• 제목/요약/키워드: Organic polymers

검색결과 418건 처리시간 0.03초

Organic Solvent Absorption characteristics of Split-type micro fiber fabrics

  • Lee, Kwang-Ju;Kim, Seong-Hun
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.95-95
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    • 2003
  • In this study, the influences of organic solvent viscosity on absorption properties of split-type micro fiber fabrics is examined with real time absorption measurement device built by our research group recently. And the absorption behavior of these fabrics is analyzed by material, fineness, construction, weight, thickness, and density of fabrics.

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Synthesis and Characterization of Blue Light-Emitting Polymers Containing Phenylenevinylene Units

  • 황도훈;강인남;장민식;심홍구
    • Bulletin of the Korean Chemical Society
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    • 제16권2호
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    • pp.135-138
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    • 1995
  • A series of new polymers containing phenylenevinylene (PV) units were synthesized by Wittig polycondensation reaction and properties of the synthesized polymers were characterized by FT-IR and UV-visible spectroscopy, and their light-emitting properties were studied. All of the synthesized polymers were soluble in organic solvents and showed good film quality. The absorption maxima and band edges of the polymers were moved to shorter wavelength region by reducing the electron donating alkoxy groups incorporated in phenylenevinylene unit. The photo-induced emission spectra were obtained and all of the polymers revealed their emission in blue region. The observed emission maxima of the polymers were ranged from 480-495 nm.

Hole trapping in carbon nanotube-polymer composite organic light emitting diodes

  • Woo, H.S.;Czerw, R.;Carroll, D.L.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.1047-1052
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    • 2003
  • Controlling carrier transport in light emitting polymers is extremely important for their efficient use in organic opto-electronic devices [1]. Here we show that the interactions between single wall carbon nanotubes (SWNTs) and conjugated polymers can be used to modify the overall mobility of charge carriers within nanotube-polymer nanocomposites. By using a unique, double emitting-organic light emitting diodes (DE-OLEDs) structure. we have characterized the hole transport within electroluminescent nanocomposites (nanotubes in poly (m-phenylene vinylene-co-2,5-dioctoxy-p-phenylene) or PmPV). We have shown using this idea that single devices with color tunability can be fabricated. It is seen that SWNTs in PmPV are responsible for hole trapping, leading to shifts in the emission wavelengths. Our results could lead to improved organic optical amplifiers, semiconducting devices, and displays.

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Synthesis and Characterization of Crosslinked Hole Transporting Polymers for Organic Light Emitting Diodes

  • Jang, Do-Young;Lim, Youn-Hee;Kim, Joo-Hyun;Kim, Jang-Joo;Shin, Jung-Hyu;Yoon, Do-Y.
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.235-235
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    • 2006
  • Triphenylamine derivatives play important roles as hole transporting materials in organic light emitting devices. However, low molecular weight triphenylamine derivatives show low glass transition temperature and aggregation behavior, and the vapor deposition step of low molecular weight materials is incompatible with large area display fabrication. Conventional polymer PEDOT-PSS HTL has serious drawbacks such as the ITO anode corrosion, poor surface energy match with aromatic EMLs. To solve these problems, we introduced crosslinkable units to triphenylamine-based polymers to make insoluble HTL by thermal curing following spin-coating. Electrochemical and optical properties of the new hole transporting materials were investigated. In addition, the device characteristics obtained with new hole transporting polymers were investigated in details.

