• 제목/요약/키워드: Organic substrates

검색결과 626건 처리시간 0.027초

말레에이트 공중합체 LB막의 유기 가스 반응 특성 (Organic Gas Response Characteristics of Maleate Copolymer LB Films)

  • 이을식;김도균;유승엽;최용성;권영수;박재철
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
    • /
    • pp.415-418
    • /
    • 1998
  • The maleate copolyrner($C_{18}MA-VE_2$) is used as sensitive materials and deposited on the slide-glass substrates at room temperature using Langmuir-Blodgett(LB) method. The results of current-time(1-t) measurements are performed to investigate the gas-detection characteristics of the sensitive LB films in the presence of organic gases just as chloroform, acetone, ethanol, methanol using the apparatus for the gas-detection measurement. Several interesting responses are observed at room temperature, such as reversible response, sensitivity and response time. Response time and sensitivities are evaluated 160~220[sec], minimum 6[times], maximum 70[times] for each organic gas by adsorption and penetration of the organic gases in the relation concentration of 100[%], respectively.

  • PDF

Direct route to high yield synthesis of metal nanoparticles for printable electronic devices

  • 김동훈;이귀종;이영일;전병호;최준락;서영관;김태훈;강성구
    • 한국재료학회:학술대회논문집
    • /
    • 한국재료학회 2009년도 춘계학술발표대회
    • /
    • pp.14.1-14.1
    • /
    • 2009
  • We found a high yield synthetic route to organic-soluble metal nanoparticles in the concentrated organic phase. The organic phase contains metal salt, amines, fatty acids, nonpolar solvent, and reducing agent. Even using only generic chemicals, organic-soluble silver and copper nanoparticles could be easily obtained by this simple and rapid reaction scheme at large scale. The hydrocarbon-protected metal nanoparticles showed excellent dispersion properties and were successfully printed onto polymer substrates. The printed pattern was heated at $200^{\circ}C$, which showed very low specific electrical resistance (< 10 uOhm$\cdot$cm), sufficient for conducting line of various printable devices.

  • PDF

Molecular Layer Deposition of Organic/Inorganic Nanohybrid Dielectrics for OTFTs

  • 이병훈;이광현;임성일;성명모
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
    • /
    • pp.56-56
    • /
    • 2010
  • We report a low-temperature fabrication of organic/inorganic nanohybrid dielectrics for organic thin film transistors. The self-assembled organic layers (SAOLs) were grown by repeated sequential adsorptions of C=C-terminated alkylsilane and metal (Al or Ti) hydroxyl with ozone activation, which was called "molecular layer deposition (MLD)". The $TiO_2$ and $Al_2O_3$ inorganic layers were grown by ALD, which relies on sequential saturated surface reactions resulting in the formation of a monolayer in each sequence and is a potentially powerful method for preparing high quality multicomponent superlattices. The MLD method combined with ALD (MLD-ALD) was applied to fabricate SAOLs-$Al_2O_3$-SAOLs-$TiO_2$ nanohybrid superlattices on polymer substrates at relatively low temperature. The MLD method is an ideal fabrication technique for various flexible electronic devices.

  • PDF

유럽표준분석법에 의한 원예용 상토의 이화학성 및 안정성 평가 (Evaluation of physio-chemical properties and stability of some commercial horticultural substrates by the European Standard Methods)

