• 한국물환경학회지
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• 제28권3호
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• pp.479-482
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• 2012

Membrane process has been one of the widely applied wastewater treatment options, especially in field. However, one of the tricky issues in the process is to treat concentrates generated from reverse osmosis (RO) system in a manner of saving cost with maximum efficiency for treating a wide range of contaminants. Stimulated with the challenging issues, we have conducted a series of experimental studies in the evaluation for removing organics and nutrients using activated carbon. Results indicated that while powdered activated carbon (PAC) efficiently removed organics and the extent of removal was proportional to the PAC dosage, little removal of nitrogen and phosphorus was observed despite increasing the PAC dose. Interestingly, applying PAC was superior in removing organics than using granular activated carbon (GAC). These results suggest smaller particle size with higher surface area could provide greater chemical reactivity in removing organics.

• 상하수도학회지
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• 제14권1호
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• pp.37-44
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• 2000

Laboratory experiments were conducted to investigate the performances of anaerobic filters packed with ceramic tube and pall-ring media treating a dairy waste. The media packing volume was 65% of effective volume of anaerobic filter. Organics removals of anaerobic filters were maintained above 80% even at an organics loading rate of $10kgCOD/m^3/d$, and this was comparable to aerobic treatment of organic wastes. Organics removals of the ceramic tube anaerobic filters were always lower than those of the pall-ring anaerobic filters due to intrinsic physical property of ceramic tube, especially lower void space which caused to clogging and entrapment of biogas, substrate transfer limitation, and irregular evolution of biogas leading to loss of solids and biomass. This was clearly observed in higher concentration of TSS in the effluent from the ceramic tube anaerobic filter despite of higher retention capacity of TSS compared with pall-ring media. Vertical distribution of organics and solids in the filters showed above 90% of organics and solids in influent were removed below 20% of reactor height, and 50% of remaining organics and solids were removed though media packing zone. Effluent quality from the anaerobic filter was heavily depended on media itself as well as suspended biomass formed below media. It is therefore concluded that the type of media played an important role in biomass accumulation arid gas-liquid-solid separation efficiency. Type of media did not affect the start-up behaviors of the anaerobic filter, and supernatant from anaerobic digested sludge showed a good performance as a seeding materials.

• 한국막학회:학술대회논문집
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• 한국막학회 1998년도 춘계 총회 및 학술발표회
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• pp.83-86
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• 1998

1. Introduction : Low molecular harmful organics such as 1-naphthol and phenol are widely used in industries, and pose serious environmental problems. Wastewater containing low molecular harmful organics may be ejected from various sources including metal-plating industries, circuit-board manufacturing process, photographic and photo-processing industries, refineries and metal-tailing leachate. The pollution of nation harbors, waterways and ground water resources with these organics has reached critical portions, and might also give hazardous influence on human health. Micellar enhanced ultrafiltration(MEUF) is a recently developed process to remove dissolved organics and/or heavy metals present in small or trace quantities from aqueous solution. In this system, the fatal defect is leakage of surfactants especially at low concentration below CMC(critical micelle concentration), which becomes a secondary pollution. Our group proposed to use biosurfactant and polymeric micelle to solve problems mentioned above. In this study we investigated a modified MEUF using PEO-PPO-PEO (polyethyleneoxide-polypropyleneoxide-polyethyleneoxide) block copolymers for the removal of organic solutes such as 1-naphthol and phenol from aqueous wastewater. We proposed PEO-PPO-PEO block copolymers as new surfactants for forming micelles in MEUF, and investigated the solubilization characteristics and efficiency for the removal of 1-naphthol and phenol. PEO-PPO-PEO block copolymers are, environmentally mild and safe as biosurfactants.

• KSBB Journal
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• 제16권2호
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• pp.140-145
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• 2001

To treat piggery wastewater containing refractory compounds including nitrogen, physical treatments using zeolite and biological processes were investigated. In biogical treatment, the removal efficiencies of organics and nitrogen in bioreador using BACC (Biological Activated Carbon Cartridge) media filled with granule activated carbon were examined. The best removal efficiencies achieved for TKN and COD(sub)cr were 82% and 53% respectively, when zeolite dosage was 300 g/L. Specific nitrogen removal ability was 3.2 mg/g at a zeolite dosage of 50 g/L, whereas specific nitrogen removal ability was 1.8 mg/g at a zeolite dosage of 300 g/L. The increased of C/N ratio resulting from the removal of nitrogen using zeolite led to an increase in removal efficiency of organics. As C/N ratio was increased to 2.0, 2.44 and 6.58 at a HRT of 48 hours in a BACC bioreactor, removal efficiencies of COD(sub)cr were increased to 53.5%, 57.4% and 80.6%. The removal efficiency of wastewater using a zeolite dosage of 399 g/L was increased by 27.1% compared to that of control treatment.

• 공업화학
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• 제32권1호
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• pp.97-101
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• 2021

스코리아와 활성탄의 혼합 충전탑에서 중금속과 유기물의 흡착 특성, 스코리아의 물리화학적 특성과 관능기를 조사하였다. 스코리아의 혼합비율이 증가할수록 카드뮴, 니켈, 크롬, 납 이온의 평균제거율은 증가하였으나, 벤젠과 톨루엔의 평균 제거율은 감소하였다. 스코리아와 활성탄의 혼합 충전탑은 중금속과 유기물의 동시 제거에 효과적으로 사용될 수 있었다. 스코리아는 Si-H와 Si-O 작용기를 갖고 있으며, 이중 Si-O 관능기가 중금속의 흡착에 크게 기여함을 확인할 수 있었다.

