• 제목/요약/키워드: Organic wax

검색결과 27건 처리시간 0.464초

Powder Injection Molding of Alumina Parts Using a Binder System Based in Paraffin Wax and High Density Polyethylene

  • Thomas-Vielma, P.;Cervera, A.;Levenfeld, B.;Varez, A.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.207-208
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    • 2006
  • In this experimental work, the development of a multicomponent binder system based on high density polyethylene (HDPE) and paraffin wax for Powder Injection Molding of Alumina $(Al_2O_3)$ parts was carried out. The optimum composition of the injection mixture was established through mixing torque measurements and a rheological study. The maximum powder loading was 58 vol%. The miscibility of organic components and the optimum injection temperature was evaluated by thermal characterization of binder and feedstock. The thermal debinding cycle was developed on the basis of thermogravimetrical analysis of the binder. After sintering the densities achieved were closed to 98% of the theoretical one.

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밀랍주조법을 활용한 청동반가사유상 복원 연구 (Experimental Research of Lost-wax Casting: Gilt-Bronze Pensive Bodhisattva)

  • 윤용현;조남철;도정만
    • 보존과학회지
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    • 제36권2호
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    • pp.123-142
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    • 2020
  • 고문헌 조사를 토대로 밀랍주조법을 이용한 사전실험, 재현실험을 통해 청동반가사유상의 복원 연구를 실시하였다. 복원대상은 국보 제83호 금동미륵보살반가사유상으로, 이에 대한 과학적 분석결과를 바탕으로 합금비, 주조방법 등을 설정하였다. 사전실험에서 합금비는 구리:주석:납=95.5:4.0:0.5로 설정하였으나, 본실험에서는 기화량을 감안하여 납과 주석을 각각 2.5%씩 증량하여 장입하였다. 밀랍주조법을 적용하였으며, 본실험에서는 밀랍 경도 실험을 실시하여 송진 30%를 투입하였을 때 적정 강도를 가짐을 알 수 있었다. 미세조직은 일반적인 주조조직(α-Cu, δ)이 확인되었고, 성분분석 결과 선행연구와 유사한 양상을 나타내었다. 거푸집 분석결과, 구조적 안정성과 내화성을 위해 석영 비짐을 넣었으며, 다수의 유기물이 확인되었다. 본 연구가 향후 청동반가사유상의 전통주조법과 복원기술 연구에 대한 기초 자료로 활용될 것을 기대한다.

Chamber System을 이용한 조선왕조실록의 미세유출가스 분석 (Analysis of VOCs emitted from the Annals of the Joseon Dynasty by Dynamic Chamber System)

  • 강영석;서진호
    • 보존과학연구
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    • 통권31호
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    • pp.9-16
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    • 2010
  • The Annals of the Joseon Dynasty is one of the World Heritage which should be conserved well. However, some of wax treated volume of the Annals of the Joseon Dynasty have damaged seriously. Currently a variety of efforts to conserve and restore the injured volumes are continued and many studies about the aging mechanism of the wax treated volume have being progressed. The analysis of VOCs (Volatile Organic Compounds) emitted from paper cultural heritage is one of the methods to understand the degradation pathway of paper cultural heritage. The analysis of VOCs emitted from paper cultural heritage has been mainly conducted by SPME (Solid Phase Microextraction) method. SPME is potable and simple method but it is difficult to collect all VOCs emitted from a book such as the Annals of Joseon Dynasty. The dynamic chamber system has generally used to do analysis of VOCs emitted from the building materials, furniture and electric appliances. The chamber system is possible to do quantitative and qualitative analysis by a continuous $N_2$ gas flow and the proper chamber which is able to gather all VOCs emitted from the Annals of the Joseon Dynasty. In this study, the most material among detected VOCs was Naphthalene. Naphthalene has used to prevent organic cultural heritage from being damaged by various microbes for a long time. Apart from Naphthalene, main VOCs were Acetic acid, 2-Chloroethanol, 2-Bromoethanol, Furfural, 1-Methylnaphthalene, Azulene, and 2,4-Dioctylphenol. Of these VOCs, Furfural especially was known for a marker which represents a different emission rate according to the aging level.

