• Title/Summary/Keyword: Organic removal

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Fabrication of Flow Cell Using Carbon Fiber and Electrochemical Decomposition Characteristics for Organic Dyes (탄소섬유전극을 이용한 흐름형 전기분해조 제작 및 유기염료의 전기화학적 분해 연구)

  • Park, Deog-Su
    • Journal of Environmental Science International
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    • v.21 no.11
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    • pp.1371-1377
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    • 2012
  • The simulated dyes solution containing Basic Red 46(BR 46), Yellow 21(Y 21), and Maxilon Blue 30(MB 30) were electrochemically oxidized using carbon fiber as an anode. The electrolyses were performed in a electrolytic flow cell constructed by Vycor glass tube. The carbon fiber was positioned in the inside of Vycor glass tube and platinum wire coiled around outside of tube as a cathode. Several operating variables, such as current, time, pH and flow rate of solution were studied. Increasing current density would lead to a corresponding increase in the dye removal efficiency 99.2 % at a 200 mA. The electrolyses time could also improve and removal efficiency was about 99 % after 1.5 hours of electrolyses. The removal efficiency was increased with the increase of flow rate of solution and optimum flow rate was 5 mL/min. THe pHs of solution affect the removal efficiency. The removal efficiency was decreased with the increase of pH of solution and optimum pH was 5.05 (0.1 M $KNO_3$).

Removal Efficiency of the Pollutants from Piggery Wastes with Activated Carbon Treated with Metal and Their Pilot Scale Design

  • Oh, Won-Chun;Park, Chong-Sung;Bae, Jang-Soon;Ko, Young-Shin
    • Carbon letters
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    • v.7 no.3
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    • pp.180-187
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    • 2006
  • The treatment of piggery wastes was carried out at pilot scale using a multilayered metal-activated carbon system followed by carbon bed filtration. The physicochemical properties were obtained from treated samples with aqueous solutions containing metallic ions such as $Ag^+$, $Cu^{2+}$, $Na^+$, $K^+$ and $Mn^{2+}$, which main obsevations are subjected to inspect surface properties, color removal properties by Uv/Vis and EDX. Multilayered metal-activated carbons were contacted with waste water to investigation of the simultaneous catalytic effect for the COD, BOD, T-N and T-P removal. The removal results for the piggery waste using multilayered metal-activated carbon bed was achieved the satisfactory removal performance under permitted values of Ministry of Environment of Korea. The high efficiency of the multilayered metal-activated carbon bed was determined by the performance of this material for trapping, catalytic effect and adsorption of organic solid particles.

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Advanced Wastewater Treatment using Sludge Solubilization by the Cavitation and PGA addition (Cavitation에 의한 슬러지 가용화와 PGA를 이용한 하수고도처리에 관한 연구)

  • KIM, Dongha
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.4
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    • pp.449-454
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    • 2008
  • Some pretreatment methods have been proposed to enhance the biodegradability and to shorten the hydrolysis reaction time. By means of efficient pretreatment the suspended solids (SS) can be made of better accessible for the anaerobic bacteria. There are several ways how this can be accomplished, which include biological, mechanical, thermal, and chemical methods. For the sludge solubilization using the cavitation phenomenon, we have tried to develop a pretreatment process consisted of a reactor and pumps. The objectives of this study were to develop a advanced wastewater treatment consisted of IABR and the cavitation with PGA. The most effective removal for organic matter and nutrients were occured when both cavitation pretreatment and ${\gamma}$-PGA were applied at the IABR process. Only small portion of ${\gamma}$-PGA at a rate of 1.38mg/L, was enough to improve sedimentation ability, SS removal efficiencies, and sludge volume reduction. After the sludge solubilization by the cavitation, SCOD increased to 193% and SS decreased to 36%. The removal ratio of BOD was 94.5%, T-N removal ratio was 85.5% and T-P removal ratio was 84.9%. The combination process of the IABR with the cavitation and PGA addition seems to be very effective alternative wastewater treatment process.

