• Title/Summary/Keyword: Organic relationship

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Effects of Annealing on Structure and Properties of TLCP/PEN/PET Ternary Blend Fibers

  • Kim, Jun-Young;Seo, Eun-Su;Kim, Seong-Hun;Takeshi Kikutani
    • Macromolecular Research
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    • v.11 no.1
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    • pp.62-68
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    • 2003
  • Thermotropic liquid crystalline polymer (TLCP)/poly(ethylene 2,6-naphthalate) (PEN)/poly(ethylene terephthalate) (PET) ternary blends were prepared by melt blending, and were melt-spun to fibers at various spinning speeds in an effort to improve fiber performance and processability. Structure and property relationship of TLCP/PEN/PET ternary blend fibers and effects of annealing on those were investigated. The mechanical properties of ternary blend fibers could be significantly improved by annealing, which were attributed to the development of more ordered crystallites and the formation of more perfect crystalline structures. TLCP/PEN/PET ternary blend fibers that annealed at 18$0^{\circ}C$ for 2 h, exhibited the highest values of tensile strength and modulus. The double melting behaviors observed in the annealed ternary blend fibers depended on annealing temperature and time, which might be caused by different lamellae thickness distribution as a result of the melting-reorganization process during the DSC scans.

Determination of Aconitine and Related Alkaloids in Processed Buza (부자류 생약의 성분인 아코니틴과 관련 알칼로이드의 정량)

  • 엄동옥;한상욱;신현덕
    • YAKHAK HOEJI
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    • v.44 no.2
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    • pp.135-140
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    • 2000
  • Determination of Aconitum alkaloids in processed Buza (Cho-0, Salted Buza, Moist-heating Buza, Limed Buza), which had been prepared from the raw tubers of Aconitum chiisanenseb(Ranunculaceae), was established using visible spectrophotometry and high-performance liquid chromatography (HPLC) method especially for Aconitine analysis. Aconitum alkloids were reacted with tetra- thiocy-anatocobalt[II] complex ion to form a stable ion pair. The reaction product was insoluble in water but freely soluble in several organic solvents. 1.2-Dichloroethane was the best extracting solvent among the examined solvents. Spectrophotometry of Aconitum alkaloids at nax. 625 was carried out. The HPLC method for aconitine was carried out using Radial PAK-CN column with gradient solvent system by solvent mixture of acetonitrile and phosphate buffer (pH 3.0) at 4$0^{\circ}C$ and 254 nm. Linear relationship was found between absorbance response and concentration of aconitine in range of 0.45 mM~0.9 mM ($r^2$=0.9949) by spectrophotometry and 0.3 mM~1.2mM($r^2$=0.9983) by HPLC method. These methods have been found to be suitable and reproducible for routine analysis of Aconitum alkaloids and its pharmaceutical preparations.

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Acidities of Benzyltetrahydrothiophenium Halides in Water. A Simple Method of Estimation

  • 조봉래;김용관;한만소;오광진
    • Bulletin of the Korean Chemical Society
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    • v.16 no.12
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    • pp.1218-1222
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    • 1995
  • The pKa values of benzyltetrahydrothiophenium halides 1a-f in water have been estimated by measuring the absorbances of the solution in aqueous hydroxide ion solution. Assuming that the ratios of the activity coefficients remains close to unity, the absorbance of the solution can be expressed as A/[SH]o=(εSH+εS-K[OH-])/(1+K[OH-]), where A, [SH]o, K, εSH, and εS- are the absorbance of solution, the initial concentration of 1a-f, the equilibrium constant, and the extinction coefficients for SH and S-, respectively. The εS- and K values that best fit with this equation were calculated by a nonlinear regression analysis with a large number of absorbance data determined at different [OH-] and [SH]o. The pKa values of the SH were then calculated with the relationship Ka=-log K+14. The validity of this method has been demonstrated by the excellent agreements between the experimental and literature pKa values of three organic acids. The pKa values of 1a-f estimated by this method are in the range of 12.5-15.3 and correlate well with the Hammett equation. The large negative deviation for the pKa values of 1e and 1f from the Hammett plot has been attributed to the extra hydrogen bonding between the phenyl group and water molecules attracted by the hydrophilic substituents.

