numerically studied. In order to search for a way to minimize numerical diffusion, the effectiveness and the appropriateness of two selected numerical schemes for convective terms in the governing equations have been tested. They are Linear Upwind Difference Scheme and Hybrid Scheme. Using a standard k-.epsilon. turbulence model, the calculation has been carried out basically up to 180.deg. of crank angle. As a result, it was shown from comparison with previous experimental data that Linear Upwind Difference Scheme is less influenced than Hybrid Scheme by the numerical diffusion and it was suggested that these effects of numerical diffusion can be more significant than those due to turbulence modeling.