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나노 사이즈 폴리파이롤의 합성 조건에 따른 크기 변화 (Effect of Polymerization Conditions on the Size Development of Nano-sized PPy)

  • Kim, Hyemin;Park, Chong-Rae
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 가을 학술발표회 논문집
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    • pp.171-172
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    • 2003
  • Electrically conducting polymers have attracted a great deal of attention because of their unusual electronic Properties.1 One of them, polypyrrole has been widely studieddue to its high conductivity and good environmental stability. 2Especially polypyrrole nano-Particles and -fibers are interesting because of their unique properties and applications. Recently amorphous polypyrrole nano-particles were fabricated using microemulsion Polymerization at low temperature. (omitted)

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다른 configuration을 가진 1,2-diaminocyclohexane이 폴리아크릴로니트릴(PAN)의 중합 거동과 입체규칙성에 미치는 영향 (Effect of the Addition of 1,2-Diaminocyclohexane with Different Configuration on the Polymerization Kinetics and Stereoregularity of Polyacrylonitrile(PAN))

  • Bae, Dong-Jin;Park, Chong-Rae
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2001년도 가을 학술발표회 논문집
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    • pp.101-102
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    • 2001
  • The control of the stereochemistry during the radical polymerization of vinyl monomer has been a long standing concern and is still one of the most important topic in synthetic polymer chemistry.[1-5] The stereoregularity of vinyl polymers often has significant effect on the properties of polymer materials. Therefore, it is important to devise methods to control stereoregularity during the polymerization reactions. (omitted)

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Effects of the Nitrile Group Substitution on the Gas Separation Properties of Aromatic Polyamide Membranes

  • Park, Ho-Seung;Jo, Won-Ho;Oh, Tae-Jin;Kang, Yong-Soo;Park, Hyun-Chae
    • Fibers and Polymers
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    • 제1권2호
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    • pp.111-115
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    • 2000
  • The effects of nitrile group substitution onto aromatic polyamide backbone on the gas permeability and permselectivity of the polymers are examined. The gas permeability of aromatic polyamides increase with increasing the content of nitrile group substitution, whereas the permselectivity decreases with increasing the nitrile group contents. The effects of chain linrearity on the permeability and permselectivity are also examined. The non-linearity of the polymers increases the permeability. These behaviors are interpreted in terms of chain packing and crystallinity of the aromatic polyamides.

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Rapid Formation of Optically Active and Organosoluble Polyamides Containing L-Alaninephthalimide Side Chain via Microwave Irradiation

  • Mallakpour, Shadpour;Rafiee, Zahra
    • Macromolecular Research
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    • 제17권11호
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    • pp.901-906
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    • 2009
  • Several aromatic optically active polyamides (PA)s were synthesized from 5-(2-phthalimidiylpropanoylamino)isophthalic acid with various aromatic diamines via direct polycondensation with triphenyl phosphite and pyridine in the presence of calcium chloride and N-methyl-2-pyrrolidone under microwave irradiation and conventional heating conditions. Under the optimized conditions, the reaction mixture was irradiated for 2 min. with a 100% irradiation power (900 W). The resulting polymers were obtained in high yield and moderate inherent viscosity ranging from 0.35 to 0.60 dL/g. All synthesized polymers showed excellent solubility in amide-type solvents. Thermogravimetric analysis revealed a 10% weight loss temperature and char yield at $600^{\circ}C$ in a nitrogen atmosphere of > $350^{\circ}C$ and > 58%, respectively, which suggests that the resulting PAs have good thermal stability.

A photoswitch from conjugative aromatic polymers

  • Kwon, Tae-Chang;Kim, Yong-Jung;Kim, Yu-Na;Lee, Hyo-Jin;Rameshbabu Krishnamurthy;Sarwade Bhimrao D.;Kim, Eun-Kyoung
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.174-174
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    • 2006
  • By condensing two different functional monomers, highly fluorescent aromatic polymers were prepared to produce a conjugated- conjugated spacer-type copolymer or conjugated-non-conjugated spacer-type copolymer. As synthesized polymers were soluble in an organic solvent and showed significantly enhanced optical properties compared to its monomer. Variation in the monomer composition afforded polymers having multifunctionaility such as photochromic-fluorescent polymers. Transparent thin films of the polymer as a solid medium were prepared using spin coating method and fabricated as a photoswitch, which showed photo-induced conductivity switching properties depending on the core monomeric unit in the polymers.

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