• 제목/요약/키워드: Organic substrates

검색결과 626건 처리시간 0.03초

PACVD of Plasma Polymerized Organic Thin Films and Comparison of their Electrochemical Properties

  • I.S. Bae;S.H. Cho;Kim, M.C.;Y.H. Roh;J.H. Boo
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2003년도 춘계학술발표회 초록집
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    • pp.53-53
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    • 2003
  • Plasma polymerized organic thin films were deposited on Si(100) glass and metal substrates using thiophene and ethylcyclohexane precursors by PECVD method. In order to compare electrochemical properties of the as-grown thin films, the effects of the RF plasma power in the range of 30~100 W. AFM showed that the polymer films with smooth surface and sharp interface could be grown under various deposition conditions. Impedance analyzer was utilized for the determination of I-V curve for leakage current density and C-V for dielectric constants, respectively. To obtain C-V curve, we used a MIM structure of metal(Al)-insulator(plasma polymerized thin film)-metal(Pt) structure. Al as the electrode was evaporated on the thiophene films that grew on Pt coated silicon substrates, and the dielectric constants of the as-grown films were then calculated from C- V data measured at 1MHz. From the electrical property measurements such as I-V and C-V characteristics, the minimum dielectric constant and the best leakage current of thiophene thin films were obtained to be about 3.22 and $1{\;}{\times}10^{-11}{\;}A/cm^2$. However, in case of ethylcyclohexane thin films, the minimum dielectric constant and the best leakage current were obtained to be about 3.11 and $5{\;}{\times}10^{-12}{\;}A/cm^2$.

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이온빔 플라즈마 처리된 플라스틱 기판에 의한 OLED의 광추출 효율 향상 (Improvement of Out-coupling Efficiency of Organic Light Emitting Device by Ion-beam Plasma-treated Plastic Substrate)

  • 김현우;송태민;이형준;전용민;권정현
    • 반도체디스플레이기술학회지
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    • 제21권2호
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    • pp.7-10
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    • 2022
  • A functional polyethylene terephthalate substrate to increase light extraction efficiency of organic light-emitting diodes is studied. We formed nano-structured PET surfaces by controlling the power, gas, and exposure time of the linear ion-beam. The haze of the polyethylene terephthalate can be controlled from 0.2% to 76.0% by changing the peak-to-valley roughness of nano structure by adjusting the exposure cycle. The treated polyethylene terephthalate shows average haze of 76.0%, average total transmittance of 86.6%. The functional PET increases the current efficiency of organic light-emitting diodes by 47% compared to that of organic light-emitting diode on bare polyethylene terephthalate. In addition to polyethylene terephthalate with light extraction performance, by conducting additional research on the development of functional PET with anti-reflection and barrier performance, it will be possible to develop flexible substrates suitable for organic light-emitting diodes lighting and transparent flexible displays.

Sol-Gel 법에 의해 Colloidal Silica와 Glycidoxypropyl Trimethoxysilane으로 부터 하드코팅 용액의 제조 (Preparation of Hard Coating Solutions using Colloidal Silica and Glycidoxypropyl Trimethoxysilane by the Sol-Gel Method)

  • 김대현;송기창;정재식;이범석
    • Korean Chemical Engineering Research
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    • 제45권5호
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    • pp.442-447
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    • 2007
  • 투명 플라스틱 필름의 표면강도를 향상시키기 위하여 유-무기 혼성 코팅용액을 Sol-Gel 법을 이용하여 합성하였다. 코팅용액은 입자 직경이 12 nm 크기의 무기물인 colloidal silica 용액(Ludox)에 유기물인 GPTMS(glycidoxypropyl trimethoxysilane)를 첨가하여 제조하였다. 그 후에 기재인 PC(polycarbonate) 필름에 담금 코팅(dip-coating)시키고, 상온에서 10분 동안 건조시킨 후, $80^{\circ}C$에서 30분 동안 열 경화시켜 하드 코팅 막을 제조하였다. 이 과정 중 코팅용액의 pH 변화와 GPTMS 첨가량의 변화가 코팅 막의 물성에 미치는 영향을 살펴보았다. pH 4의 산성 조건에서 제조된 코팅용액으로 PC 필름 위에 코팅한 경우는 중성이나 염기성 조건으로 제조된 경우 보다 우수한 연필경도 및 기재와의 부착력을 보였다. 또한 GPTMS의 첨가량이 증가할수록 코팅 막의 연필경도 및 기재와의 부착력이 증가하였다.

