• 제목/요약/키워드: Organic-inorganic hybrid composite

검색결과 34건 처리시간 0.032초

Barrier property Enhancement of Plastic Substrates for Flexible Display by Inorganic-organic Hybrid Multilayer

  • Kim, Hyun-Gi;Ryu, Hyun-Sun;Kim, Sung-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.617-619
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    • 2008
  • Inorganic-organic hybrid multilayers were formed on the plastic substrate to enhance the barrier properties of substrate to water vapor and oxygen transport. Plasma pretreatment of substrate with $Ar/O_2$ lead to adhesion improvement and the densification of inorganic layer on the substrates. Combination of $SiO_xN_y$ layer and silanenanoclay composite layer offered quite good barrier properties (WVTR and OTR) to PES substrate.

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PVdF/SPEEK/$TiO_2$ 하이브리드 막의 프로톤 전도도 및 메탄올 전이현상 (Proton Conductivity and Methanol Transport Behaviour of PVdF/SPEEK/$TiO_2$ Hybrid Membrane)

  • 유선경;;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.409-411
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    • 2005
  • A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxidenanoparticles content. Their water uptake, methanol permeability and proton conductivity as a function of inorganic oxide content were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and water swelling. It is also found that increase in inorganic oxide content leads to decrease of methanol permeability. In terms of the morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with the standard nation membrane.

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Titanium Dioxide Nanoparticles filled Sulfonated Poly(ether ether ketone) Proton Conducting Nanocomposites Membranes for Fuel Cell

  • Kalappa, Prashantha;Hong, Chang-Eui;Kim, Sung-Kwan;Lee, Joong-Hee
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2005년도 추계학술발표대회 논문집
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    • pp.87-90
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    • 2005
  • This paper presents an evaluation of the effect of titanium dioxide nanoparticles in sulfonated poly(ether ether ketone) (SPEEK) with sulfonation degree of 57%. A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxide nanoparticles content. Their water uptake, methanol permeability and proton conductivity as a function of temperature were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and water swelling. It is also found that increase in inorganic oxide content leads to decrease of methanol permeability. In terms of morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with standard nafion membrane.

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PVdF/SPEEK/TiO2 하이브리드 막의 수분함량과 메탄올 전이현상 (Water Swelling and Methanol Transport Behaviour of $PVdF/SPEEK/TiO_2$ Hybrid Membrane)

  • 유선경;김한주;박수길;김영재
    • 한국전기화학회:학술대회논문집
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    • 한국전기화학회 2005년도 수소연료전지공동심포지움 2005논문집
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    • pp.233-240
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    • 2005
  • A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxidenanoparticles content. Their water uptake, methanol permeability and proton conductivity as a function of inoranic oxide content were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and water swelling. It is also found that increase In inorganic oxide content leads to decrease of methanol permeability. In terms of the morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with the standard nafion membrane.

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DMFC용 $PVdF/SPEEK/TiO_2$ 하이브리드 막의 수분함량과 메탄올 전이현상 (Liquid uptake and Methanol Transport Behaviour of $PVdF/SPEEK/TiO_2$ Hybrid Membrane for DMFC)

  • 유선경;김한주;김영재;박수길
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.194-196
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    • 2005
  • A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxidenanoparticles content. Their liquid uptake, methanol permeability and proton conductivity as a function of inoranic oxide content were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and liquid uptake. It is also found that increase in inorganic oxide content leads to decrease of methanol permeability. In terms of the morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with the standard nafion membrane.

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하이브리드 절연필름의 전동기권선 적용 특성 연구 (Technology and Application of Hybrid Insulation Film for Electric Magnet Wire)

  • 한세원;한동희;강동필
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.210-211
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    • 2006
  • This study presents the technology and application of hybrid insulation film for electric magnet wire. In order to make the high efficient motor with high space factor, it is necessary to develop a self-lubrication heat-resistant insulation film that can be used when the space factor 70% or more. A key to achieving high windability is to increase the lubricity and bonding strength of vanish, which for a magnet wire generally determines the mechanical scratches characteristics. Effective ways to reduce scratches include improving insulation film prepared by organic and inorganic hybrid synthesis methods.

