• Title/Summary/Keyword: Organic removal

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Effect of Coagulation Condition on Coagulation/Ultrafiltration Membrane Process (응집·한외여과 공정에서 응집조건 결정에 관한 연구)

  • Moon, Seong-Yong;Lee, Sang-Hyup;Kim, Seung-Hyun;Moon, Byung-Hyun
    • Journal of Korean Society on Water Environment
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    • v.21 no.4
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    • pp.379-384
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    • 2005
  • In this research, coagulation was employed as the pretreatment for membrane process. The effective coagulation conditions were decided after the discussion of different coagulant doses and mixing conditions, etc. Raw water was taken from Nakdong River. The best operation occurred when G value was $230s^{-1}$ and the slow mixing lasted around 5 minutes at G value was $23s^{-1}$. To investigate the optimum coagulant dosage, the optimum organics removal was target as organic removal reduces membrane fouling effectively than particle removal. This result indicated that organics are more important causes than turbidity for membrane fouling. However, turbidity becomes an important factor after certain amount of organic matters is removed.

Operation Characteristics of an UASB at High Organic Loading Condition for Thermal Elutriated Acids of Piggery Wastewater Treatment (가축분뇨 고온 세정산발효액 처리를 위한 고부하 조건에서의 UASB 운전특성)

  • Kwon, Koo-Ho;Jung, Yong Jun;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.28 no.6
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    • pp.781-785
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    • 2012
  • This study was carried out to treat the thermal elutriated acids of piggery wastewater using UASB process. The UASB reactor was operated at an organic loading rate (OLR) of $7.4\;kgCOD/m^3-day$ (6.5 ~ 9.0). During the start-up period, the low COD removal efficiency (20%) was caused by shock loading and instability in the reactor. It was mainly due to the high concentration amounts of ammonia nitrogen, which caused inhibitory and toxic effects to toward the anaerobic bacteria. In steady state, the UASB reactor showed a SCOD removal efficiency of 71% and a VS removal efficiency of 39%. The gas production and methane content were 1.3 L/day $(0.21\;m^3\;CH^4/kg$ COD removed) and 77%, respectively.

The study of chemical treatment of pulp mill bleaching waste liquor using lime (석회를 이용한 펄프공장 폐액의 화학적 처리에 관한 연구)

  • 정병곤;이헌모;윤종호
    • Journal of environmental and Sanitary engineering
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    • v.12 no.2
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    • pp.23-28
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    • 1997
  • This study was conducted to know the possibility of reducing lime dosage by recycling sludge from bleaching wastewater lime coagulation settlement treatment at pulp mill process. In case of bleaching wastewater at the pulp mill process, when the lime dosage was increased, the removal efficiency of TSS(Total Suspended Solids) was increased, proportionally, but the organic removal efficiency was increased very slowly. It was concluded that sludge recycling at the lime coagulation settlement process was effective method to reduce the requirement of lime dosage. At the lime coagulation settlement process with sludge recycling, when the recycling number was increased, the organic removal efficiency was decreased, sharply. It was evaluated that the pH could be the basic standard for lime supplement by sludge recycling.

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Column Removal of Trichloroethylene and Dichloromethane using Low Cost Activated Carbon

  • Radhika, M.;Lee, Young-Seak;Palanivelu, K.
    • Carbon letters
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    • v.11 no.1
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    • pp.13-21
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    • 2010
  • Coconut shell activated carbon (CSAC) was investigated for its ability in the removal of two neutral chlorinated organic compounds, namely trichloroethylene (TCE) and dichloromethane (DCM) from aqueous solution using a packed bed column. The efficiency of the prepared activated carbon was also compared with a commercial activated carbon (CAC). The important design parameters such as flow rate and bed height were studied. In all the cases the lowest flow rate (5 mL/min) and the highest bed height (25 cm) resulted in maximum uptake and per cent removal. The experimental data were analysed using bed depth service time model (BDST) and Thomas model. The regeneration experiments including about five adsorption-desorption cycles were conducted. The suitable elutant selected from batch regeneration experiments (25% isopropyl alcohol) was used to desorb the loaded activated carbon in each cycle.