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자수정(Amethyst) 보석을 응용한 장신구 조형과 Interior Jewel Modeling의 디자인 개발 (The ornaments modeling applied of amethyst gems and design development of interior jewel modeling)

  • 김은주
    • 한국결정성장학회지
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    • 제22권4호
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    • pp.170-177
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    • 2012
  • 자수정(Amethyst) 보석은 원적외선을 방출하여 온열 효과를 나타내고, 체내에서 신진대사를 촉진시키는 친환경 인테리어 재료로서 주목을 받고 있다. 본 논문은 세공 장식(Jeweling)의 가치를 높이는 보랏빛 자수정을 특징적 모티프로 응용하여, Design Model로 개발하고자 하였다. Rhino CAD의 Data에 생성된 유기적 입체 형상은 정밀하고 표면이 깨끗한 왁스(Wax) 적층 가공이 가능하였고, 'Golden Ratio'를 적용한 Brooch 및 Necklace 작품으로 제작, 완성하였다. 이러한 장신구를 비롯하는 장식품 가운데, 자수정 세공 장식의 Interior Jewel Modeling의 활용 사례를 제안하였으며, 본 논문의 연구 결과가 귀금속 제조업체의 생산성 향상에 일조할 수 있을 것으로 기대된다.

계면활성제에 의해 유도되는 농약의 엽면 침투성 연구 현황 (Review of the study on the surfactant-induced foliar uptake of pesticide)

  • 유주현;조광연;김정한
    • 농약과학회지
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    • 제6권1호
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    • pp.16-24
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    • 2002
  • 농약의 식물 엽면 침투성에 관하여 보고한 국내외 논문을 조사하여 최근에 빈번하게 사용되고 있는 침투율 측정법과, 계면활성제에 의해서 유도되는 농약의 엽면 침투기작에 관한 연구 동향을 고찰하였다. 농약의 식물 엽면 침투성 연구에는 생물검정법, 식물 잎이나 cuticular membrane을 이용하는 방사능 추적 기술이 주로 이용되고 있다. 가장 최근에는 수용성 색소 Congo Red를 추적물질로 이용하는 새로운 침투율 측정법이 제안되었다. 농약의 엽면 침투에 있어서 최대의 장벽은 epicuticular wax와 cuticular wax를 포함하는 잎 표면의 왁스층이며, 일부 연구자들은 이를 limiting skin이라 부르기도 한다. 농약의 몰부피(molar volume), 수용해도 및 분배계수 등의 이화학적 성질은 식물 엽면 침투성에 영향을 미치지만 제한적인 상관관계를 나타낼 뿐이며, 일반화할 수 있는 어떠한 상관관계도 아직 발견되지 않았다. Polyoxyethylene을 친수기로 가지는 지방족 알콜 계면활성제들은 많은 농약에 대하여 좋은 침투성 증진제로 알려져 있다. 침투성 증진제로 사용되는 계면활성제가 농약의 엽면 침투성을 증진하는 데에는 계면활성, 가용화 능력, 흡습성 및 미셀생성임계농도 등 계면활성제 고유의 성질이 크게 관여하는 것 같지는 않다. 최근의 연구에서 침투성 증진 효과가 큰 계면활성제는 식물의 왁스층에 쉽게 흡수되어 가역적으로 왁스층의 유동성을 증가시키는 가소제 역할(plasticizing effect)을 한다는 것이 밝혀졌다. 계면활성제가 왁스층에 먼저 침투하면 wax층의 유동성이 증가하고, 이로 인하여 wax층 내에서 농약의 이동성과 분배계수가 달라짐으로써 농약의 엽면 침투 속도가 변화한다는 것이다. 그러나 계면활성제의 친유기 부분인 지방족 알콜의 탄소수와 친수기의 ethylene oxide 부가중합도가 농약의 침투성 증진에서 어떠한 역할을 하는지는 상세히 밝혀져 있지 않다. 다만 계면활성제 자체의 엽면 침투 속도가 농약의 침투속도와 깊은 관련이 있을 것으로 추정되고 있다.