Ralstonia pickettii Enhance the DDT Biodegradation by Pleurotus eryngii

  • Purnomo, Adi Setyo;Maulianawati, Diana;Kamei, Ichiro
    • Journal of Microbiology and Biotechnology
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    • v.29 no.9
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    • pp.1424-1433
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    • 2019
  • DDT is a hydrophobic organic pollutant, which can be bio-accumulated in nature and have adverse consequences on the physical condition of humans and animals. This study investigated the relationship between the white-rot fungus Pleurotus eryngii and biosurfactant-producing bacterium Ralstonia pickettii associated with the degradation of DDT. The effects of R. pickettii on fungal development were examined using in vitro confrontation assay on a potato dextrose agar (PDA) medium. R. pickettii culture was added to the P. eryngii culture at 1, 3, 5, 7, and 10 ml ($1ml{\approx}1.44{\times}10^{13}CFU$). After 7 d incubation, about 43% of the initial DDT ($12.5{\mu}M$) was degraded by the P. eryngii culture only. The augmentation of 7 ml of R. pickettii culture revealed a more highly optimized synergism with DDT degradation being approximately 78% and the ratio of optimization 1.06. According to the confrontational assay, R. pickettii promoted the growth of P. eryngii towards the bacterial colony, with no direct contact between the bacterial cells and mycelium (0.71 cm/day). DDD (1,1-dichloro-2,2-bis(4-chlorophenyl) ethane), DDE (1,1-dichloro-2,2-bis(4-chlorophenyl) ethylene), and DDMU (1-chloro-2,2-bis(4-chlorophenyl) ethylene) were identified as metabolic products, indicating that the R. pickettii could enhance the DDT biodegradation by P. eryngii.

Radioactivity analysis for EPS waste using organic solvents

  • Bae, Jun Woo;Kim, Hee Reyoung
    • Nuclear Engineering and Technology
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    • v.53 no.11
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    • pp.3717-3722
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    • 2021
  • In this study, the recovery rates of the dissolution method for radioactivity analysis of expandable polystyrene (EPS) with a liquid scintillation counter (LSC) using tetrahydrofuran (THF), toluene, and acetone as solvents were estimated. The detection efficiency calibration curve for each solvent was derived. Two methods-the volumetric ratio method and the quenching agent method-were used to prepare quench source sets, and calibration curves were derived by linking the data from the two quench source sets. The R2 value of the calibration curve for THF was found to be 0.984. The relationship between the mass of dissolved EPS and the quench level was estimated: the quench level increased as the mass of dissolved EPS increased. Premix and postmix dissolution methods were tested. The recovery rates using THF with the premix method were 84.9 ± 0.9% and 96.5 ± 1.5% for 3H and 14C, respectively. Furthermore, the stability of the recovery rate over time when using THF was evaluated. The dissolution method with the premixed solution exhibited a more stable recovery rate over time. The dissolution methods were found to be applicable for analysis using LSC, and THF was found to be the most suitable solvent for the proposed method.

A Study on Pritzker Architecture Prize and Urban Society (프리츠커 건축상과 도시사회에 관한 연구)

  • Choi, Suhl Ah
    • Journal of the Architectural Institute of Korea Planning & Design
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    • v.35 no.3
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    • pp.21-30
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    • 2019
  • The purpose of this study is to investigate how Pritzker Architecture Prize as a social act has maintained an organic relationship with the architecture, the urban society through the speakings and writings of the laureates of the Pritzker Architecture Prize. The composition of this research is to grasp the background of the establishment of Pritzker Architecture Prize and the examination process, to examine its social meaning, and to identify the main flow of words from writings about the laureates through the literature survey and text frequency analysis. And is to interpret the meaning of urban society change and words about the laureates. As a result of the analysis of the flow, it is a tendency to move from ideology and style to newness and innovation, and now to publicity and sociality. Especially in recent years, a wide range of values are floated as much as the complicated issues of urban society and the natural environment. The various architectural activities that make up the urban life became more important than the building units existing like an icon. It is considered possible because the Pritzker Architecture Prize has been awarded for a sustainable common social act. In addition, through literature surveys, have also seen changes in the value of individual laureates, the mixing of styles, and the eclectic aspect. Therefore, the task of reading change should not be a process of finding a new style for a new age, but a task of acknowledging heterogeneity of each architect and recognizing diversity through pluralization.

Henry James's The Wings of the Dove: Free Self and Identity (헨리 제임스의 『비둘기의 날개』 : 자유와 정체성의 문제)

  • Kim, Kyung-ah
    • English & American cultural studies
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    • v.9 no.1
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    • pp.27-50
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    • 2009
  • Henry James tries to describe minutely in The Wings of the Dove the process in which a bad faith grows, is practiced in one's self, and spreads to a society. Through this fictional specificity, he embodies an analogy between a bad faith and social role-playing. That is, he shows, through the main characters such as Milly Theale and Merton Densher, how self interacts with the other and a society. In this interaction, there is some essential element, namely, an organic relationship between a self identity and a social role-model, which James describes very meticulously. Therefore, the characters are depicted as seeking to define self identity and eventually distorting it. Thus, The Wings of the Dove can be seen as a tragedy in which the characters who have this wrongly distorted self identity come to experience its effects. The distorted self identity appears to function as a social role. Milly distorts her true self identity by internalizing a dove-image for it. This results in a bad faith. Moreover, the American girl Milly utilizes it as a convenient social role-model which makes it easy for her to interact and engage with the others in the European society. Merton also evades adventurous and painful self-reflection and self-criticism by sticking to the mannerisms of gentlemanship and imitates the sublimity which Milly shows him. Thus, Milly and Merton clearly omit self-inspection and self-inquiry for the contact between a free self and a society, which is essential to obtain social objectivity, namely, intersubjectivity.