  • 김혁수;김계훈
    • 한국토양비료학회지
    • /
    • 제43권1호
    • /
    • pp.44-50
    • /
    • 2010
  • 본 연구는 현재 유통 중에 있는 원예용 상토에 대해 이화학적 특성 및 안정도를 조사하여 상토이용의 최적화를 도모하기 위하여 수행하였다. 이를 위하여 12개 업체에서 생산하는 19 종류 원예용 상토를 수집하여 유럽표준분석법에 준해 상토의 이화학성을 분석하였다. 또한 이 결과를 이용하여 유럽에서 사용 중인 산소호흡률 측정방법에 따라 상토의 안정도를 평가하였다. 원예용 상토의 이화학성은 건물함량 39.33~69.00%, 수분함량 31.00~60.67%, 유기물함량 25.05~39.14%, 회분함량 60.86~74.95%, 실험실가밀도 227.38~391.20$g{\cdot}L^{-1}$ pH 4.75~6.10 EC 0.41~0.85 $dS{\cdot}m^{-1}$ T-N 0.19~1.29%, $P_2O_5$ 0.73~18.95 $mg{\cdot}L^{-1}$로 각각 조사되었다. 양이온 K, Mg, Ca, Na은 각각 49.72~306.74 $mg{\cdot}L^{-1}$, 9.97~91.17 $mg{\cdot}L^{-1}$, 6.90~283.32 $mg{\cdot}L^{-1}$, 80.68~295.83 $mg{\cdot}L^{-1}$의 범위를 나타내었다. 또한 가밀도 124.48~243.16 $kg{\cdot}m^{-3}$, 진밀도 2073.94~2249.99 $kg{\cdot}m^{-3}$, 총공극률 89.19~94.05%, 액상 57.14~78.35%, 기상 12.19~35.62%로 조사되었다. 원예용 상토의 산소호흡률은 2.03~5.63 mmol $O_2{\cdot}kg$ OM $hour^{-1}$로 선행연구를 통해 설정된 유기물질의 안정도 평가기준과 비교시 19점의 원예용 상토 중 17점의 상토에서 '매우 안정'의 단계로 조사되었으며, 나머지 2점의 상토에 대해서도 '안정' 단계로 평가되었다. 향후 상토의 산소호흡률을 이용한 안정도 평가를 통해 최적조건의 상토가 지속적으로 관리될 수 있을 것으로 판단된다.

Effects of Simultaneous Bending and Heating on Characteristics of Flexible Organic Thin Film Transistors

  • Cho, S.W.;Kim, D.I.;Lee, N.E.
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
    • /
    • pp.470-470
    • /
    • 2013
  • Recently, active materials such as amorphous silicon (a-Si), poly crystalline silicon (poly-Si), transition metal oxide semiconductors (TMO), and organic semiconductors have been demonstrated for flexible electronics. In order to apply flexible devices on the polymer substrates, all layers should require the characteristic of flexibility as well as the low temperature process. Especially, pentacene thin film transistors (TFTs) have been investigated for probable use in low-cost, large-area, flexible electronic applications such as radio frequency identification (RFID) tags, smart cards, display backplane driver circuits, and sensors. Since pentacene TFTs were studied, their electrical characteristics with varying single variable such as strain, humidity, and temperature have been reported by various groups, which must preferentially be performed in the flexible electronics. For example, the channel mobility of pentacene organic TFTs mainly led to change in device performance under mechanical deformation. While some electrical characteristics like carrier mobility and concentration of organic TFTs were significantly changed at the different temperature. However, there is no study concerning multivariable. Devices actually worked in many different kinds of the environment such as thermal, light, mechanical bending, humidity and various gases. For commercialization, not fewer than two variables of mechanism analysis have to be investigated. Analyzing the phenomenon of shifted characteristics under the change of multivariable may be able to be the importance with developing improved dielectric and encapsulation layer materials. In this study, we have fabricated flexible pentacene TFTs on polymer substrates and observed electrical characteristics of pentacene TFTs exposed to tensile and compressive strains at the different values of temperature like room temperature (RT), 40, 50, $60^{\circ}C$. Effects of bending and heating on the device performance of pentacene TFT will be discussed in detail.

  • PDF

폐코이어를 재활용한 혼합 유기질 비료가 배추와 상추의 생육에 미치는 영향 (Effect of the Organic Fertilizer Mixed with Various Recycled Coir Substrates on Chinese Cabbage(Brassica Campestris Ssp. Pekinensis) and Lettuce(Lactuca Sativa))

  • 이규빈;박은지;박영훈;최영환;서정민;강점순
    • 한국환경과학회지
    • /
    • 제24권9호
    • /
    • pp.1221-1231
    • /
    • 2015
  • The present study was conducted to find a way to recycle the coir substrate by investigating changes in its physical and chemical properties based on the number of use year. Specific gravity of unused coir substrate was $0.212g/cm^3$, while it was higher for the substrate used for 2 years. Porosity was different depending on the number of use year. The porosity of unused substrate was 51.9%, but it increased to 68.6% after used for 2 years. In general, physical and chemical properties were better in the coir substrate used for 2 years than in unused one. The number of leaves, leaf area, flesh weight and dry weight of oriental cabbage and lettuce were higher in coir substrate used for 2 years than those in unused one. Whereas, no significant difference was observed between the substrates used for one year and 2 years, indicating that the one time-used wast substrate could be recycled for cultivating vegetables. Growth of the vegetables was improved when organic fertilizer composed of complex organics with different mixing ratios was provided to the coir substrate, compared to untreated plot. The optimum mixing ratio of the wast substrate and complex organics was 2:8(v/v) for fertilization using wast coir substrate. Therefore, coir substrate generally wasted after being used for one time was reuseable by supplying organic fertilizer.