Measurements of 50 Non-polar Organic Compounds Including Polycyclic Aromatic Hydrocarbons, n-Alkanes and Phthalate Esters in Fine Particulate Matter (PM2.5) in an Industrial Area of Chiba Prefecture, Japan

  • Ichikawa, Yujiro;Watanabe, Takehisa;Horimoto, Yasuhide;Ishii, Katsumi;Naito, Suekazu
    • Asian Journal of Atmospheric Environment
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    • 제12권3호
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    • pp.274-288
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    • 2018
  • Quantitative data of 50 non-polar organic compounds constituting $PM_{2.5}$ were continuously collected and analyzed from June 2016 to October 2017 (approximately 17 months) at Ichihara, one of the largest industrial areas in Japan. Target non-polar organic compounds including 21 species of polycyclic aromatic hydrocarbons (PAHs), 24 species of n-alkanes and 5 species of phthalate esters(PAEs) were simultaneously measured by gas chromatography/mass spectrometry. Basically, the average concentrations of the total PAHs, n-alkanes and PAEs in each season remained nearly level, and seasonal variations were little throughout the study period. These results suggest that the emission sources, which are not influenced by the seasons, are the dominant inputs for the target organic compounds. Diagnostic ratios of PAHs, assessment of n-alkane homologue distributions, carbon preference index, and the contribution of wax n-alkanes from plants were used to estimate source apportionments. These results indicate that anthropogenic sources were the main contributor for most PAHs and n-alkanes throughout the study period. The concentrations of PAEs selected in this study were low because emission amounts of these chemicals were little within the source areas of the sampling site. To our knowledge, this study is the first attempt to simultaneously measure a high number of non-polar organic compounds in $PM_{2.5}$ collected from the ambient air of Japan, and the resultant data will provide valuable data and information for environmental researchers.

볼트 결합부 풀림에 관한 마찰 특성 (The Friction Characteristics on the Loosening of Bolted Joints)

  • 박태원;신귀수
    • 한국안전학회지
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    • 제19권1호
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    • pp.12-17
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    • 2004
  • By using an experimental approach recently developed to determine the torque-tension relationship for bearing frictional characteristics of several typical bolted joints were studied. The experimental approach allows the direct determination of the bearing friction between the nut and its bearing surface. Detailed friction studies were made on the influences of the size and shape of the hole, the use of a slot in a bolted joint, contact area and position, and other factors such as turning speed, coating, and the use of wax on the bearing surface. The contact area and position of the washer have a marginal effect on the bearing friction. The organic coating on the nuts reduces the bearing friction significantly. Nuts with organic coating over a washer with zinc finish provide the smallest and the most consistent bearing friction. The results from the experimental investigation will be helpful for the better design of bolted joints bearing friction. The results from the experimental investigation Will be helpful for the better design of bolted joints.

가리비의 조형성을 이용한 한지직물 의상 디자인 연구 (A Study on the Fashion Design of Hanji(Korean traditional paper) Textile Using the Formative Features of Scallop)

