• Economic and Environmental Geology
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• v.30 no.1
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• pp.35-49
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• 1997

The coal formation of the Deokpyeong area are interbedded along metapelites of the Ogcheon Supergroup, which are composed mainly of graphite, quartz, muscovite and associated with small amounts of biotite, chlorite, pyrite and barite. The ratios of $SiO_2/Al_2O_3$, $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ of the coaly metapelite are variable and wide range from 1.80 to 10.21, from 27.8 to 388.8 and from 7.6 to 61.8, respectively. These coal formation were deposited in basin of marine environments, and the REE of these rocks are not influenced with metamorphism and hydrothermal alterations on the basis of $Al_2O_3$ versus La, La against Ce, the ratios of La/Ce (0.19 to 0.99) and Th/U (0.02 to 4.75). These rocks also show much variation in $La_N/Yb_N$ (1.19 to 22.89), Th/Yb (0.14 to 21.43) and La/Th (0.44 to 13.67), and their origin is explained by derivation from a mixture of sedimentary and igneous rocks. The wide range in trace and REE element characteristics as Co/Th (0.12 to 2.78), La/Sc (0.33 to 10.18), Sc/Th (0.57 to 5.73), V/Ni (8 to 2347), Cr/V (0.02 to 0.67) and Ni/Co (1.56 to 32.95) of these coaly metapelites argues for inefficient mixing of the various source lithologies during sedimentation. Deep to pale green barium-vanadium muscovites (vanadium-oellacherite) have been found in this coal formations. Modes of occurrence and grain size of muscovite are heterogeneous, but most of the barium and vanadium-bearing muscovites occur along the boundaries between graphite and quartz grains, ranging from 200 to $350{\mu}m$ in length and from 40 to $60{\mu}m$ in width. Results of X-ray diffraction data of the minerals characterized to be monoclinic system with $a=5.249{\AA}$, $b=8.939{\AA}$, $c=20.924{\AA}$ and ${\beta}=95.894^{\circ}$. Representative chemical formula of the muscovite was $(Na_{0.09}K_{1.44}Ba_{0.46})(Al_{2.75}Ti_{0.07}V_{0.56}Fe_{0.08}Mg_{0.50})(Si_{6.12}Al_{1.88})O_{22}$. The V possibly substitute octahedral Al, and the Ba is coupled substitution of $K^+Si^{4+}=Ba^{2+}Na^+Ca^{2+}$, which compositional ranges of V and Ba are from 0.42 to 0.69 and from 0.34 to 0.56 based on $O_{22}$, respectively. Formation mechanism of the barium-vanadium muscovites in the coaly metapelite is shown that the formed by high pressure and temperature from regional metamorphism origanated during diagenesis at the interface between a basinal brine and organic matter.

• The Journal of the Petrological Society of Korea
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• v.13 no.1
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• pp.1-15
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• 2004

In this study we propose that the ‘enclaves’ which occur in the granites should be translated into ‘Po-yu-am’in Korean. Also we suggest some criteria to discriminate the mafic microgranular enclaves (MME) of igneous origin from the xenoliths, which possibly come from the plutonic, volcanic and sedimentary country rocks. The color of the MME is gray green∼dark gray and the mineral grains are fine and equigranular. The MME are generally of ellipsoidal shape and can be easily found within the granites. They do not show any evidence of contact metamorphism by granite host. On the other hand. the xenoliths are generally of angular shape and are of the same mineral assemblage and texture as the country rocks around the granites. The distribution of the xenoliths is mostly concentrated along the intruding plane of the granites near the country rocks. The xenoliths were partly metamorphosed by the granite intrusion. The xenoliths from the plutonic rocks are easily distinguished from the MME in terms of their angular shape and coarser grain size, but they do not have any metamorphic mineral assemblage and texture. The xenoliths from the tuffaceous rocks show angular shape and porphyritic and pyroclastic textures. Large size xenoliths from the sedimentary rocks specifically preserve bedding structure which are indicative of the sedimentary strata. However, the sedimentary xenoliths of small size are often difficult to distinguish from the MME. Metamorphic minerals and texture are a useful key to discriminate the small-sized sedimentary xenoliths from the MME. In summary the xenoliths in the granites can be megascopic ally distinguished from the MME by comparing their color, shape, grain size and remnant original structure like bedding. Additionally the metamorphic mineral assemblage and texture are microscopic discriminators between the xenoliths and the MME in the granites.