플라스틱 기판에 제작된 유기박막태양전지의 출력특성 경시변화 (Time-Variant Characteristics of Organic Thin Film Solar Cell Devices on Plastic Substrates)

  • 노임준;이선우;신백균
    • 한국진공학회지
    • /
    • 제22권4호
    • /
    • pp.211-217
    • /
    • 2013
  • $PCDTBT:PC_{71}BM$$PTB7:PC_{71}BM$을 유기고분자 활성층 재료로 이용한 Bulk Hetero-Junction (BHJ) 구조의 유기박막태양전지를 플라스틱 기판 위에 각각 제작하여, 시간변화에 따른 단락전류밀도($J_{SC}$), 개방전압($V_{OC}$), 곡선인자(FF) 및 전력변환효율(PCE) 등 출력특성의 변화에 대해 고찰하였다. 유기박막태양전지의 출력특성 파라메터는 시간 경과에 따라 모두 감소하는 경향을 나타내었으며, 특히 개방전압의 감소폭이 컸다. 이러한 개방전압 감소의 원인은 빛에 대한 장시간의 노출과 산소를 포함하는 수분과의 접촉에 의한 LUMO 준위와 HOMO 준위 차의 감소가 그 원인이라 생각되며, 그 메커니즘에 대해 고찰하였다. 또한 유기박막태양전지 소자의 직렬 및 병렬 저항 값은 감소하다가 다시 증가하는 경향을 보였다. 이는 LUMO 준위와 HOMO 준위 차가 감소함에 의한 것과 공액 고분자 활성층 내부에서의 열적과정 손실에 기인하여 전극과 고분자의 계면에서의 접촉저항의 증가 때문이라고 생각된다. 유기박막태양전지의 전력변환효율은 초기에 급격한 감소를 보이다가 시간이 지날수록 감소폭이 차츰 둔화되어 한계치에 도달한 후, 포화되는 경향을 보였다. 이것이 유기박막태양전지가 실제 구동에서 발생시킬 수 있는 최소 출력특성값인 것으로 판단된다.

A Brief Investigation on the Performance Variation and Shelf Lifetime in Polymer:Nonfullerene Solar Cells

  • Lee, Sooyong;Kim, Hwajeong;Lee, Chulyeon;Kim, Youngkyoo
    • Current Photovoltaic Research
    • /
    • 제7권3호
    • /
    • pp.55-60
    • /
    • 2019
  • Polymer:nonfullerene solar cells with an inverted-type device structure were fabricated by employing the bulk heterojunction (BHJ) active layers, which are composed of poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)-benzo[1,2-b:4,5-b']dithiophene))-alt-(5,5-(1',3'-di-2-thienyl-5',7-bis(2-ethylhexyl)benzo[1',2'-c:4',5'-c']dithiophene-4,8-dione))] (PBDB-T) and 3,9-bis(6-methyl-2-methylene-(3-(1,1-dicyanomethylene)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2',3-d']-s-indaceno[1,2-b:5,6-b']dithiophene (IT-M). The BHJ layers were formed on a pre-patterned indium-tin oxide (ITO)-coated glass substrate by spin-coating using the blend solutions of PBDB-T and IT-M. The solar cell performances were investigated with respect to the cell position on the ITO-glass substrates. In addition, the short-term shelf lifetime of solar cells was tested by storing the PBDB-T:IT-M solar cells in a glovebox filled with inert gas. The results showed that the performance of solar cells was relatively higher for the cells close to the center of substrates, which was maintained even after storage for 24 h. In particular, the PCE of PBDB-T:IT-M solar cells was marginally decreased after storage for 24 h owing to the slightly reduced fill factor, even though the open circuit voltage was unchanged after 24 h.