Effects of sludge and $CO_2$ addition on advanced treatment of swine wastewater by using microalgae (미세조류를 이용한 양돈폐수 고도처리에서 슬러지 및 이산화탄소의 첨가의 영향)

  • Lim, Byung-Ran;Park, Ki-Young;Lee, Ki-Say;Lee, Soo-Koo
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.3
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    • pp.307-312
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    • 2011
  • The potential of algal-bacterial culture was investigated for advanced treatment of animal wastewater. Fed-batch experiments were carried out to examine treatability of nitrogen and phosphorus in different microbial consortium: Chlorella vulgaris, activated sludge, three microalgae strains (Scenedesmus, Microcystis, Chlorella) and Bacillus consortium, and three microalgae strains and sludge consortium. Single culture of C. vugaris showed the better efficiency for nitrogen removal but was not good at organic matter and phosphorus removal compared with activated sludge. Three microalgae and Bacillus consortium was best culture among the culture and consortium for pollutants removal tested in this experiment. Effect of $CO_2$ addition was studied by using three microalgae and Bacillus consortium. $CO_2$ addition enhanced T-P removal efficiency up to 60%. However, removal efficiencies of T-N and ammonia nitrogen reduced on the contrary.

Reactive separation of boron using a liquid membrane of diol in vegetable oil

  • Hossain, Md. M.;Maraqa, M.A.
    • Membrane and Water Treatment
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    • v.8 no.1
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    • pp.19-34
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    • 2017
  • Boron exists in dilute concentrations in sea water, ground water and waste waters. Reactive liquid extraction can be used for removing boron to make the treated water suitable for drinking and irrigation, with its final concentration less than 0.5 ppm. The results of equilibrium experiments are reported on the removal of boron using 2-butyl-2-ethyl-1, 3-propanediol (BEPD as a nonionic carrier) in sunflower oil, a non-traditional solvent. The results of removal of boron from aqueous solutions in the concentration range 0.5-20 ppm are presented. It is shown that this new liquid membrane system, is able to remove boron from ground waters at their natural pH of 6-8 (without any chemical addition for pH adjustments). The removal efficiency is good when the process is upgraded to a hollow-fibre membrane contactor and approximately 45% boron can be removed in a single-stage contact. There are additional advantages of this new approach that includes reduced operational health and safety and environmental issues. The results reported here provide guidelines to the development of boron removal process using renewable, biodegradable, safe and cheap solvent system such as sunflower oil.

A Study on Constructed Wetland Ecological Park Design with Multiple-cell FWS Layout -focus on Structural Design of Sustainable Structured wetland Biotope(SSB) Park- (자유수면형 인공습지 환경·생태공원 설계 -생태적 수질정화비오톱 공원의 구조설계를 중심으로-)

  • Byeon, Wooil
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.9 no.5
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    • pp.1-9
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    • 2006
  • The purpose of this study is to make a design guideline in designing constructed wetland which can treat water quality both of point and nonpoint source water pollution. It focuses on structural aspects of two case studies of constructed wetland applying SSB(Sustainable Structured wetland Biotope) system in Korea. The constructed wetland of Lake Ju-am which was constructed in 2002 by Environmental Management Corporation, was designed by applying SSB system. It shows higher removal efficiency than expected - 56% of BOD removal efficiency, 60% of T-N removal, and 76% of T-P removal efficiency. In two cases, total wetland areal extents were calculated referred to treatment efficiency. The system is consist of micro-cell structures : inflow channel, forebay, multiple wetland cells and micro-pool. When designing constructed wetland appropriate in local area, the total organic system of vertical and horizontal structure : geology, hydrology, land use, and ecological surroundings of the sites should be considered totally.

Treatment of Piggery Wastewater by Anoxic-Oxic Biofilm Process (준혐기-호기 생물막 공정을 이용한 돈사폐수 처리)

  • 임재명;한동준
    • Journal of environmental and Sanitary engineering
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    • v.12 no.2
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    • pp.1-12
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    • 1997
  • This research aims to develop biofilm process for the nutrient removal of piggery wastewater. The developed process is the four stage anoxic-oxic biofilm process with recirculation of the final effluent. In summery, the results are as follows: 1. Nitrification in the piggery wastewater built up nitrite because of the high strength ammonia nitrogen. The nitrification of nitrobacter by free ammonia was inhibited in the total ammonia nitrogen loading rate with more than 0.2 kgNH$_{3}$-N/m$^{3}$·d. 2. The maximal total ammonia nitrogen removal rate was obtained at 22$\circ $C and without being affected by the loading rate. But total oxidized nitrogen production rate was largely affected by loading rate. 3. Autooxidation by the organic limit was a cause of the phosphorus release in the aerobic biofilm process. But the phosphorus removal rate was 90 percent less than the influent phosphorus volumetric loading rate of above 0.1 kgP/m$^{3}$·d. Therefore, the phosphorus removal necessarily accompanied the influent loading rate. 4. On the anoxic-oxic BF process, the total average COD mass balance was approximately 67.6 percent. Under this condition, the COD mass removal showed that the cell synthesis and metabolism in aerobic reactor was 42.8 percent and that the denitrification in anoxic reactor was 10.7 percent, respectively.