느타리버섯 폐배지에 대한 줄지렁이(Eisenia fetida) 개체군의 섭식률 및 생장률 (Feeding rate and growth rate of earthworm(Oligochaeta : Eisenia fetida) population on the spent substrate of the agaric-mushroom cultivation)

  • 배윤환;양용운
    • 유기물자원화
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    • 제18권4호
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    • pp.45-53
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    • 2010
  • 여러 가지 방법으로 전처리된 느타리 버섯 폐배지에 대한 줄지렁이 개체군의 섭식률 및 생장률을 조사하였다. 갓 발생한 버섯폐배지의 부숙기간을 달리하여 지렁이에게 급이하였을 경우, 20일 이상 부숙된 버섯 폐배지보다 10일 이하로 부숙된 버섯 폐배지에 대한 지렁이 개체군의 섭식량 및 생장률이 높았다. 분변토를 첨가한 버섯폐배지나 질소영양원으로서 요소비료를 첨가하여 부숙한 버섯폐배지는 지렁이 개체군의 섭식률과 생장률을 증대시키지 못하는 것으로 나타났다. 그러나 버섯폐배지를 분쇄하여 공급하였을 경우에는 섭식량 및 생장률이 증가하였다. 특히 분쇄된 버섯폐배지에 미강을 첨가하였을 경우에는 분쇄하지 않은 단순 버섯폐배지보다 생장률이 1.85배 증가하였다.

양액재배용 평연화 왕겨 배지의 근권 pH 안정화 (Stabilization of Rhizosphere pH during Tomato Cultivation Using Expanded Rice Hull Substrate)

  • 임상현;김경희;전신재;유근창
    • 생물환경조절학회지
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    • 제10권2호
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    • pp.95-100
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    • 2001
  • 본 연구에서는 팽연화왕겨를 이용한 토마토 양액재배시 높은 근권 pH를 적정 수준으로 유지학 위해 공급배양액의 pH를 낮추는 방안과 배지 내에 pH 3.0∼4.0 수준의 sphagnum peatmoss를 혼합하는 두 가지 방법을 시도하였다. 급액 pH를 낮추는 방법은 근권 pH의 경시적 변화가 매우 커서 뿌리에 장해가 있는 것으로 판단되며, 유의성은 없으나 수량이 약간 감소하는 경향을 보였다. Spagnunm peatmoss를 혼합하는 방법은 10%(v/v) 혼합처리에서 안정적인 pH 수준이 생육 전기간에 걸쳐 유지되었으며 수분 특성 개선 등의 부수적인 효과가 있어 유의성 있는 증수 효과를 보여 팽연화왕결르 이용한 양액재배시 높은 근권 pH의 문제는 sphagnum peatmoss를 10%(v/v) 혼합하는 처리로 해결할 수 있을 것으로 판단되었다.

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Probing the Molecular Orientation of ZnPc on AZO Using Soft X-ray Spectroscopies for Organic Photovoltaic Applications

  • Jung, Yunwoo;Lee, Nalae;Kim, Jonghoon;Im, Yeong Ji;Cho, Sang Wan
    • Applied Science and Convergence Technology
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    • 제24권5호
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    • pp.151-155
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    • 2015
  • The interfacial electronic structure between zinc phthalocyanine (ZnPc) and aluminumdoped zinc oxide (AZO) substrates has been evaluated by ultraviolet photoemission spectroscopy and angle-dependent x-ray absorption spectroscopy to understanding the molecular orientation of a ZnPc layer on the performance of small molecule organic photovoltaics (OPVs). We find that the ZnPc tilt angle improves the ${\pi}-{\pi}$ interaction on the AZO substrate, thus leading to an improved short-circuit current in OPVs based on phthalocyanine. Furthermore, the molecular orientation-dependent energy level alignment has been analyzed in detail using ultraviolet photoemission spectroscopy. We also obtained complete energy level diagrams of ZnPc/AZO and ZnPc/indium thin oxide.