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Ordered Hybrid Nanomaterials from Self-Assembled Polymeric Building Blocks

  • Kim, Dong-Ha
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.309-309
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    • 2006
  • Latest developments on hybrid nanostructured materials fabricated by applying self-assembly strategies on organic/inorganic nanotemplates are discussed. Within this frame, numerous functional nanomaterials including arrays of composite metal/semiconductor nanoparticles, planar waveguides and functional multilayer thin films are generated using self-assembled polymers as templates or building blocks. In particular, surface plasmon resonance based optical sensing is employed to investigate nanofabrication processes occurring in nanoscale dimention. We also suggest unprecedented pathways to hybrid supramolecular multilayer nanoarchitectures in 1D or 2D geometry via layer-by-layer self-assembly.

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ORGANIC - INORGANIC COMPOSITE MEMBRANE FOR POLYMER ELECTROLYTE MEMBRANE FUEL CELL

  • Shul, Yong-Gun;Kim, Hyun-Jong;Ahn, Ji-Eun;Han, Hak-Soo
    • 한국막학회:학술대회논문집
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    • 한국막학회 2003년도 The 4th Korea-Italy Workshop
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    • pp.37-40
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    • 2003
  • Mesoporous zeolite - heteropolyacid-polymer hybrid membrane was prepared by sol-gel processes to make a proton conducting membrane. The crystallinity of mesoporous zeolite in composite membrane was increased with contents of heteropolyacid. Proton conductivity obtained from impedance measurements increases with contents of heteropolyacid, about 10$^{-3}$ S/cm in ca. 1.5 Wt% heteropolyacid.

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DMFC용 PVDF/SPEEK/TiO2 하이브리드 막의 수분함량과 메탄올 전이현상 (Liquid Uptake and Methanol Transport Behaviour of PVDF/SPEEK/TiO2 Hybrid Membrane for DMFC)

  • 유선경;김한주;박수길
    • 전기화학회지
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    • 제8권4호
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    • pp.177-180
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    • 2005
  • 유 무기 혼성 막의 계열은 티타니움 디옥사이드 나노파티클 함량의 체계적인 변화에 의해 조제된다. 유 무기 혼성 막의 수분함량, 메탄올 투과도와 전자 전도 특성은 무기 산화물의 함량의 기능에 따라 연구된다. 그 결과 망상구조의 무기 산화물은 전자 전도 특성과 수분함량의 감소를 보였다. 또한 무기 산화물의 함량이 증가할수록 메탄올 투과도도 감소함을 나타내었다. 형태학적인 관점에서 막은 폴리머 기반과 무기영역 사이에 균일하고 잘 점착됨을 보여준다. 혼성막의 특성은 나피온막과 비교 실험되었다.

Preparation and Characterization of Sol-Gel Derived $SiO_2-TiO_2$ -PDMS Composite Films

  • 황진명;여창선;김유항
    • Bulletin of the Korean Chemical Society
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    • 제22권12호
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    • pp.1366-1370
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    • 2001
  • Thin films of the SiO2-TiO2-PDMS composite material have been prepared by the sol-gel dip coating method. Acid catalyzed solutions of tetraethoxy silane (TEOS) and polydimethyl siloxane (PDMS) mixed with titanium isopropoxide Ti(OiPr) were used as precursors. The optical and structural properties of the organically modified 70SiO2-30TiO2 composite films have been investigated with Fourier Transform Infrared Spectroscopy (FT-IR), UV-Visible Spectroscopy (UV-Vis), Differential Thermal Analysis (DTA) and prism coupling technique. The films coated on the soda-lime-silicate glass exhibit 450-750 nm thickness, 1.56-1.68 refractive index and 88-94% transmittance depending on the experimental parameters such as amount of PDMS, thermal treatment and heating rate. The optical loss of prepared composite film was measured to be about 0.34 dB/cm.