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Investigation of PEG(polyethyleneglycol) Removal Mechanism during UV/O2 Gas Phase Cleaning for Silicon Technology (UV/O2 가스상 세정을 이용한 실리콘 웨이퍼상의 PEG 반응기구의 관찰)

  • Kwon, Sung-Ku;Kim, Do-Hyun;Kim, Ki-Dong;Lee, Seung-Heun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.11
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    • pp.985-993
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    • 2006
  • An experiment to find out the removal mechanism of PEG(polyethyleneglycol) by using UV-enhanced $O_2$ GPC (gas phase cleaning) at low substrate temperature below $200^{\circ}C$ was executed under various process conditions, such as substrate temperature, UV exposure, and $O_2$ gas. The possibility of using $UV/O_2$ GPC as a low-temperature in-situ cleaning tool for organic removal was confirmed by the removal of a PEG film with a thickness of about 200 nm within 150 sec at a substrate temperature of $200^{\circ}C$. Synergistic effects by combining photo-dissociation and photo oxidation can only remove the entire PEG film without residues within experimental splits. In $UV/O_2$ GPC with substrate temperatures higher than the glass transition temperature, the substantial increase in the PEG removal rate can be explained by surface-wave formation. The photo-dissociation of PEG film by UV exposure results in the formation of end aldehyde by dissociation of back-bone chain and direct decomposition of light molecules. The role of oxygen is forming peroxide radicals and/or terminating the dis-proportionation reaction by forming peroxide.

Removal of Benzene and Toluene by Photo-catalyst Adsorbent Prepared from MSWI Fly Ash (소각비산재로 제조한 광촉매 흡착제의 벤젠과 톨루엔 제거특성)

  • Choi So-Young;Shim Young-Sook;Lee Woo-Keun
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.4
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    • pp.431-438
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    • 2005
  • In order to apply the photocatalytic decomposition of aromatic VOCs, adsorbent prepared from MSWI fly ash was coated by $TiO_2$ solution to endow with photo-catalytic function. The effects of coating number, existence of light source and the type of $TiO_2$ solution used for coating were examined. Adsorbent coated with amorphous $TiO_2$ solution showed higher adsorptivity than adsorbent coated with crystal $TiO_2$ solution. Without light source, breakthrough curve of photo -catalyst absorbent for VOCs removal was similar to that of absorbent made from MSWI fly ash. On the other hand, breakthrough time was enlarged with light source and total removal efficiency of benzene and toluene was also increased. It can be explained as photo-decomposition effect of $TiO_2$ photo-catalyst. Total removal efficiency of benzene and toluene was increased according to the increase of coating number with light source. It was due to the effect of adsorption and photo reaction of photo-catalytic adsorbent. But total removal efficiency of benzene was lower than that of toluene. Because benzene was removed more effectively than toluene by adsorption, but photo - decomposition effect oi toluene was more high than benzene.

A Comparison Study on the Simultaneous Organic, Nitrogen and Phosphorus Removal in Sequencing Batch Reactor and Sequencing Batch Biofilm Reactor (연속 회분식 반응기와 연속 회분식 생물막 반응기의 유기물, 질소 및 인의 동시 제거에 관한 비교 연구)

  • Park Young-Seek;Kim Dong-Seog
    • Journal of Environmental Health Sciences
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    • v.31 no.2 s.83
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    • pp.152-159
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    • 2005
  • Laboratory scale experiments were conducted to study the applicability, and to compare the performance of two types of sequencing batch reactor (SBR)systems, a conventional SBR and sequencing batch biofilm reactor (SBBR) on the biological nitrogen and phosphorus removal. The nitrification rate in SaR was higher than that in SBBR both in high influent TOC concentration. The denitrification was completed at the first non-aeration period in SBR, however, the additional non-aeration period should be installed or the first aeration period should be extended more in order to complete the nitrogen removal in SBBR. The time at the first aeration period was more needed as about 4-5 h in order to uptake all the released $PO_4^{3-}\;-P$ at the first non-aeration period. SBBR needed more operation time, especially the first aeration time, than SBR at the high influent TOC concentration in order to complete nitrogen and phosphorus removal.