• Title/Summary/Keyword: Organic vapor

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The implementation of liquefaction equipment monitoring system based on Android (안드로이드 기반의 유증기 액화장치 모니터링 시스템 구현)

  • Park, Man-Kyu;Tack, Han-Ho;Kim, Gwan-Hyung
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.20 no.3
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    • pp.583-589
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    • 2016
  • Volatile organic compounds(VOCs) are regarded as a harmful cause substance not only causing air pollutions but also causing global warming phenomenon. For this reason, VOCs are managed politically to reduce emissions by each country. In particular, the vapor from the gas station contains VOCs which is harmful to the human body such as carcinogens benzene and pollute the atmosphere, the Ministry of Environment defined every gas station must install vapor recovery equipment to recover volatile organic compounds. Recently, there are many accidents caused by existing vapor treatment methods, the liquefaction recovery technology is getting the spotlight to cool the vapor at the field. However, because the liquefaction recovery technology have risks of fire or explosion in accordance with temperature, the real time monitoring is critical factor. In this paper, we implement an Android-based monitoring application for liquified vapor recovery device which attached sensor module for temperature and power to monitoring real time information.

Imaging on a Vapor Deposited Film by Photopolymerization of a Rod-Like Molecule Consisting of Two Diacetylenic Groups

  • Chang, Ji-Young;Kyung Seo;Cho, Hyun-Ju;Lee, Cheol-Ju;Lee, Changjin;Yongku Kang;Kim, Jaehyung
    • Macromolecular Research
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    • v.10 no.4
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    • pp.204-208
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    • 2002
  • A linear rod-like molecule, bis[4-(1,3-octadynyl)phenyl] terephthalate (2), consisting of two diacetylenic groups, was prepared. The unsymmetric diacetylene was prepared by the Cadiot-Chodkiewicz coupling reaction of 1-bromohexyne with 4-ethynylphenol and linked to a benzene core by an esterification reaction with terephthaloyl chloride in tetrahydrofuran. The thin film (200 nm thickness) of compound 2 was fabricated by the physical vapor deposition on a glass plate with a thermal evaporator. In the X-ray diffraction (XRD) study, the vapor deposited film on the glass plate showed peaks with d spacings of 19.4, 5.7, and 4.5 $\AA$. This XRD pattern was quite different from that observed for compound 2 isolated by recrystallization from methylene chloride/hexane. The vapor deposited film was polymerized by UV irradiation. Photopolymerization was carried out through a photomask, resulting in a patterned image, where the irradiated part became isotropic.

Air-Soil Partitioning of PCBs in Rural Area

  • Yeo, Hyun-Gu;Park, Min-Kyu;Chun, Man-Young;Young, Sun-Woo
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.E1
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    • pp.1-9
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    • 2003
  • The soil concentrations of polychlorinated biphenyls (PCBs) were measured at 12 sites in Ansung, Kyonggi province, Korea. Correlation coefficient (r) between total PCBs and organic matter content (OM) was significant (r=0.562, p< 0.05). It suggests that organic matter may be a key factor of soil absorption of PCBs. The PCB concentrations of low chlorinated congeners with high vapor pressure were relatively abundant in air but high chlorinated congeners with low vapor pressure were mainly dominated by soil. The results indicated the influence of physicochemical properties of PCBs such as vapor pressure, octanol - air partition coefficient ( $K_{OA}$ ). The calculated soil/air fugacity quotients suggested that the soil may be a source of heavier molecular PCBs (>penta-CBs) to the atmosphere, where lighter molecular PCBs appear to be affected by a movement from air to soil, especially tetra-CBs. Therefore, PCB homologs with low vapor pressure might have been influenced by revolatilization from soil.