Synthesis of Silica Microspheres Containing Iron Oxide Nanoparticles for Removal of Organic Pollutant by Adsorption and Photocatalytic Decomposition

  • Young-Sang Cho;Sohyeon Sung
    • Archives of Metallurgy and Materials
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    • v.66 no.3
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    • pp.771-776
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    • 2021
  • Iron oxide nanoparticles were incorporated to form composite microspheres of SiO2 and Fe2O3 for magnetic separation of the particles after adsorption or photochemical decomposition. Economic material, sodium silicate, was purified by ion exchange to prepare aqueous silicic acid solution, followed by mixing with iron oxide nanoparticles. Resulting aqueous dispersion was emulsified, and composite microspheres of SiO2 and Fe2O3 was formed from the emulsion droplets as micro-reactors during heating. Removal of methylene blue using the composite microspheres was performed by batch adsorption process. Synthesis of composite microspheres of silica containing Fe2O3 and TiO2 nanoparticles was also possible, the particles could be separated using magnets efficiently after removal of organic dye.

Evaluation of Haloacetic Acid Formation Potential in Drinking Water Treatment Process by Fraction Technique (정수처리 공정에서 용존 유기물질 분류에 의한 haloacetic acid 생성능 평가)

  • Son, Hee-Jong;Hwang, Young-Do;Ryu, Dong-Choon;Jung, Chul-Woo;Lee, Gun;Son, Hyeng-Sik
    • Journal of Environmental Science International
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    • v.23 no.9
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    • pp.1655-1662
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    • 2014
  • A comprehensive fractionation technique was applied to a set of water samples obtained along drinking water treatment process with ozonation and biological activated carbon (BAC) process to obtain detailed profiles of dissolved organic matter (DOM) and to evaluate the haloacetic acid (HAA) formation potentials of these DOM fractions. The results indicated that coagulation-sedimentation-sand filtration treatment showed limited ability to remove hydrophilic fraction (28%), while removal of hydrophobic and transphilic fraction were 57% and 40%, respectively. And ozonation and BAC treatment showed limited ability to remove hydrophobic fractions (6%), while removal of hydrophilic and transphilic fractions were 25% and 18%. The haloacetic acid formation potential (HAAFP)/dissolved organic carbon (DOC) of hydrophilic fraction was the highest along the treatment train and HAAFP/DOC of hydrophilic fraction was higher than hydrophobic and transphilic fraction as 23%~30%, because of better removal for hydrophobic fraction both in concentration and reactivity.

Nutrient Removal Using Fermented Organic Acids Derived from the Primary Sludge in the Intermittent Aeration Activated Sludge Process

  • Weon, Seung-Yeon;Lee, Sang-Il;Lee, Chan-Won
    • Environmental Engineering Research
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    • v.16 no.4
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    • pp.213-218
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    • 2011
  • The two-stage intermittent aeration activated sludge process (IAP) and dynamic-flow intermittent aeration activated sludge process (DFP) were investigated for the nutrient removal of domestic wastewater. Three sets of IAP and one set of DFP were operated. The fermented settled sludge taken from the primary settling tank was added to two IAP and one DFP as an external electron donor, with one IAP, in which an external carbon source was not added, as a control. All the systems were operated at a sludge retention time of 20 days and a hydraulic retention time of 12 hr. A Higher denitrification rate was observed with the fermented settled sludge for the denitrification compared to the process without the addition of the organic source. The result indicates that the fermented acid from the primary domestic sludge has been proved to be an excellent electron donor for denitrification and biological phosphorus removal with IAP and DFP in treating relatively low C/N ratio(Carbon / Nitrogen ratio) wastewater. Phosphate accumulating organisms have a capability of competing with denitrifiers in the presence of volatile organic acids under anoxic conditions.