• 한국환경과학회지
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• 제8권3호
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• pp.337-347
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• 1999

This study was carried out to evaluate the characteristics of dissolved organics based on their origins, which were divided into two categories. The first group consisted of river, lake and secondary sewage treatment effluent, which were chosen as representative of their origins. The second group were artificial samples which were made of AHA(Aldrich humic acids) and WHA(Wako humic acids). Physicochemical characteristics, biological degradability and THMEP(trihalomethane formation potential) of the samples were analysed based on the AMWD(apparent molecular weight distribution). Large portion of dissolved organic carbon(DOC) in the river and lake samples was comprised of LMW(low molecular weight), which that of AHA and WHA was HMW(high molecular weight). The DOC of the lake was evenly distributed in the all range of molecular weight. The river, lake and secondary treated effluent have lower ultraviolet(UV) absorbance at 254nm, and have a higher amount of humic acids. Higher absorbance of humic acids means that aliphatic bond and benzenoid type components that absorb UV light were contained in these kind of humic acids. It was expected that lake sample was the most biodegradable in the different samples investigated, and in order of secondary sewage treatment effluent, river, WHA and AHA based on the result of determination of specific ultraviolet absorbance(SUVA). Biodegradability showed similar result except for AHA, while dissolved organics in the range of LMW decreased during the biodegradability test, and on the contrary those of HMW increased. Production of the SMPs(soluble micobial products) was observed during humicfication of dissolved organics and the SMPs were higher production of the SMPs. THM formation was high in the samples containing HMW and similar tendency was shown in the THMEP(trihalomethane formation potential), except for WHA.

• 한국세라믹학회지
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• 제41권1호
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• pp.41-44
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• 2004

층상구조를 갖는 점토광물은 층상의 이온교환자리에 친소수성 유기물을 화학적으로 치환할 수 있어 도자기 소지의 친소수성 정도를 조절할 수 있다. 본 연구에서는 Montmorillonite를 이온교환법으로 dodecylamine, hexadecylamine과 반응시켜 유기물이 점토광물에 복합화된 유기-점토 복합체를 조조하였다. 유기물이 점토광물 구조에 치환된 위치 및 층상구조의 간격변화는 FT-IR과 WAXD로, 수식된 유기물의 양은 TG-DSC, C/S 기기를 사용하여 조사하였다. 분석을 통하여 유기물은 층상에 선택적으로 치환하여 층간격을 증가 (12${\AA}{\leftrightarro}16{\AA}$) 시키는 역할을 하였고, 비교적 친수성을 보이는 MMT가 첨가된 가소제로 인하여 소수성으로 변하고 있음을 발견하였다.

• 환경위생공학
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• 제6권1호
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• pp.103-108
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• 1991

Visibility studies are conducted in oxidizing organic compounds with ozone to investigate the oxidation in the waste and sewage water. While the ozone has been used as one of the major oxidation of the waste and sewage water, it is not effective to distroy the polluted organic compounds with the practical concentration in waste water treatment. The result are shown follows ; 1. Upon oxidizing organic compound with ozone, the former is much oxidized under three meters and the latter under the ABS waste water. 2. In case of being oxidized organics waste water with ozone codis, much removed under medicine and chemical waste water than anothers of primary treatment process. 3. The final treated waste water of oxidizing organics is higher than that of filtered water or sedimented water. Specially in organics waste water the colority after oxidizing decrease from 95% to 99.9% this suggests that any organic compounds produced during ozonation night be dissdved in the final treated waste water.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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• pp.76-77
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• 2009

In this paper, We have studied Electron Transport Layer(ETL) in the New Organics applied to Red phosphorescent organic light-emitting devices. The structure of ITO/2-TNATA(15nm)/CBP;$Ir(piq)_3$/DPVBi(30nm)/New ETL(60nm)/LiF(0.5nm)/Al(100nm) has been used, measured changing doping concentration of EML. The results of OLED turn-on voltage at 2.2V, and Maximum Luminance at 2.8V was $1000cd/m^2$. This high luminance at low voltage results from a high electron. conduction of the new electron transport layer.

• 아시안잔디학회지
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• 제10권2호
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• pp.143-150
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• 1996

The removal rates of gross production and organic matters were investigated in the Lake Paldangho. In 1995 and 1996, soils and litter sarraples were collected and annual mean production and removal rates were calculated. Communities in the Lake Paldangho were Phragrnites communis, Miscanthus sacchariflorus, Typha aegustata and Scirpas tahernaemoutani. Removal constants of aquatic plant communities estimated by the mathematical theoretical models, were 0.826, 0.567, 0.571 and 0.751, respectively. The durations of reaching half of initial organic amounts were 0.839 yeras, 1.221 years, 1.213 years and 0.922 years respectively at the steady state of removal and accumulation for organics For organics, the rapidity of removal were more speedy P. communis, S.tahernaemontani, T. augustata, M sacehariflorus in order. The times needed for 99% removal were 6.051 years, 6.651 years, 8.752 years and 8.811 years, respectively. Key wotds:Gross production, Organic matters, Lake Paldangho, Phragmites communis, Mis-ca ethus sacchariflorus, Typha angustata, Scirpus tahernaemoutani., Removal constants.