Effect of Surface Finishing Materials on the Moisture Conditions in Concrete: Vapor and Water Permeability of Finishing Materials Under Changing Environmental Conditions

  • Ryu, Dong-Woo
    • International Journal of Concrete Structures and Materials
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    • v.2 no.2
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    • pp.83-90
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    • 2008
  • Permeability to vapor and water among other performances required for finishing materials is dealt with in this study. The relative moisture content of concrete coated/covered with a finishing material was experimentally investigated while changing the environmental conditions including temperature, relative humidity, and rainfall. An organic paint (water-based urethane), organic synthetic resin emulsion-type film coating (film coating E), and inorganic porcelain tiles were selected as the finishing materials. When compared from the aspect of vapor and water permeability, the vapor permeability and water permeability of water-based urethane were high and low, respectively; those of film coating E were high and high, respectively; and those of porcelain tiles were low and low, respectively. This means that the moisture state of concrete structures is governed not only by the environmental conditions but also by the performance of finishing materials. It is therefore of paramount importance to appropriately select a finishing material to address the specific deteriorative factors involved in the concrete structure to be finished.

A Study on the Calculation Method of VOCs Emissions Using Equation of State in the Gas Station Tank (상태방정식을 이용한 주유소 탱크에서의 유증기 배출량 산정법에 관한 연구)

  • Park, Taejoon;Oh, Wheesung;Lee, Chang-Eon
    • Journal of the Korean Society of Combustion
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    • v.20 no.4
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    • pp.42-48
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    • 2015
  • This study was investigated the estimation of VOCs (Volatile Organic Compounds) emission from a gas station tank. To improve the atmosphere environmental quality near the gas station, the installation of vapor recovery system has been expanded recently. Therefore, it was necessary to calculate VOCs emissions from the gas station tank with vapor recovery systems for evaluation of their performance. The VOCs emissions are difficult to measure directly because of various sources and irregularly emission by pressure rise. In this study, VOCs emissions were estimated by simple calculation based on the equation of state for measured pressure, temperature and volume of a gasoline tank at a gas station. The result confirmed that the present national emission factor did not have significant discrepancy with the calculated value.

Performance Analysis of 1MW Organic Rankine Cycle with Liquid-Vapor Ejector using Effluent from Power Plant (화력발전소 폐열에 따른 작동유체별 액-증기 이젝터를 적용한 1MW급 ORC의 성능 분석)

  • Kim, Hyeon-Uk;Yoon, Jung-In;Son, Chang-Hyo
    • Journal of Power System Engineering
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    • v.18 no.6
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    • pp.120-125
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    • 2014
  • In this paper, suitable working fluid of 1MW Organic Rankine Cycle(ORC) with liquid-vapor ejector using effluent from power plant is selected. The results of comparison performance of 5 refrigerants are as follows; R600a, R134a, R1270, R236fa, R235fa. The operating parameters considered in this study include the condensation capacity evaporation capacity and efficiency. As a result of comparison of basic ORC system and with liquid-vapor ejector, with ORC system presents the higher system efficiency since the ejector makes the turbine outlet pressure lower than condensation pressure through its pressure recovery. Also, this ejector ORC system is advantageous in miniaturizing the size of components owing to decrease of evaporation capacity and condensation capacity.

Selective Vapor-Phase Deposition of Conductive Poly(3,4-ethylenedioxythiophene) Thin Films on Patterned FeCl3 Formed by Microcontact Printing

  • Lee, Bo H.;Cho, Yeon H.;Shin, Hyun-Jung;Kim, Jin-Yeol;Lee, Jae-gab;Lee, Hai-won ;Sung, Myung M.
    • Bulletin of the Korean Chemical Society
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    • v.27 no.10
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    • pp.1633-1637
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    • 2006
  • We demonstrate a selective vapor-phase deposition of conductive poly(3,4-ethylenedioxythiophene) (PEDOT) thin films on patterned $FeCl_3$. The PEDOT thin films were grown on various substrates by using the vapor-phase polymerization of ethylenedioxythiophene (EDOT) with $FeCl_3$ catalytic layers at 325 K. The selective deposition of the PEDOT thin films using vapor-phase polymerization was accomplished with patterned $FeCl_3$ layers as templates. Microcontact printing was done to prepare patterned $FeCl_3$ on polyethyleneterephthalate (PET) substrates. The selective vapor-phase deposition is based on the fact that the PEDOT thin films are selectively deposited only on the regions exposing $FeCl_3$ of the PET substrates, because the EDOT monomer can be polymerized only in the presence of oxidants, such as $FeCl_3$, Fe($CIO_4$), and iron(II) salts of organic acids/inorganic acids containing organic radicals.