Pretreatment by the Process of BAC Fluidized Bed to produce the Biologically Stable Drinking Water (생물활성탄 유동상법에 의한 상수원수의 생물학적 전처리공정)

  • 우달식;남상호
    • Journal of Environmental Health Sciences
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    • v.24 no.1
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    • pp.38-46
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    • 1998
  • This study was to investigate the effects of carbon loadings, temperature and expansion ratio on the waterborne organic removal by the biologically active GAC fluidized bed on a laboratory scale. The raw water to be treated comes from midstream of Han river. BACFB(Biological Activated Carbon Fluidized Bed) process was very effective to remove the biodegradable fraction of dissolved organic matter. The more carbon weighed, the more DOC removed in a range from 16.7 to 133.3 g/l. DOC and UV$_{254}$ were removed more than 40% and 20% above 20$\circ$C respectively. Between 5$\circ$C and 10$\circ$C, DOC and UV$_{254}$ were eliminated about 30% and 15% respectively. In general, even if the temperature was higher, DOC removal was a little sensitive, probably influenced by GAC's residual adsorption capacity. UV$_{254}$ reduction was little fluctuated in accordance with water temperature. The gradual increase in expansion ratio from 10% to 75% didn't greatly affect on the removal of DOC and UV$_{254}$. The expansion ratio, therefore, is not a key factor over the critical expansion ratio.

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Anaerobic Digestion of Pig Manure and Night Soil Mixed Waste in a Normal Temperature (I) (常溫에서 豚 . 人糞混合廢棄物의 嫌氣性處理(I))

  • Kim, Nam-Cheon;Min, Dal-Ki
    • Journal of Environmental Health Sciences
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    • v.14 no.1
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    • pp.63-71
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    • 1988
  • This study is an experimental research on the anaerobic digestion of pig manure and night soil mixed waste at room temperature (25$\circ$C), and the results are shown below: 1. The steady-state condition based on gas production as digestion temperature dropped to 25$\circ$C from 35$\circ$C was achieved at around 28, 47, 56, 64 days respectively when its hydraulic retention time(HRT) are 10, 20, 30, 40 days. 2, Alkalinity and volatile acid(VA) was increased as increasing the organic loading. 3. Removal efficiency of chemical oxygen demand(COD) and biochemical oxygen demand (BOD) was improved as longer HRT, and generally COD value is lower and BOD value is higher relatively. 4. Overall treatment efficiencies of mixed waste are higher than of pig manure and of night soft. 5. Organic removal efficiency at room temperature (25$\circ$C) is 20-25% lower at medium temperature (35$\circ$C) in a same VS loading condition. 6. Refractory fraction of the infiuent VS and organic removal rate constant(K) estimated at around 37% and 0.107/day respectively.

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Performance Evaluation of the Multistage Soil Washing Efficiency for Remediation of Mixed-contaminated Soil with Oil and Heavy Metals (유류/중금속 복합오염토양 정화를 위한 다단 토양세척 효율평가)

  • Kim, Daeho;Park, Kwangjin;Cho, Sungheui;Kim, Chikyung
    • Journal of Soil and Groundwater Environment
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    • v.22 no.2
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    • pp.33-40
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    • 2017
  • In typical remediation practices, separate washing systems have to be applied to clean up the soils contaminated with both oil and heavy metals. In this study, we evaluated the efficiency of successive two-stage soil washing in removal of mixed-contaminants from soil matrix. Two-stage soil washing experiments were conducted using different combinations of chemical agent: 1) persulfate oxidation, followed by organic acid washing, and 2) Fenton oxidation, followed by inorganic acid washing. Persulfate oxidation-organic acid washing efficiently removed both organic and inorganic contaminants to meet the regulatory soil quality standard. The average removal rates of total petroleum hydrocarbons (TPH), Cu, Pb, and Zn were 88.9%, 82.2%, 77.5%, and 66.3% respectively, (S/L 1:10, reaction time 1 h, persulfate 0.5 M, persulfate:activator 3:1, citric acid 2 M). Fenton oxidation-inorganic acid washing also gave satisfactory performances to give 89%, 80.9%, 87.1%, and 67.7% removal of TPH, Cu, Pb, and Zn, respectively (S/L 1:10, reaction time 1 hr, hydrogen peroxide 0.3 M, hydrogen peroxide:activator 5:1, inorganic acid 1 M).