  • 권민정;유금화
    • 한국의상디자인학회지
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    • 제13권3호
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    • pp.149-163
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    • 2011
  • Hanjisa(Korean paper yarn), a new material made from the traditional Korean paper, has been developed through local R&D efforts, reflecting the current trend highly valuing environmental friendly. This new material is considered suitable for the 21C lifestyle and culture pursuing improved quality of human life and the environment. Therefore, this study aims to widely make known the originality and functions of the environmentally friendly Korean paper yarn, as well as to increase its commercial value. Furthermore, a new category of apparel design is presented by studying painting dyeing based on transformational tuck techniques and wax resist dyeing with formative features of repeated lines and rhythms of shells in order to implement three-dimensional and decorative artistic expressions. The texture of the Korean cotton paper yarn was particularly suitable to employ tuck and dyeing techniques Which express formative features of shell. Also, the material was useful for expressing the three-dimensional feelings with repeated curves and cross sections of shells. Moreover, paraffin resist dyeing and stitch techniques were used in order to avoid monotony and the images of shells visually materialized. Through the results stated above, this study could explore how to overcome obstacles to globalization of the Korean modern apparel such as its uniqueness, limit of materials or absense of internationality by applying modern design to the Korean paper fabrics. In the future, it is expected that more manufactures could produce and supply the new materials so as to make widely known the originality of the Korean paper fabrics and develop the material into a popular organic product fitting the modern lifestyle.

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Effect of Residual Carbon on the Microstructure Evolution during the Sintering of M2 HSS Parts Shaping by Metal Injection Moulding Process

  • Herranz, G.;Levenfeld, B.;Varez, A.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.225-226
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    • 2006
  • In this present investigation, Metal Injection Moulding (MIM) of M2 High Speed Steel (HSS) parts using a wax-High Density Polyethylene (HDPE) binder is shown. The elimination of organic binder was carried out by thermal debinding under inert atmosphere. In order to keep carbon in the sample that could improve the sintering process, incomplete debinding was performed between 450 and $600^{\circ}C$. The specimens were sintered at temperatures between 1210 and $1280^{\circ}C$ in high vacuum atmosphere, obtaining the 98% of the theoretical density. In the samples with higher residual carbon content, the sintering window was extended up to 20 degrees and the optimum temperature was lower.

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다이어트와인 동아주 제조에 관한 연구 (Studies on Wax Gourd Wine)

  • 안용근;신상철;김승겸;신철승
    • 한국식품영양학회지
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    • 제13권6호
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    • pp.578-584
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    • 2000
  • 설탕 20%를 탄소원으로 하고, 동아를 15%, 20%, 25%로 달리하여 효모를 가해 5~1$0^{\circ}C$에서 100일간 발효시켜서 동아주를 제조하였다. 총당은 동아함량 15%짜리는 8.0%, 20%짜리는 8.6%. 25%짜리는 8.3%를 나타냈고, 환원당은 15%짜리는 7.4%, 20%짜리는 7.6%, 25%짜리는 7.4%를 나타냈다. 단백질 함량은 동아함량 15%짜리는 10.3mg/ml, 20%짜리는 9.8mg/ml, 25%짜리는 11.3mg/ml를 나타냈고, 아미노산 함량은 동아함량 15%짜리는 0.13$\mu$mo1/ml, 20%짜리는 0.03$\mu$mo1/ml, 25%짜리는 0.03$\mu$mo1/ml을 나타냈다. pH는 동아함량15%짜리는 3.88, 20%짜리는 3.99, 25%짜리는 3.97을 나타냈고, 산도는 15%짜리는 0.37%, 20%짜리는 0.44%, 25%짜리는 0.43%를 나타냈다. 균체수는 동아함량 15%짜리는 8.33logCFU/ml, 20%짜리는 8.56 logCFU/ml, 25%짜리는 8.57 log CFU/ml를 나타냈다. 에탄올 함량은 동아함량 15%짜리는 13.4%, 20%짜리는 14.9%, 25%짜리는 15.5%를 나타냈다. 숙신산 함량은 1,407~1,800mg/l 범위를 나타냈으며, 모두 acetic acid, pyruvic acid, citric acid, lactic acid의 순으로 많은 양을 나타냈다. 기호도는 동아함량 15짜리는 3.93, 20%짜리는 3.66, 25%짜리는 3.40을 나타냈다.

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