Red ginseng (Panax ginseng Meyer) oil: A comprehensive review of extraction technologies, chemical composition, health benefits, molecular mechanisms, and safety

  • Truong, Van-Long;Jeong, Woo-Sik
    • Journal of Ginseng Research
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    • v.46 no.2
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    • pp.214-224
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    • 2022
  • Red ginseng oil (RGO), rather than the conventional aqueous extract of red ginseng, has been receiving much attention due to accumulating evidence of its functional and pharmacological potential. In this review, we describe the key extraction technologies, chemical composition, potential health benefits, and safety of RGO. This review emphasizes the proposed molecular mechanisms by which RGO is involved in various bioactivities. RGO is mainly produced using organic solvents or supercritical fluid extraction, with the choice of method greatly affecting the yield and quality of the end products. RGO contains a high unsaturated fatty acid levels along with considerable amounts of lipophilic components such as phytosterols, tocopherols, and polyacetylenes. The beneficial health properties of RGO include cellular defense, antioxidation, anti-inflammation, anti-apoptosis, chemoprevention, hair growth promotion, and skin health improvement. We propose several molecular mechanisms and signaling pathways that underlie the bioactivity of RGO. In addition, RGO is regarded as safe and nontoxic. Further studies on RGO must focus on a deeper understanding of the underlying molecular mechanisms, composition-functionality relationship, and verification of the bioactivities of RGO in clinical models. This review may provide useful information in the development of RGO-based products in nutraceuticals, functional foods, and functional cosmetics.

Characteristics of collaboration and artification in the fashion of Issey Miyake (이세이 미야케 패션의 컬래버레이션과 예술화 특성)

  • Oh, Mi Yeon;Lee, Younhee
    • The Research Journal of the Costume Culture
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    • v.30 no.2
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    • pp.173-188
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    • 2022
  • The purpose of this study is to analyze the collaboration and artification of the Issey Miyake fashion brand and to suggest the best course of artification that can secure the brand's value. The research methods are as follows: i) identifying the companies' strategy and flow through collaboration concepts and examples from Issey Miyake; ii) selecting Issey Miyake fashion brands and carrying out a literature review through websites, articles, and books; and iii) examining prior studies on the relationship between fashion and art. Results are as follows. The exhibition is divided into spaces for brand intangible assets, artistic collaboration with partners, art co-creation, and the aesthetics and tradition of the brand. Using exhibitions to share the artistic work of collaboration partners is expected to positively affect the brand's likability. The exhibit shares art collaborations in display cases for clothes and photographs. Artists and brands appear as an extension of the creative space and convergence design area. The artist's improvisation forms the creative space that communicates with the audience, and the convergence design area is expanded through the unifying organic connection between the various media in the fashion brand. The photographers and brands section displays the nature images of Pleats Please, as well as human and prism garment images. In these images, the viewer can perceive a story in the interplay between the human body and nature.

Changes in the Composition and Microbial Community of the Pepper Rhizosphere in Field with Bacterial Wilt Disease

  • Hyun Gi, Kong;Mee Kyung, Sang;Ju Hee, An;Songhwa, Kim;Yong Ju, Jin;Jaekyeong, Song
    • The Plant Pathology Journal
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    • v.38 no.6
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    • pp.692-699
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    • 2022
  • Bacterial wilt caused by Ralstonia solanacearum is considered one of the most harmful diseases of pepper plants. Recently, research on plant disease control through the rhizosphere microbiome has been actively conducted. In this study, the relationship with disease occurrence between the neighboring plant confirmed by analyzing the physicochemical properties of the rhizosphere soil and changes in the microbial community. The results confirmed that the microbial community changes significantly depending on the organic matters, P2O5, and clay in the soil. Despite significant differences in microbial communities according to soil composition, Actinobacteriota at the phylum level was higher in healthy plant rhizosphere (mean of relative abundance, D: 8.05 ± 1.13; H: 10.06 ± 1.59). These results suggest that Actinobacteriota may be associated with bacterial wilt disease. In this study, we present basic information for constructing of healthy soil in the future by presenting the major microbial groups that can suppress bacterial wilt.