Effect of the Addition of 1,2-Diaminocyclohexane with Different Configuration on the Polymerization Kinetics and Stereoregularity of Polyacrylonitrile(PAN)

다른 configuration을 가진 1,2-diaminocyclohexane이 폴리아크릴로니트릴(PAN)의 중합 거동과 입체규칙성에 미치는 영향

  • Bae, Dong-Jin (Enviro-Polymers Design Laboratory. Hyperstructured Organic Materials Research Center and School of Materials Science and Engineering, Seoul National University) ;
  • Park, Chong-Rae (Enviro-Polymers Design Laboratory. Hyperstructured Organic Materials Research Center and School of Materials Science and Engineering, Seoul National University)
  • Published : 2001.10.01

Abstract

The control of the stereochemistry during the radical polymerization of vinyl monomer has been a long standing concern and is still one of the most important topic in synthetic polymer chemistry.[1-5] The stereoregularity of vinyl polymers often has significant effect on the properties of polymer materials. Therefore, it is important to devise methods to control stereoregularity during the polymerization reactions. (omitted)

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