경유의 Model solution에서 고정화효소를 이용한 Dibezothiophene의 산화

  • 허정찬;성현태;류근갑
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2001년도 추계학술발표대회
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    • pp.517-520
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    • 2001
  • Fossil fuels such as coal and crude oil contain various organic sulfur compounds. Combustion of these fuels emit sulfur oxides which are considered as msjor air pollutants causing acid rain problem. Among various organic sulfur compounds, aromatic sulfur compounds of thiophenes which constitute major sulfur fractions of heavy oils are not easily removed by hydrodesulfurization. Many peroxidase and hemoproteins are known to oxidize dibenzothiophene (DBT) to dibenzothiophene-sulfoxide(DBT - sulfoxide) then dibenzothiophene- sulfone (DBT-sulfone). The oxidation of DBT by the immobilized hemoproteins in n-octane was increased significantly when the hemoproteins were deposited on celites of the particle size between 0.75 - 1.0 mm and a conventional substrates. such as t-butyl hydroperoxide and cumene hydroperoxide. In anhydrous organic solvents with log P values larger than 4.0 DBT was completely oxidized by cumene hydroperoxide catalyzed by cytochrome c deposited on celites.

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4" E-ink Active-matrix Displays based on Ink-jet Printed Organic Thin Film Transistors

  • Koo, Bon-Won;Kim, Do-Hwan;Moon, Hyun-Sik;Kim, Jung-Woo;Jung, Eun-Jeong;Kim, Joo-Young;Jin, Yong-Wan;Lee, Sang-Yun;Kim, Jong-Min
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.1631-1633
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    • 2008
  • We demonstrate 4-in QVGA active-matrix electrophoretic display based on ink-jet printed organic transistors on glass substrates. Our TFT array had a bottom-gate, bottom-contact device architecture. The organic semiconductor and gate dielectric were solution processed. The field-effect mobility of the printed devices, calculated in the saturation region, was $0.1{\sim}0.3cm^2/Vs$ at Vg=-20 V.

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Fabrication of Roll-Printed Organic Thin-Film Transistors using Patterned Polymer Stamp

  • Jo, Jeong-Dai;Yu, Jong-Su;Kim, Dong-Soo;Kim, Kwang-Young;Lee, Eung-Sug
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.243-246
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    • 2008
  • Roll-printed organic thin-film transistors (OTFTs) were fabricated by gravure or flexography printing using patterned PDMS stamp with various channel lengths, silver pastes, coated polyvinylphenol dielectric, and jetted bis(triisopropyl-silylethynyl) pentacene semiconductor on plastic substrates. The roll-printed OTFT parameters were obtained: fieldeffect mobility of $0.1\;cm^2/Vs$, an on/off current ratio of $10^4$ and a subthreshold slope of 2.53 V/decade.

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ZnO/ITO anode for organic electro-luminescence devices

  • Jeong, S.H.;Kho, S.;Jung, D.;Boo, J.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.885-886
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    • 2003
  • A bilayer is used as an anode electrode for organic electroluminescent devices. The bilayer consist of an ultrathjn ZnO layer adjacent to an hole-transporting layer and an Indium tin oxide(ITO) outerlayer. We tried to bring low the barrier between the devices as deposited ZnO films on ITO substrates. We fabricated the organic EL structure consisted of Al as cathode, $Al_{2}O_{3}$ as electro transport layer, Alq3 as luminously layer, triphenyl diamine(TPD) as hole transport layer and ZnO(l nm )/ITO(l50 nm) as anode. The result of this experiment was not good compared with the case of using ITO, Nevertheless, at this structure we obtained the lowest turn-on voltage as the value of 19 V and the good brightness (6200 $cd/m^{2}$) of the emission light from the devices. Then the quantum efficiency was to be 1.0%.

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