DEVELOPMENT OF MEMBRANE AND COLD-CONDENSATION PROCESS FOR REMOVAL AND RECOVERY OF VOLATILE ORGANIC COMPOUNDS

  • Kim, Sung-Soo;Lee, Jong-Hwa;Kim, Hyunki;Kim, Sang-Yong
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.69-72
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    • 2003
  • Volatile organic compounds (VOC) cause air pollution problem and deterioration of atmosphere of petrochemical and fine chemical plants. Hybrid process of membrane and cold-condensation were developed and it effectively removed and recycled the VOC. Operation parameters of the process were optimized to attain hish removal and recycle of VOC. Composite membranes for organic vapor separation were developed in this work by PDMS coating and plasma polymerization on polypropylene and polysulfone support membranes. PDMS and various silicone monomers were tested for several organic vapors such as benzene, toluene, TCE, and HCFC, which are produced in petrochemical and fine chemical industry and causes air pollution problems if are released to atmosphere. Composite membranes prepared in this work showed appreciable performance in terms of organic vapor removal and reuse. Performance variation of the membranes was correlated with their surface characteristics.

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Electrical Effects in Organic Thin-Film Transistors Using Polymerized Gate Insulators by Vapor Deposition Polymerization (VDP)

  • Lee, Dong-Hyun;Pyo, Sang-Woo;Koo, Ja-Ryong;Kim, Jun-Ho;Shim, Jae-Hoon;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.661-664
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    • 2004
  • In this paper, it was demonstrated that the organic thin film transistors with the organic gate insulators were fabricated by vapor deposition polymerization (VDP) processing. The configuration of OTFTs was a staggered-inverted top-contact structure and gate dielectric layer was deposited with 0.45 ${\mu}m$ thickness. In order to form polyimide as a gate insulator, VDP process was also introduced instead of spin-coating process. Polyimide film was respectively co-deposited with different materials. One was from a 4,4'-oxydiphthalic anhydride (ODPA) and 4, 4'-oxydianiline (ODA) and the other was from 2,2-bis(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA) and ODA. And it was also cured at 150 $^{\circ}C$ for 1 hour followed by 200 $^{\circ}C$ for 1 hour. Electrical characteristics of the organic thin-film transistors were detailed comparisons between the ODPA-ODA and the 6FDA-ODA which were used as gate insulator.

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Behavior of Water Vapor Permeability on Layered System

  • Oh, Ae-Gyeong
    • Fashion & Textile Research Journal
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    • v.11 no.2
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    • pp.359-362
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    • 2009
  • This study investigates the behavior of water vapor permeability of a layered system to find out a comfortable combination of a layered system for outdoor activities and examines the water vapor permeability of various types of outdoor clothing fabrics. The layered system includes the base layer such as sportswool and polyester/cotton fabrics, the middle layer such as single and double sided fleece fabrics, and the shell layer such as polyurethane-coated, PTFE-laminated and microfiber fabrics in this experiment. Results show that the layered system was applied, it was working together as a whole having some influence on each other layer, though every layer offered varying degree of water vapor permeability. Water vapor permeability of layered system exactly followed the same trend as the shell layer, which is all vapor permeable water repellent fabrics as a single layer. The rate of water vapor transfer through a layered system is mainly related to the type of vapor permeable water repellent fabrics used for the shell layer.