• The Journal of the Petrological Society of Korea
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• v.14 no.3 s.41
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• pp.141-148
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• 2005

Lead isotopic compositions are analyzed from the sulfide minerals of the Yeonhwa, Janggun and Uljin deposits and from host limestone, intrusives, and basement rocks to reveal the source of Pb in these deposits. In the $^{206}Pb/^{204}Pb$ vs $^{207}Pb/^{204}Pb$ plot, Galenas from the Yeonhwa mine display relatively well defined positive linear array, similar to the Precambrian basement rocks of the Korean peninsula. A galena sample from the Uljin mine, Janggun limestone and the basement rocks also follow the variation of Yeonhwa mine. However, ore minerals from the Janggun mine, having relatively low $^{206}Pb/^{204}Pb$ values, reveal offset from such trend toward lower $^{207}Pb/^{204}Pb$ values. Considering the fact that Mesozoic igneous rocks and ores within the Gyeongsang basin display considerably lower $^{207}Pb/^{204}Pb$ values than basement rocks of the Korean peninsula, the deviation of Janggun ore minerals can be interpreted as to reflect mixing between leads from old continental crustal materials and from Mesozoic igneous rocks with more mantle signature. The lead of the Yeonhwa and Uljin mine, following trend of Precambrian basement rather well, seems to have been originated mostly from such basement. However, regarding that they occupy low $^{207}Pb/^{204}Pb$ side of the variation trend of the basement, the possibility of having some leads derived from the Mesozoic igneous rocks cannot be excluded.

• Economic and Environmental Geology
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• v.34 no.6
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• pp.555-571
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• 2001

The dynamic evolution of the Chugaryeong fault valley is studied by paleomagnetic works on 163 samples at 16 sites from Late Cretaceous and Quaternary volcanic rocks in the valley. Conglomerate test and stepwised thermal/alternating field demagnetization indicate that all the characteristic directions are of primary origin. Paleomagnetic pole ponsition(216.8$^{\circ}$E/7l .6$^{\circ}$N; dp=7.1$^{\circ}$, dm=10.0$^{\circ}$) for the upper par of the Jijangbong Volcanic Complex Is indistinguishable from the coeval retference pole position from the Gyeongsang Basin, which further substanciates the reliability of the Paleomagnetic data. This indicates the study area has not undergone any tectonic rotation since Late Cretaceous by uy significant reactivation of the Chugaryeong fault valley. The Quaternary pole position (134.2$^{\circ}$E/86.5$^{\circ}$N; $A_{95}$=7.1 $^{\circ}$) from the Jeongog Basalt reflects the present geocentric axial dipole field for the area, supporting the above conclusion. Unlike the upper part, paleomasnelic directions of the lower part of the Jijangbong Volcanic Complex show random distrinution between sites. We interpret that the early stage of the volcanic activity was created by sinistral strike slip motion of the Chugaryeong fault during early Late Cretaceous. The creation and evolution of the Chugaryeong fault valley emphasize the significance of the kinematic FR (folding ruler) model in east Asia.

• Journal of the Korean earth science society
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• v.37 no.4
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• pp.211-217
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• 2016

There have been found mine tailings, wastes, and mining drainage scattered in the area of Nakdong River due to the improper maintenance of the abandoned mines. These contaminants can flow into rivers during the heavy rain periods in summer. Along the study area beginning Seokpo-myeon, Bonghwa-gun of Gyeongsangbuk-do untill Dosan-myeon, Andong-si, there are one hundred five mines including sixty metalliferous mines and forty-five nonmetal mines, which can adversely affect the adjacent rivers. To verify the contamination, we collected sediments, seepage water and surface water for a year both in rainy season and dry season. This study found that sediments, containing high concentrations of heavy metals caused by mining activities, are dispersed throughout the entire river basin (68 sample points with pollution index, based on the concentration of trace element, (PI) >10 among the total of 101 samples). The results of river water analysis indicated the increased concentrations of arsenic and cadmium at branches from Seungbu, Sambo, Okbang and Janggun mine, which concerns that the river water may be contaminated by mining drainage and tailing sediments. However, it is difficult to sort out the exact sources of contamination in sediments and waters only by using the chemical compositions. Thus the control of mining pollution is challenging. To prevent water from being contaminated by mining activities, we should be able to divide inflow rates from each origin of the mines. Therefore, there should be a continued study about how to trace the source of contaminants from mining activities by analyzing stable isotopes.

• The Journal of the Petrological Society of Korea
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• v.18 no.2
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• pp.137-151
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• 2009

Synthetic analyses of field data, including rock facies, contact relationships, petrography, structural elements, and etc., and previous geochemical and absolute age data of the Tertiary Churyeong Breccia and its surrounding volcanics in the Gyeongju city, Korea, have led to the following results. (1) The Tertiary rocks are divided into the dacitic tuffs, Churyeong Breccia, and andesitic rocks in ascending order. The dacitic tuffs are unconformably overlain by the Churyeong Breccia which is intruded by or conformably overlain by the andesitic rocks. (2) The dacitic tuffs are correlated with the Paleocene${\sim}$Eocene Wangsan dacitic volcanics, while the Churyeong Breccia and andesitic rocks are correlated with the early Early Miocene Andongri Formation and Yongdongri Tuffs in the Waeup Basin, respectively. (3) The Churyeong Breccia accumulated rapidly in the NE-trending graben about 1.5 km in width during the crustal extension in the NW-SE direction due to the East Sea opening. (4) Dacitic${\sim}$andesitic volcanism and crustal extension were active during the early Early Miocene times in SE Korean peninsula. During the deposition the Churyeong Breccia, especially, the volcanism ceased for some time, but the active normal faulting led to the formation of grabens in places.

• The Journal of the Petrological Society of Korea
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• v.9 no.2
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• pp.70-83
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• 2000

The purpose of this study is to identify the petrographic and geochemical characteristics of four granitic masses and clanfy for the origin and relationship among the masses. These granitic rocks are distributed in the eastern part of Yangsan fault in the Kyongsang basin, southeastern part of Korea. Based on the mineralogy and texture, the granitic rocks are divided into three facies; granodiorite, porphyritic fine-grained granite, and equigranular granite. According to the result of modal analysis, northern part and most of the southern part of Daebon granitic rocks are plotted in granodiorite field and the rest part of the xocks are plotted in granite field. These granitic rocks belong to the sub-alkaline series, and are subdivided into calc-alkaline series. The rare earth elements normalized bv chondrite show LREE is more enriched than HREE and the lowest values in O-w m- i t e and Daebon equigranular granite. The crystallization pressures and temperatures of minimum melt compositions of granitic rocks estimated from the study area are about 0.5-1 kbar and $700~820^{\circ}C$, respectively. Referring to the petrographic characteristics, geochemical data and radiogenic age data, Oyu granite was emplaced in the Paleocene, but Daebon granodiorite, Sanseo porphyritic granite, and Hoam equigranular granite are co-magmatic differentiation products, were emplaced in the Eocene.

• The Journal of the Petrological Society of Korea
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• v.17 no.1
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• pp.36-43
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• 2008

Many plutonic rock fragments of granitic composition were collected from the Deception Island. We obtained K-Ar ages of $62.5{\pm}1.2\;Ma$ and $140.7{\pm}2.7\;Ma$ from the two samples. Such result contradicts the general belief that most of the volcanic rocks of Deception Island are products of very recent activities and their maximum age does not exceed 200 ka. On the other hand, Mesozoic to Cenozoic rocks produced by subduction-related active magmatism have been reported from both South Shetland Islands and Antarctic Peninsula, located to the north and south of the Deception Island respectively. Also, various kinds of plutonic rocks with granitic composition are distributed widely. Therefore, plutonic rock fragments with granitic composition discovered from the Deception Island seem to indicate their derivation by capturing granitic crustal material underlying volcanic edifice during the volcanic activities, instead of differentiation from magmas related with recent volcanism. Ages and rock types of the plutonic rock fragments suggest arc-related origin just as adjacent South Shetland Islands and Antarctic Peninasula.

• Economic and Environmental Geology
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• v.34 no.6
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• pp.539-553
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• 2001

Geochemical data of the Han river water, including four tributary water samples in the main Han river are presented in this paper. The concentration of dissolved ions in the North Han river water decreases in order of Ca>Na>K>Mg and HCO$_3$>NO$_3$>SO$_4$>Cl, which it mainly affected by the chemical weathering of granite and gneiss in the drainage basin. Meanwhile, the South Han river water shows a decreasing order of Ca>Mg>Na>K and HCO$_3$>SO$_4$>NO$_3$>Cl, which is controlled by the bed rock geology of carbornate rooks and the inflow of acid mine drainage from the metal and coal mines in the Taebaegsan and Hwanggangri areas. The main Han river waters are characterized by unusually high concentration of Na, Cl and SO$_4$ (Ca>Na>K>Mg and HCO$_3$>SO$_4$>CI>NO), indicating a significant anthropogenic pollution by human activities in the metropolitan Seoul city. The geochemical data of the Han river waters from 1981 through 1996 to 1999 records a significant increase in SO$_4$ and NO$_3$, which responsible for the increasing arid mane drainage and municipal anthropogenic pollution.

• Analytical Science and Technology
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• v.15 no.6
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• pp.556-566
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• 2002

Gunpo city, a medium sized city formed with a basin is populated with a little more than 270,000 peoples and includes the industrial area with about 600 factories. It has been recognized for a long time that peoples living nearby industrial area have complained on serious air contamination due to the geographical and environmental factors. This study was performed on measurement of volatile organic compounds (VOCs) and malodor for the air sampled in various places of Gunpo city, and made comparison with VOCs levels in specific area of Seoul. This work would play important role for the efficient management of air contamination of Gunpo city. Samplings were done in the rooftop of eleven village office buildings including Gunpo station in June 12th, 2001. Analytical results indicate that VOCs levels of Gunpo-1-dong, Gunpo station and Kumjungdong regions neighboring industrial area were much higher than the rest of areas, and this fact shows that the origin for air contamination of Gunpo would be industrial area than car exhaustion gases.